3,7-dimethyl-[1,2]naphthoquinone | 7475-01-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 3,7-dimethyl-[1,2]naphthoquinone
• 英文别名: 3,7-Dimethyl-[1,2]naphthochinon；3.4-Dioxo-2.6-dimethyl-3.4-dihydro-naphthalin；3,7-Dimethylnaphthalene-1,2-dione
• CAS: 7475-01-6
• 化学式: C₁₂H₁₀O₂
• 分子量: 186.21
• InChiKey: SJOKRUOFICLCJY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  14
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  34.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  3,7-dimethyl-[1,2]naphthoquinone 在 sodium hydroxide 、 air 、 硫酸 作用下， 生成 3-hydroxy-2,6-dimethyl-[1,4]naphthoquinone
  参考文献：
  名称：

  A Study of the Addition Reactions of Certain Alkylated Naphthoquinones¹

  摘要：

  DOI：

  10.1021/ja01327a049
• 作为产物：
  描述：

  2,6-二甲基萘 在 氢氧化钾 、 dipotassium hydrogenphosphate 、 potassium nitrososulfonate 、 硫酸 作用下， 以 水 、 丙酮 为溶剂， 反应 12.5h， 生成 3,7-dimethyl-[1,2]naphthoquinone
  参考文献：
  名称：

  Gready, Jill E.; Hata, Kazumi; Sternhell, Sever, Australian Journal of Chemistry, 1990, vol. 43, # 3, p. 593 - 600

  摘要：

  DOI：

文献信息

• Cobalt(II) chelates as chain transfer agents in free radical polymerizations
  申请人：E.I. DU PONT DE NEMOURS AND COMPANY

  公开号：EP0196783A1

  公开（公告）日：1986-10-08

  Free radical polymerization processes employing cobalt (11) chelates of vicinal iminohydroxyimino compounds, diazadihydroxyiminodialkyldecadienes and -undecadienes, tetraazatetraalkylcyclotetradecatetraenes and -dodecatetraenes, N,N'-bis-(saliqylidene) ethylenediamines and dialkyldiazadioxodialkyldodecadienes and -tridecadienes as catalytic chain transfer agents for controlling the molecular weight of the homopolymers and copolymers produced.

  自由基聚合工艺，采用邻位亚氨基羟基亚氨基化合物、重氮二羟基亚氨基二烷基十二烷二烯和十一烷二烯、四氮四烷基环十四烷四烯和十二烷四烯、N,N'-双（水杨亚基）乙二胺和二烷基重氮二氧二烷基十二烷二烯和十三烷二烯的钴 (11) 螯合物作为催化链转移剂，以控制所生产的均聚物和共聚物的分子量。
• DE301079
  申请人：——

  公开号：——

  公开（公告）日：——
• Cassebaum, Chemische Berichte, 1957, vol. 90, p. 1537,1541
  作者：Cassebaum

  DOI：——

  日期：——
• Mentally disordered parricide and stranger killers admitted to high-security care. 1: A descriptive comparison
  作者：Helen Baxter、Conor Duggan、Emmet Larkin、Christopher Cordess、Kim Page

  DOI：10.1080/09585180122057

  日期：2001.1

  Parricide is an uncommon crime, so that many of the descriptive studies suffer from methodological shortcomings of small sample sizes and a non-representative ascertainment. We describe a consecutive series of mentally disordered offenders convicted of parricide who were admitted to high-security care and we compare their index characteristics with a group convicted of killing one or more strangers. The main findings were that the parricides were more likely to suffer from schizophrenia but less likely to have had a disrupted childhood and criminal history, as compared with those who had killed a stranger. Those in the parricide group had made a previous attack on their victim in 40% of cases. Overall, the study confirmed some of the differences that one might expect between these two groups of homicides, which had entirely different relationships to their victims.
• Weiszgerber; Kruber, Chemische Berichte, 1919, vol. 52, p. 363
  作者：Weiszgerber、Kruber

  DOI：——

  日期：——