Ag(+)-pyridine complex | 18746-47-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: Ag(+)-pyridine complex
• 英文别名: {Agpy}(1+)；[Ag-pyridine](1+)；Ag(pyridine)(1+)；[Ag-Py](1+)；Silver;pyridine
• CAS: 18746-47-9
• 化学式: C₅H₅AgN
• 分子量: 186.97
• InChiKey: HECBJDCKLPXEDK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.08
• 重原子数：
  7
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  12.9
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  Ag(+)-pyridine complex 以 gaseous matrix 为溶剂， 生成 银
  参考文献：
  名称：

  Ag + –吡啶配合物中的光解离电荷转移

  摘要：

  在气相中生成了Ag + -吡啶配合物。通过光解离技术观察到了离解性金属向配体的电荷转移。通过监测吡啶阳离子片段作为激光波长的函数，记录了两个连续吸收/解离谱带，并讨论了可能的解离机理。经测定，Ag + -吡啶的结合能为45 kcal / mol。建议通过离子-偶极相互作用将Ag +与C 5 H 5 N中的氮原子键合。

  DOI：

  10.1016/s0009-2614(99)00378-4
• 作为产物：
  描述：

  silver(I) iodate 在 吡啶 作用下， 以 水 为溶剂， 生成 Ag(+)-pyridine complex
  参考文献：
  名称：

  Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Ag: MVol.B6, 1.5.1.5.1, page 74 - 76

  摘要：

  DOI：

文献信息

• Bockris, J. O'M.; Ignatowicz, S., Transactions of the Electrochemical Society, 1947, vol. 92, p. 465 - 472
  作者：Bockris, J. O'M.、Ignatowicz, S.

  DOI：——

  日期：——
• Tamisier, A., Bulletin de la Societe Chimique de France, 1933, vol. 53, p. 157 - 166
  作者：Tamisier, A.

  DOI：——

  日期：——
• Complex formation of the Ag+ ion with pyridine in a methanol-dimethylformamide binary solvent: Changes in the enthalpy and entropy of the reaction
  作者：G. V. Moshorin、G. I. Repkin、V. A. Sharnin

  DOI：10.1134/s1070328407050107

  日期：2007.5

  The heat effects of formation of silver(1) mono- and bicomplexes with pyridine in a methanol-dimethylformamide binary solvent with different compositions at 298.15 K were determined by calorimetry. The changes in the entropy and Gibbs energy of these reactions were calculated, and the effect of the solvent composition on the shift of equilibrium of the complex formation reactions were considered. The contributions of the enthalpy of solvation of the reactants and the change in the heat effects of the reactions were analyzed.
• Calculation of equilibrium concentrations of complex ions from stability constant data
  作者：G. Curthoys、W. Brisley

  DOI：10.1016/s0003-2670(00)87286-4

  日期：——
• Investigation of pyridine–Ag(X), aqueous solutions: SERS and Raman study supported by NMR spectroscopy
  作者：Elena V. Potapkina、Anna S. Denisova、Liubov A. Myund、Artiom A. Makarov、Evgeniya M. Dem’yanchuk

  DOI：10.1016/j.molstruc.2011.04.035

  日期：2011.6

  The Ag-pyridine system has been investigated by Surface Enhanced Raman spectroscopy (SERS), Raman and Nuclear Magnetic Resonance (NMR) spectroscopy. Raman and NMR spectroscopy data concerning the formation of a pyridine complex with silver cations in the solution bulk have been used to explain the nature of a band at 1025 cm(-1) appearing in the SERS spectrum at the anode etching of a silver electrode. The existence of two complexes of different stoichiometric composition Ag(py)(+) and Ag(py)(2)(+), has been confirmed. The distribution of pyridine forms at Ag:py mole ratios from 0 to 6 has been obtained from the analysis of the intensities of individual components of the Raman spectrum. Both types of complexes have been shown to exist in solution at equimolar 1:1 ratio. It has been assumed that a complex of 1:1 composition will be adsorbed at the excess of Ag+ ions near the surface. (C) 2011 Elsevier B.V. All rights reserved.