2-(2H-Benzotriazol-2-yl)-6-[(3-tert-butyl-2-hydroxy-5-methylphenyl)methyl]-4-(2,4,4-trimethylpentan-2-yl)phenol | 209324-18-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-(2H-Benzotriazol-2-yl)-6-[(3-tert-butyl-2-hydroxy-5-methylphenyl)methyl]-4-(2,4,4-trimethylpentan-2-yl)phenol
• 英文别名: 2-[[3-(benzotriazol-2-yl)-2-hydroxy-5-(2,4,4-trimethylpentan-2-yl)phenyl]methyl]-6-tert-butyl-4-methylphenol
• CAS: 209324-18-5
• 化学式: C₃₂H₄₁N₃O₂
• 分子量: 499.7
• InChiKey: LEGLETKSWODEBL-UHFFFAOYSA-N

物化性质

• 沸点：
  614.8±65.0 °C(Predicted)
• 密度：
  1.09±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  10
• 重原子数：
  37
• 可旋转键数：
  7
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.44
• 拓扑面积：
  71.2
• 氢给体数：
  2
• 氢受体数：
  4

文献信息

• Curable resin composition and cold-setting adhesive
  申请人：Mori Shigeki

  公开号：US20060189736A1

  公开（公告）日：2006-08-24

  Disclosed is a moisture-curing type curable resin composition containing: a curable resin intramolecularly having a silicon-containing functional group; and a Lewis acid or a complex of the Lewis acid as a curing catalyst, the Lewis acid being selected from the group consisting of metal halides and boron halides, which is rapidly cured at room temperature. The silicon-containing functional group is represented by general formula: —SiX 1 X 2 X 3 or —SiR 1 X 1 X 2 (wherein, X 1 , X 2 and X 3 respectively represent a hydrolytic group and may be the same as or different from each other, and R 1 represents a substituted or unsubstituted organic group having 1 to 20 carbons). If the silicon-containing functional group is —SiR 1 X 1 X 2 , the curable resin further contains intramolecularly a polar component that is one of urethane, thiourethane, urea, thiourea, substituted urea, substituted thiourea, amide, and sulfide bonds, and hydroxyl, secondary amino and tertiary amino groups. Two-part type adhesive is constitutible with separating the curable resin from the curing catalyst.

  本发明公开了一种含有湿气硬化型可硬化树脂组分，包括：具有含硅官能团的可硬化树脂分子内部；以及一种Lewis酸或Lewis酸的复合物作为固化催化剂，所述Lewis酸选自金属卤化物和硼卤化物组成的群体，该组分在室温下迅速固化。所述含硅官能团由下式表示：—SiX1X2X3或—SiR1X1X2（其中，X1、X2和X3分别表示水解基团，可以相同也可以不同，R1表示具有1到20个碳的取代或未取代的有机基团）。如果所述含硅官能团为—SiR1X1X2，则可硬化树脂还包括分子内部的极性成分，该极性成分是尿素、硫脲、脲、硫代脲、取代脲、取代硫脲、酰胺和硫化物键以及羟基、二级胺和三级胺基之一。两部分型粘合剂可通过将可硬化树脂与固化催化剂分离而形成。
• Curable Resin Composition and Cold Setting Adhesive
  申请人：Mori Shigeki

  公开号：US20090264602A1

  公开（公告）日：2009-10-22

  Disclosed is a moisture-curing type curable resin composition containing: a curable resin intramolecularly having a silicon-containing functional group; and a Lewis acid or a complex of the Lewis acid as a curing catalyst, the Lewis acid being selected from the group consisting of metal halides and boron halides, which is rapidly cured at room temperature. The silicon-containing functional group is represented by general formula: —SiX 1 X 2 X 3 or —SiR 1 X 1 X 2 (wherein, X 1 , X 2 and X 3 respectively represent a hydrolytic group and may be the same as or different from each other, and R 1 represents a substituted or unsubstituted organic group having 1 to 20 carbons). If the silicon-containing functional group is —SiR 1 X 1 X 2 , the curable resin further contains intramolecularly a polar component that is one of urethane, thiourethane, urea, thiourea, substituted urea, substituted thiourea, amide, and sulfide bonds, and hydroxyl, secondary amino and tertiary amino groups. Two-part type adhesive is constitutible with separating the curable resin from the curing catalyst.

  本发明公开了一种含有湿度固化型可固化树脂组成物，包括：具有硅含有官能团的可固化树脂分子内部；以及作为固化催化剂的路易斯酸或路易斯酸的复合物，所述路易斯酸选择自金属卤化物和硼卤化物的组中，该组成物在室温下快速固化。硅含有官能团由通式表示：—SiX1X2X3或—SiR1X1X2（其中，X1、X2和X3分别表示一个水解基团，可以相同或不同，R1表示具有1到20个碳的取代或未取代的有机基团）。如果硅含有官能团为—SiR1X1X2，则可固化树脂还包含分子内部的极性组分之一，该极性组分为脲、硫脲、尿素、硫代尿素、取代尿素、取代硫脲、酰胺和硫化物键以及羟基、次级氨基和三级氨基基团。可将可固化树脂与固化催化剂分离以构成两部分型粘合剂。
• Benzotriazolyl-alkylene bisphenol compounds, process for their preparation, and stabilized organic materials containing them
  申请人：Johoku Chemical Co. Ltd.

  公开号：EP0847997A1

  公开（公告）日：1998-06-17

  A process for preparing benzotriazolyl-alkylene bisphenol compounds which comprises reacting a 2-hydroxyphenylbenzotriazole and a 2,4-substituted phenol with an aldehyde in the presence of a basic catalyst and an amine compound; benzotriazolyl-alkylene bisphenol compounds obtained by the process; and stabilized organic materials containing the resulting benzotriazolyl-alkylene bisphenol compounds in an amount of 0.01-10 percent by weight. It is possible to prepare the benzotriazolyl-alkylene bisphenol compounds at a high yield, and organic materials can be effectively stabilized with the resulting compounds.

  一种制备苯并三唑基-烯丙基双酚化合物的工艺，包括在碱性催化剂和胺化合物存在下，使 2-羟基苯基苯并三唑和 2，4-取代酚与醛反应；通过该工艺获得苯并三唑基-烯丙基双酚化合物；以及含有所得苯并三唑基-烯丙基双酚化合物的稳定有机材料，其含量为 0.01-10%（重量百分比）。可以高产率制备苯并三唑基亚烷基双酚化合物，并用所得化合物有效稳定有机材料。
• Primer composition
  申请人：SHIN-ETSU CHEMICAL CO., LTD.

  公开号：EP0934987A1

  公开（公告）日：1999-08-11

  A primer composition comprising (A) an acrylic resin, (B) a benzotriazole compound having not more than 1% by weight of heat loss when held at 150°C for 1 hour, and (C) an organic solvent. Also disclosed are an article obtained by forming a primer coat of the primer composition on the surface of a substrate, and an article obtained by forming the primer coat on the surface of a transparent plastic substrate and coating on the primer coat a protective coat comprising a condensation type curable silicone resin. The primer coat, which contains the above benzotriazole compound as an ultraviolet light absorber, has a superior weatherability while maintaining a good adhesion to the substrate.

  一种底漆组合物，包括(A)丙烯酸树脂，(B)苯并三唑化合物，当在 150°C 下保持 1 小时时，其热损失不超过 1%（按重量计），以及(C)有机溶剂。本发明还公开了一种通过在基材表面形成底漆组合物的底漆涂层而获得的物品，以及一种通过在透明塑料基材表面形成底漆涂层并在底漆涂层上涂覆包含缩合型可固化硅树脂的保护层而获得的物品。底涂层含有上述作为紫外线吸收剂的苯并三唑化合物，具有优异的耐候性，同时与基材保持良好的附着力。
• Process for producing a novel resin for optical materials having excellent color tone and transparency
  申请人：MITSUBISHI GAS CHEMICAL COMPANY, INC.

  公开号：EP0950905A2

  公开（公告）日：1999-10-20

  A process for producing a resin used for optical materials which process comprises curing a composition comprising an ultraviolet light absorbent and an epithio compound by polymerization in the presence of a catalyst, wherein amounts of the ultraviolet light absorbent and the catalyst each expressed as parts by weight per 100 parts by weight of the total amount of the epithio compound, the ultraviolet light absorbent and the catalyst satisfy both of the following relations (a) and (b):(a)0.001 ≦ ultraviolet light absorbent ≦ 1. 000(b).0.001 ≦ catalyst ≦ 5.000 Coloration and clouding of the material of a lens obtained by polymerization of an epithio compound caused by addition of an ultraviolet light absorbent can be prevented.

  一种生产光学材料用树脂的工艺，该工艺包括在催化剂存在下通过聚合固化由紫外光吸收剂和表硫基化合物组成的组合物，其中紫外光吸收剂和催化剂的量分别以表硫基化合物、紫外光吸收剂和催化剂总量每100重量份的重量份数表示，满足以下关系(a)和(b)：(a)0.001 ≦ 紫外线吸收剂 ≦ 1. 000(b).0.001 ≦ 催化剂 ≦ 5.000 可防止因添加紫外线吸收剂而使表硫醇化合物聚合得到的镜片材料变色和混浊。