N,N,N-Trimethylanilinium fluoride | 92477-88-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N,N,N-Trimethylanilinium fluoride
• 英文别名: trimethyl(phenyl)azanium;fluoride
• CAS: 92477-88-8
• 化学式: C9H14FN
• 分子量: 155.21
• InChiKey: IOIJXJFMFHVESQ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -1.11
• 重原子数：
  11
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  1

文献信息

• FLUORIDE ION BATTERY ELECTROLYTE COMPOSITIONS
  申请人：CALIFORNIA INSTITUTE OF TECHNOLOGY

  公开号：US20160181665A1

  公开（公告）日：2016-06-23

  A fluoride ion battery includes a substantially lithium-free anode and cathode. At least one of the anode or cathode contains fluorine, and a substantially lithium-free liquid electrolyte is used for charge transport. The electrolyte is liquid at temperatures below about 200 degrees Celsius, and can be formed from an organic-soluble fluoride salt dissolved in selected classes of solvents.

  氟离子电池包括一个基本上无锂的阳极和阴极。阳极或阴极中的至少一个含有氟，并且使用基本上无锂的液体电解质来进行电荷传输。该电解质在低于约200摄氏度的温度下是液态的，可以由溶于选定类别的溶剂中的有机溶性氟盐形成。
• Organic metal compound and process for preparing optically-active alcohols using the same
  申请人：Miki Takashi

  公开号：US20090062573A1

  公开（公告）日：2009-03-05

  The present invention provides an asymmetric reduction catalyst effective in preparing optically-active alcohol compounds having various functional groups, and a process for preparing optically-active alcohol compounds using said asymmetric reduction catalyst. The organic metal compound of the present invention is represented by the following general formula (1): wherein R 1 and R 2 may be mutually identical or different, and are an alkyl group, a phenyl group, a naphthyl group, a cycloalkyl group, or an alicyclic ring formed by binding R 1 and R 2 , which may have a substituent; R 3 is a hydrogen atom or an alkyl group; Cp is a cyclopentadienyl group, which may have a substituent, bound to M 1 via a π bond; X 1 is a halogen atom or a hydrido group; M 1 is rhodium or iridium; and * denotes asymmetric carbon.

  本发明提供了一种在制备具有各种官能团的光学活性醇化合物中有效的非对称还原催化剂，以及使用所述非对称还原催化剂制备光学活性醇化合物的方法。 本发明的有机金属化合物由以下通式(1)表示： 其中R1和R2可以相互相同或不同，并且是烷基、苯基、萘基、环烷基或由R1和R2结合形成的脂肪环环，其中可能含有取代基；R3是氢原子或烷基；Cp是环戊二烯基，可能含有取代基，通过π键与M1结合；X1是卤素原子或氢化物基团；M1是铑或铱；*表示不对称碳。
• ASYMMETRIC CATALYST AND PROCESS FOR PREPARING OPTICALLY ACTIVE ALCOHOLS USING THE SAME
  申请人：Watanabe Masahito

  公开号：US20100261924A1

  公开（公告）日：2010-10-14

  The present invention provides an organic metal compound, a ligand, an asymmetric catalyst, and a process for preparing optically-active alcohols using the asymmetric catalyst. The organic metal compound of the present invention is expressed by the following general formula (1): wherein in general formula (1), R 1 and R 2 are a mutually identical or mutually different, unsubstituted or substituted alkyl group, aryl group, cycloalkyl group, or R 1 and R 2 are bound to form an alicyclic ring, R 3 is a hydrogen atom or an alkyl group, R 4 is a branched alkyl group or an alkyl group that does or does not form a ring by itself, or an unsubstituted or substituted aryl group, or an unsubstituted or substituted heterocyclic group, Ar is an unsubstituted or substituted cyclopentadienyl group that is bound to M via a π bond, or an unsubstituted or substituted benzene, X is a hydride group or an anionic group, M is ruthenium, rhodium or iridium, L is a solvent molecule or a water molecule, l is 1 or 2, m is an integer from 0 to 2, n is 0 or 1, and when n is 0, X does not exist, and * represents asymmetric carbon, wherein R 4 is not a camphor group, a camphor derivative group, an isopropyl group or a phenyl group whenever R 1 and R 2 are both a phenyl group.

  本发明提供一种有机金属化合物、配体、不对称催化剂以及利用该不对称催化剂制备光学活性醇的方法。本发明的有机金属化合物由以下通用式（1）表示： 在通用式（1）中，R1和R2是相互相同或相互不同的未取代或取代的烷基基团、芳基团、环烷基团，或R1和R2结合形成脂环，R3是氢原子或烷基基团，R4是支链烷基基团或自身形成环或不形成环的烷基基团，或未取代或取代的芳基团，或未取代或取代的杂环基团，Ar是通过π键与M结合的未取代或取代的环戊二烯基团，或未取代或取代的苯，X是氢化物基团或阴离子基团，M是钌、铑或铱，L是溶剂分子或水分子，l为1或2，m为0到2的整数，n为0或1，当n为0时，X不存在，*代表不对称碳，其中当R1和R2均为苯基团时，R4不是藿香基团、藿香衍生基团、异丙基团或苯基团。
• Process for producing allylsubstituted phenol compound and the product
  申请人：MITSUBISHI PETROCHEMICAL CO., LTD.

  公开号：EP0394949A2

  公开（公告）日：1990-10-31

  A process for producing an allyl-substituted phenol compound is described, which comprises a combi­nation of a first step in which a phenol is reacted with an allyl halide in the presence of an alkaline aqueous medium to allyl-etherify the phenol and a second step in which the reaction product obtained in the first step and containing the allyl-etherified phenol is subjected to a Claisen rearrangement reaction in the absence of a medium. Also, a compound obtained by the above process is described.

  本发明描述了一种生产烯丙基取代的苯酚化合物的工艺，该工艺包括两个步骤：第一步，在碱性水介质存在下，苯酚与烯丙基卤化物反应，使苯酚烯丙基醚化；第二步，在没有介质存在的情况下，对第一步得到的含有烯丙基醚化苯酚的反应产物进行克莱森重排反应。此外，还描述了通过上述工艺获得的一种化合物。
• Trimerisierungskatalysatoren, ein Verfahren zu ihrer Herstellung und ihre Verwendung bei der Herstellung von Isocyanuratgruppen aufweisenden Polyisocyanaten
  申请人：BAYER AG

  公开号：EP0443167A1

  公开（公告）日：1991-08-28

  Für die Heterogenkatalyse geeignete Trimerisierungskatalysatoren für organische Isocyanate, bestehend aus quartären Ammonium- oder Phosphoniumfluoriden, die an ausgewählten Trägermaterialien adsorbiert vorliegen, ein Verfahren zur Herstellung dieser Katalysatoren durch Herstellung einer alkoholischen Lösung eines quartären Ammonium- oder Phosphoniumsalzes und Aufziehen der so erhaltenen Katalysatorlösung auf das Trägermaterial und die Verwendung der Katalysatoren bei der Herstellung von Isocyanuratgruppen aufweisenden Polyisocyanaten.

  适用于异相催化的有机异氰酸酯三聚化催化剂，由吸附在特定支撑材料上的季铵盐或氟化鏻组成；通过制备季铵盐或鏻盐的醇溶液，并将由此获得的催化剂溶液涂覆在支撑材料上制备这些催化剂的工艺；以及使用这些催化剂制备含有异氰尿酸酯基团的聚异氰酸酯。