(C6H5)3SnOCO(2,4,6-(CH3)3C6H2) | 61057-38-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (C6H5)3SnOCO(2,4,6-(CH3)3C6H2)
• 英文别名: Ph3SnOC(O)-C6H2-2,4,6-Me3；Triphenyl[(2,4,6-trimethylbenzoyl)oxy]stannane；triphenylstannyl 2,4,6-trimethylbenzoate
• CAS: 61057-38-3
• 化学式: C₂₈H₂₆O₂Sn
• 分子量: 513.223
• InChiKey: WCVZAZIXQGWUCG-UHFFFAOYSA-M

物化性质

• 沸点：
  564.9±60.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.44
• 重原子数：
  31
• 可旋转键数：
  6
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2,4,6-三甲基苯甲酸 、 双(三苯基锡)氧化物 以 苯 为溶剂， 生成 (C6H5)3SnOCO(2,4,6-(CH3)3C6H2)
  参考文献：
  名称：

  First example of a Sn–C bond cleaved product in the reaction of Ph3SnOSnPh3 with carboxylic acids. 3D-Supramolecular network formation in the X-ray crystal structure of [Ph2Sn(OH)OC(O)(Rf)]2, Rf = 2,4,6-(CF3)3C6H2

  摘要：

  Ph3SnOSnPh31 与 RfCOOH 2 的 1–2 反应通过简单的 Sn–C 键断裂过程导致形成 [Ph2Sn(OH)OC(O)(Rf)]23。

  DOI：

  10.1039/b212409b

文献信息

• First example of a Sn–C bond cleaved product in the reaction of Ph3SnOSnPh3 with carboxylic acids. 3D-Supramolecular network formation in the X-ray crystal structure of [Ph2Sn(OH)OC(O)(Rf)]2, Rf = 2,4,6-(CF3)3C6H2
  作者：Vadapalli Chandrasekhar、Selvarajan Nagendran、Kandasamy Gopal、Alexander Steiner、Stefano Zacchini

  DOI：10.1039/b212409b

  日期：2003.3.24

  A 1∶2 reaction of Ph3SnOSnPh31 with RfCOOH 2 leads to the formation of [Ph2Sn(OH)OC(O)(Rf)]23, by means of a facile Sn–C bond cleavage process.

  Ph3SnOSnPh31 与 RfCOOH 2 的 1–2 反应通过简单的 Sn–C 键断裂过程导致形成 [Ph2Sn(OH)OC(O)(Rf)]23。
• Solventless Reactions for the Synthesis of Organotin Clusters and Cages
  作者：Vadapalli Chandrasekhar、Viswanathan Baskar、Ramamoorthy Boomishankar、Kandasamy Gopal、Stefano Zacchini、Jamie F. Bickley、Alexander Steiner

  DOI：10.1021/om030338c

  日期：2003.9.1

  Organotin clusters and cages have been synthesized in quantitative yields by using a benign solventless synthetic methodology. Using this method a variety of structural forms, which include the drum, O-capped cluster, tetranuclear oxo cage, discrete, and polymeric compounds, have been synthesized. All these compounds (1-11) have been characterized by spectroscopic and analytical techniques. The new compounds, which include the hexameric drum [n-BuSn-(O)OCOAd](6) (Ad = adamantyl) 9, a triorganotin-based discrete structure Ph3SnO2C-C(6)H(2-)2,4,6-Me-3 (10), and a polymer Ph3SnOSO2-C6H3-2,5-Me-2 (11), have been characterized by single-crystal X-ray crystallography.