decyl(phenyl)phosphinic acid | 109730-18-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: decyl(phenyl)phosphinic acid
• 英文别名: decylphenylphosphinic acid；Decyl-phenyl-phosphinsaeure
• CAS: 109730-18-9
• 化学式: C₁₆H₂₇O₂P
• 分子量: 282.363
• InChiKey: NJHKTGAMDQLUIG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.9
• 重原子数：
  19
• 可旋转键数：
  10
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  37.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  ethyl Phenylphosphinate 在 盐酸 、 过氧化苯甲酰 作用下， 生成 decyl(phenyl)phosphinic acid
  参考文献：
  名称：

  Pudovik,A.N.; Konovalova,I.V., Journal of general chemistry of the USSR, 1960, vol. 30, p. 2328 - 2332

  摘要：

  DOI：

文献信息

• Synthesis of Disubstituted Phosphinates via Palladium-Catalyzed Hydrophosphinylation of H-Phosphinic Acids
  作者：Christelle Petit、Fabien Fécourt、Jean-Luc Montchamp

  DOI：10.1002/adsc.201100361

  日期：2011.8

  The first metal-catalyzed hydrophosphinylation of unsaturated hydrocarbons with H-phosphinic acids is described. A strategy to activate the PH bond through control of the tautomeric equilibrium using ethylene glycol is described. The reactions also avoid chromatographic purification.

  描述了用H-次膦酸的不饱和烃的第一金属催化的氢次膦酰基化。描述了一种通过使用乙二醇控制互变异构平衡来激活PH键的策略。反应还避免色谱纯化。
• Rapid and Efficient Microwave-Assisted Hydrophosphinylation of Unactivated Alkenes with H-Phosphinic Acids without Added Metal or Radical Initiator
  作者：Stamatia Vassiliou、Panagiota Troupa、Georgia Katsiouleri

  DOI：10.1055/s-0035-1560209

  日期：——

  A microwave-assisted hydrophosphinylation of unactivated alkenes with phosphinic acid and its derivatives under metal-free and initiator-free conditions is reported. Such hydrophosphinylations are operationally simple, use aqueous hypophosphorus acid, H-phenylphosphinic acid, and H-alkylphosphinic acids, and seem to proceed by a radical mechanism. Good isolated yields were obtained using a reasonable excess of the appropriate reagent.