azaperfluorooctane | 131968-13-3

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氟化物
• 英文名称: azaperfluorooctane
• 英文别名: N,N,1,1,2,2,3,3,4,4,5,5,6,6,7,7,7-heptadecafluoroheptan-1-amine
• CAS: 131968-13-3
• 化学式: C₇F₁₇N
• 分子量: 421.057
• InChiKey: CLZYIDYJEQZHQI-UHFFFAOYSA-N

物化性质

• 沸点：
  102.6±40.0 °C(Predicted)
• 密度：
  1.723±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.6
• 重原子数：
  25
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  18

反应信息

• 作为产物：
  描述：

  七亚甲基亚胺 在 fluorine 作用下， 以64%的产率得到perfluoro N-fluoroheptamethyleneimine
  参考文献：
  名称：

  直接氟化法合成全氟高支化杂环氟化合物

  摘要：

  六亚甲基亚胺，七亚甲基亚胺，2，6-二甲基吗啉，硫代吗啉，1，4-二甲基哌嗪和哌嗪的直接氟化产生相应的全氟化产物。发现全氟N，N 1-二氟哌嗪的19 F NMR光谱是温度依赖性的。

  DOI：

  10.1016/s0022-1139(00)82176-4

文献信息

• Surface modification method and surface-modified elastic body
  申请人：Sumitomo Rubber Industries, Ltd.

  公开号：EP2623335A2

  公开（公告）日：2013-08-07

  The present invention aims to provide a surface modification method for a rubber vulcanizate or a thermoplastic elastomer, which can impart various functions such as sliding properties and biocompatibility according to its use. The present invention relates to a surface modification method for modifying a rubber vulcanizate or a thermoplastic elastomer as an object to be modified, the method including: Step 1 of forming polymerization initiation points on a surface of the object to be modified; Step 2 of radical polymerizing monomers starting from the polymerization initiation points to grow polymer chains on the surface of the object to be modified; and Step 3 of functionalizing the polymer chains.

  本发明旨在提供一种橡胶硫化胶或热塑性弹性体的表面改性方法，该方法可根据用途赋予橡胶硫化胶或热塑性弹性体各种功能，如滑动性能和生物相容性。本发明涉及一种用于改性作为改性对象的橡胶硫化胶或热塑性弹性体的表面改性方法，该方法包括：步骤 1 在待改性物体表面形成聚合起始点；步骤 2 从聚合起始点开始对单体进行自由基聚合，在待改性物体表面生长聚合物链；步骤 3 对聚合物链进行官能化。
• Process for producing a modified electrolyte and the modified electrolyte
  申请人：KABUSHIKI KAISHA TOYOTA CHUO

  公开号：US20020160272A1

  公开（公告）日：2002-10-31

  A first process for producing a modified electrolyte consistent with the present invention comprises an amine treatment step of contacting a solid polymer electrolyte or a precursor thereof with an amine compound. Further, a first modified electrolyte consistent with the present invention consists essentially of what is obtained in such a process. A second process for producing the modified electrolyte consistent with the present invention includes a step of introducing, to a solid polymer compound having a functional group A, a first modifying agent comprising at least one functional group B capable of reacting with the functional group A thereby forming a first intermediate acid group; and the step also includes reacting the functional group A and the functional group B. Further, a second modified electrolyte consistent with the present invention comprises a solid polymer compound having side chains, at least one terminal acid group present at terminals of the side chains, and at least one intermediate acid group and/or reformed acid group present within the side chains identical with the side chains containing the terminal acid group.

  生产符合本发明的改性电解质的第一种工艺包括将固体聚合物电解质或其前体与胺化合物接触的胺处理步骤。此外，符合本发明的第一种改性电解质基本上由在这种工艺中得到的电解质组成。生产符合本发明的改性电解质的第二种工艺包括以下步骤：向具有官能团 A 的固体聚合物化合物中引入第一种改性剂，该改性剂包含至少一个能与官能团 A 反应从而形成第一中间酸基的官能团 B；该步骤还包括使官能团 A 和官能团 B 反应。此外，符合本发明的第二种改性电解质包括一种固体聚合物化合物，该化合物具有侧链、至少一个存在于侧链末端的末端酸基，以及至少一个存在于侧链中与含有末端酸基的侧链相同的中间酸基和/或重整酸基。
• SURFACE MODIFICATION METHOD AND SURFACE-MODIFIED ELASTIC BODY
  申请人：SUMITOMO RUBBER INDUSTRIES, LTD.

  公开号：US20130203883A1

  公开（公告）日：2013-08-08

  The present invention aims to provide a surface modification method for a rubber vulcanizate or a thermoplastic elastomer, which can impart various functions such as sliding properties and biocompatibility according to its use. The present invention relates to a surface modification method for modifying a rubber vulcanizate or a thermoplastic elastomer as an object to be modified, the method including: Step 1 of forming polymerization initiation points on a surface of the object to be modified; Step 2 of radical polymerizing monomers starting from the polymerization initiation points to grow polymer chains on the surface of the object to be modified; and Step 3 of functionalizing the polymer chains.
• US5587413A
  申请人：——

  公开号：US5587413A

  公开（公告）日：1996-12-24
• US5744640A
  申请人：——

  公开号：US5744640A

  公开（公告）日：1998-04-28