methyl propyl benzene-1,2-dicarboxylate | 34006-78-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: methyl propyl benzene-1,2-dicarboxylate
• 英文别名: phthalic acid methyl ester-propyl ester；Phthalsaeure-methylester-propylester；Methyl-propyl-phthalat；Phthalic acid, methyl 2-propyl ester；1-O-methyl 2-O-propyl benzene-1,2-dicarboxylate
• CAS: 34006-78-5
• 化学式: C₁₂H₁₄O₄
• 分子量: 222.241
• InChiKey: DIKFCKYFIUJMJY-UHFFFAOYSA-N

物化性质

• 保留指数：
  1578

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  16
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  methyl propyl benzene-1,2-dicarboxylate 生成 甲醇 、 三聚丙烯
  参考文献：
  名称：

  Nagel; Abelsdorff, vol. 5, p. 203

  摘要：

  DOI：
• 作为产物：
  描述：

  丙醇 、 2-(氯羰基)苯甲酸甲酯 生成 methyl propyl benzene-1,2-dicarboxylate
  参考文献：
  名称：

  Nagel; Abelsdorff, vol. 5, p. 203

  摘要：

  DOI：

文献信息

• Method for producing polyolefins
  申请人：IDEMITSU PETROCHEMICAL CO. LTD.

  公开号：EP0206172A1

  公开（公告）日：1986-12-30

  A method for producing a polyolefin is disclosed which comprises polymerizing an a-olefin in the presence of a catalyst composition comprising (A) a solid catalyst component prepared by contacting (a) a solid component comprising a magnesium alkoxide and/or a magnesium salt of a fatty acid supported on an inorganic oxide composed of at least one member selected from the group consisting of oxides of elements belonging to Groups II, III and IV of the periodic table and/or a composite inorganic oxide containing at least one member selected from the group consisting of oxides of elements belonging to Groups II, III and IV of the periodic table, the inorganic oxide or composite inorganic oxide having a surface hydroxide concentration of 3 µmol/m2 or less, (b) an electron donating compound and (c) a titanium halide, (B) an organic metal compound, and (C) an electron donating compound. According to the method, a step of removing the catalyst residue from the polypropylene produced can be eliminated and the products have well balanced mechanical strength such as stiffness and impact strength.

  本发明公开了一种生产聚烯烃的方法，该方法包括在催化剂组合物存在下聚合 a-烯烃，该催化剂组合物包括(A)固体催化剂组分，该固体催化剂组分通过与(a)固体组分接触制备，该固体组分包括支撑在无机氧化物上的烷氧化镁和/或脂肪酸镁盐，该无机氧化物由至少一种选自元素周期表中属于第 II、III 和 IV 族的元素的氧化物所组成的组的成员组成，和/或含有至少一种选自元素周期表中属于第 II、III 和 IV 族的元素的氧化物所组成的组的成员的复合无机氧化物、或复合无机氧化物，该无机氧化物或复合无机氧化物的表面氢氧化物浓度为 3 µmol/m2 或更低，(b)电子捐赠化合物和(c)卤化钛，(B)有机金属化合物和(C)电子捐赠化合物。 根据该方法，可以省去从生产的聚丙烯中去除催化剂残留物的步骤，产品具有良好的机械强度平衡，如刚度和冲击强度。
• Method for producing butene-1 polymer
  申请人：IDEMITSU PETROCHEMICAL CO. LTD.

  公开号：EP0257131A2

  公开（公告）日：1988-03-02

  A process for producing a butene-1 polymer is disclosed which is characterized in that, in a process for producing a homopolymer of butene-1 or a copolymer of butene-1 and an α-­olefin other than the butene-1 in the presence a catalyst obtained from a solid catalyst component (A), an organic aluminium compound (B) and an electron donating compound (C) and under the condition of vapor phase polymerization, the solid catalyst component (A) is a non-layer solid catalyst component obtained by producing a carrier by chlorinating at least one kind of organic magnesium compounds represented by formula MgRʹRʺ (1) wherein Rʹ and Rʺ, which may be the same or different, each represent an alkyl group having 1 to 20 carbon atoms, with at least one kind of chlorinating agents, the carrier produced is contacted in the presence of the electron donor with a titanic halide at a temperature of -25 to + 180°C, and the electron donating compound (C) is a heterocyclic compound represented by wherein R¹ and R⁴ each represent a hydrocarbon group, and R², R³ and R⁵ each represent a hydrogen atom or a hydrocarbon group, and reaction temperature as the vapor phase polymerization condition is from 45 to 70°C.

  本发明公开了一种生产丁烯-1聚合物的工艺，其特征在于，在由固体催化剂组分(A)、有机铝化合物(B)和电子捐赠化合物(C)得到的催化剂存在下，在气相聚合条件下，生产丁烯-1均聚物或丁烯-1与丁烯-1以外的α-烯烃共聚物的工艺中，固体催化剂组分(A)是通过氯化至少一种由式表示的有机镁化合物生产载体而得到的非层状固体催化剂组分。 MgRʹRʺ (1) 其中 Rʹ和 Rʺ（可以相同或不同）分别代表具有 1 至 20 个碳原子的烷基，与至少一种氯化剂一起，在电子供体存在的情况下，在-25 至 + 180°C 的温度下，将所生产的载体与卤化钛接触，电子供体化合物 (C) 是由以下式子表示的杂环化合物 其中 R¹ 和 R⁴ 各代表一个烃基，R²、R³ 和 R⁵ 各代表一个氢原子或烃基，作为气相聚合条件的反应温度为 45 至 70°C。
• A solid catalyst component for the polymerization of olefins and an olefin polymerization catalyst
  申请人：TOHO TITANIUM CO. LTD.

  公开号：EP0297163A1

  公开（公告）日：1989-01-04

  A solid catalyst component prepared by washing a solid substance, which has been obtained by reacting diethoxymagnesium (a) suspended in an alkylbenzene (b) with titanium tetracloride (c) in an amount less than l/2 of the alkylbenzene (b) in a ratio by volume and a phthalic diester (d) at a temperature within the range of 80-l35°C, with an alkylbenzene, and thereafter reacting the solid substance in a presence of an alkylbenzene (b) with titanium tetrachloride (c) in an amount less than l/2 of the alkylbenzene (b) in a ratio by volume as well as an olefin polymerization catalyst comprising (A) the solid catalyst component specified above, (B) a silicon compound of the general formula:     SiRm(OAlk)4-m wherein R is a group selected from an alkyl group, a cycloalkyl group, an aryl group and vinyl group, Alk is an alkyl group and m is 0 or an integer of l-3, with the proviso that when R is an alkyl group, R may be identical with Alk and when m is l, 2 or 3, the R groups and/or the Alk groups may respectively be identical or different, and (C) an organoaluminum compound. This catalyst is capable of exhibiting a high polymerization activity combined with a high stereospecific performance and producing stereoregular olefin polymers in a high yield.

  一种固体催化剂组分，其制备方法是：将悬浮于烷基苯（b）中的二乙氧基镁（a）与四氯化钛（c）（按体积比，其用量少于烷基苯（b）的 l/2）和邻苯二甲酸二酯（d）在 80-l35°C 范围内的温度下反应，然后将固体物质与烷基苯（b）和四氯化钛（c）（按体积比，其用量少于烷基苯（b）的 l/2）反应、与烷基苯反应，然后在有烷基苯（b）存在的情况下，使固体物质与四氯化钛（c）反应，四氯化钛（c）的用量按体积比少于烷基苯（b）的 l/2，以及烯烃聚合催化剂，烯烃聚合催化剂包括 (A) 上述固体催化剂组分、 (B) 通式如下的硅化合物 SiRm(OAlk)4-m 其中 R 是选自烷基、环烷基、芳基和乙烯基的基团，Alk 是烷基，m 是 0 或 l-3 的整数，但当 R 是烷基时，R 可与 Alk 相同，当 m 是 l、2 或 3 时，R 基团和/或 Alk 基团可分别相同或不同，以及 (C) 有机铝化合物。 这种催化剂能表现出较高的聚合活性和较高的立体特异性能，并能以较高的产率生产立体配位的烯烃聚合物。
• A polyolefinic resin and a resin composition comprising said resin
  申请人：IDEMITSU PETROCHEMICAL CO., LTD.

  公开号：EP0606618A2

  公开（公告）日：1994-07-20

  A polyolefinic resin which is a homopolymer of an olefin or a copolymer of olefins, has (i) intrinsic viscosity [η] measured in decaline at the temperature of 135°C in the range of 0.5 to 10 deciliter/g and (ii) content of insoluble fraction in boiling n-heptane (W) in the range of 10 to 99 weight % and shows (iii) relation between relaxation time of rubber component measured by pulse NMR at the temperature of 30°C [T2HR (30): µs], relaxation time of rubber component measured by pulse NMR at the temperature of 80°C [T2HR (80): µs] and the content of insoluble fraction in boiling n-heptane (W) satisfying the following equations: T2H​R (80) ≦ 670 - 2.2 × W T2H​R (80) / T2H​R (30) ≦ 8.8 + 0.086 × W and a propylenic resin composition comprising (A) 10 to 95 weight % of the polyolefinic resin, particularly a propylenic resin which is at least one kind selected from a homopolymer of propylene and copolymers of propylene containing 4 mol % or less of other olefinic units, and (B) 90 to 5 weight % of a propylenic random copolymer having intrinsic viscosity [η] measured in decaline at the temperature of 135°C in the range of 0.5 to 10 deciliter/g and containing 10 to 80 mol % of olefinic units other than the propylenic unit are disclosed. The polyolefinic resin and the composition have high heat resistance and excellent mechanical properties in a wide range of modulus, show small temperature dependence of the mechanical properties and do not cause stickiness on the surface of molded articles.

  一种聚烯烃树脂，它是烯烃的均聚物或烯烃的共聚物，(i)在温度为 135℃的癸碱中测得的固有粘度[η]在 0.(ii)在沸腾的正庚烷（W）中不溶部分的含量在 10 至 99 重量百分比之间，并显示(iii)在 30°C 温度下通过脉冲核磁共振测量的橡胶成分弛豫时间[T2HR (30)：μs]、在 80°C 温度下通过脉冲核磁共振测量的橡胶成分弛豫时间[T2HR (80)：μs]和在沸腾的正庚烷（W）中不溶部分的含量之间的关系满足以下公式： T2HR (80) ≦ 670 - 2.2 × W t2hr (80) / t2hr (30) ≦ 8.8 + 0.086 × W 和一种丙烯树脂组合物，该组合物包含 (A) 10 至 95 重量％的聚烯烃树脂，特别是至少一种选自丙烯均聚物和含有 4 摩尔％或更少其他烯烃单元的丙烯共聚物的丙烯树脂，以及 (B) 90 至 5 重量％的丙烯无规共聚物，该丙烯无规共聚物在 135°C 温度下以癸碱性测量的固有粘度[η]在 0.5 至 10 分升/克，并含有 10 至 80 摩尔％的丙烯单元以外的烯烃单元。这种聚烯烃树脂和组合物具有较高的耐热性，在较宽的模量范围内具有优异的机械性能，机械性能的温度依赖性较小，并且不会在模塑制品表面产生粘性。
• Polypropylene resin and film prepared therefrom
  申请人：IDEMITSU PETROCHEMICAL CO., LTD.

  公开号：EP0693524A1

  公开（公告）日：1996-01-24

  A polypropylenic resin which is used for preparing a film and has (1) a content of an isotactic pentad fraction as an index of stereoregularity and a content of a n-heptane insoluble fraction which are in a range of 85.0 to 92.0 % by mol and in a range of 93.0 to 97.0 % by weight, respectively, and satisfies a relation expressed by an equation:0.750P+27.125

  一种用于制备薄膜的聚丙烯树脂，其(1)作为立体均匀性指数的异构五元组分的含量和正庚烷不溶组分的含量分别在 85.0 至 92.0%（按摩尔计）和 93.0 至 97.0%（按重量计）的范围内，并满足由等式表示的关系：0.750P+27.125