申请人:KONICA CORPORATION
公开号:EP0193397A2
公开(公告)日:1986-09-03
@ A light-sensitive silver halide color photographic material having photographic constituent layers including a blue-sensitive silver halide emulsion layer, a green-sensitive silver halide emulsion layer and a red-sensitive silver halide emulsion layer on a support wherein the content of silver bromide of the silver halides in the green-sensitive silver halide emulsion layer and red-sensitive silver halide emulsion layer is 5 to 65 mole %, and the green-sensitive silver halide emulsion layer contains at least one of the compounds represented by the formula [I] shown below:
wherein X represents a halogen atom or a monovalent organic group eliminable through coupling reaction with an oxidized product of a developing agent; R, to R3, which may be either identical or different, each represent a hydrogen atom, a halogen atom, an alkyl group, a cycloalkyl group, an alkenyl group, a cycloalkenyl group, an alkynyl group, an aryl group, a heterocyclic group, an acyl group, a sulfonyl group, a sulfinyl group, a phosphonyl group, a carbamoyl group, a sulfamoyl group, a cyano group, a spiro compound residue, a bridged hydrocarbon compound residue, an alkoxy group, an aryloxy group, a heterocycloxy group, a siloxy group, an acyloxy group, a carbamoyloxy group, an amino group, an acylamino group, a sulfonamide group, an imide group, a ureido group, a sulfamoylamino group, an alkoxycarbonylamino group, an aryloxycarbonylamino group, an alkoxycarbonyl group, an aryloxycarboynyl group, an alkylthio group, an arylthio group or a heterocyclic thio group, with proviso that at least two of R, to R3 are not hydrogen atoms; R4 represents a hydrogen atom, an alkyl group, an aryl group, a heterocyclic group, an acylamino group, an alkylamino group, an anilino group, an alkoxycarbonyl group or an alkylthio group.
According to the light-sensitive silver halide color photographic material of this invention, rapid developing processing is possible with improvement of processing stability in the rapid developing processing, and yet saving of silver is possible, simultaneously with inhibition of generation of fog, and moreover color image with good light resistance can be obtained.
@一种感光卤化银彩色感光材料,其感光成分层包括位于支撑物上的感蓝卤化银乳剂层、感绿卤化银乳剂层和感红卤化银乳剂层,其中感绿卤化银乳剂层和感红卤化银乳剂层中卤化银中溴化银的含量为5至65摩尔%,感绿卤化银乳剂层含有下式[I]所代表的至少一种化合物:
其中 X 代表卤素原子或可通过与显影剂的氧化产物发生偶联反应而消除的一价有机基团;R,至R3可以相同或不同,各自代表氢原子、卤素原子、烷基、环烷基、烯基、环烯基、炔基、芳基、杂环基、酰基、磺酰基、亚磺酰基、膦酰基、氨基甲酰基、氨基磺酰基、氰基、螺环化合物残基、桥接烃化合物残基、烷氧基、芳氧基、烯氧基、炔氧基、炔烃基、炔烃基、炔烃基、炔烃基、炔烃基、炔烃基、炔烃基、炔烃基、炔烃基、炔烃基、炔烃基、炔烃基、炔烃基、炔烃基、炔烃基、炔烃基、芳氧基、杂环氧基、硅氧基、酰氧基、氨基、酰氨基、磺酰胺基、酰亚胺基、 脲基、磺酰胺基、烷氧基羰基氨基、烷氧基羰基氨基、烷氧基羰基、芳氧基羰基、烷硫基、芳硫基或杂环硫基,但 R 至 R3 中至少有两个不是氢原子;R4 代表氢原子、烷基、芳基、杂环基、酰氨基、烷氨基、苯胺基、烷氧羰基或烷硫基。
根据本发明的感光卤化银彩色感光材料,可以进行快速显影处理,并在快速显影处理中提高处理稳定性,还可以节省银,同时抑制雾的产生,此外还可以获得耐光性良好的彩色图像。