N,N-dimethylcyclohexylamine bicarbonate | 1300857-36-6

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N,N-dimethylcyclohexylamine bicarbonate
• 英文别名: Cyclohexyl(dimethyl)azanium;hydrogen carbonate
• CAS: 1300857-36-6
• 化学式: CH₂O₃*C₈H₁₇N
• 分子量: 189.255
• InChiKey: CXSVORYHROOODB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.65
• 重原子数：
  13
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.89
• 拓扑面积：
  64.8
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  二氧化碳 、 N,N-二甲基环己胺 在 水 作用下， 反应 5.0h， 生成 N,N-dimethylcyclohexylamine bicarbonate
  参考文献：
  名称：

  Structure–function study of tertiary amines as switchable polarity solvents

  摘要：

  一系列三级胺已经进行了筛选，用作可切换极性溶剂（SPS）的功能。确定了三级胺和碳酸盐物种的相对比例以及最大可能浓度。已经确定了一种新形式的SPS，其胺：碳酸盐比显著大于单位。已确定N,N-二甲基-n-烷基胺结构对SPS的功能至关重要。

  DOI：

  10.1039/c3ra47724j

文献信息

• [EN] SWITCHABLE HYDROPHILICITY SOLVENTS AND METHODS OF USE THEREOF<br/>[FR] SOLVANTS COMMUTABLES ET LEURS PROCÉDÉS D'UTILISATION
  申请人：UNIV KINGSTON

  公开号：WO2011050469A1

  公开（公告）日：2011-05-05

  A solvent that reversibly converts from a hydrophobic liquid form to hydrophilic liquid form upon contact with water and a selected trigger, e.g., contact with CO2, is described. The hydrophilic liquid form is readily converted back to the hydrophobic liquid form and water. The hydrophobic liquid is an amidine or amine. The hydrophilic liquid form comprises an amidinium salt or an ammonium salt.

  描述了一种溶剂，当与水和选择的触发器（例如与CO2接触）接触时，可从疏水液态形式可逆地转变为亲水液态形式。亲水液态形式很容易转变回疏水液态形式和水。疏水液态是一种酰胺或胺。亲水液态形式包括酰胺盐或铵盐。
• Switchable Hydrophilicity Solvents and Methods of Use Thereof
  申请人：Jessop Philip G.

  公开号：US20110257334A1

  公开（公告）日：2011-10-20

  A solvent that reversibly converts from a hydrophobic liquid form to hydrophilic liquid form upon contact with water and a selected trigger, e.g., contact with CO 2 , is described. The hydrophilic liquid form is readily converted back to the hydrophobic liquid form and water. The hydrophobic liquid is an amidine or amine. The hydrophilic liquid form comprises an amidinium salt or an ammonium salt.

  描述了一种溶剂，当与水和选择的触发器（例如，与CO2接触）接触时，可从疏水液态形式可逆地转换为亲水液态形式。亲水液态形式很容易转换回疏水液态形式和水。疏水液体是一种酰胺或胺。亲水液态形式包括酰胺盐或铵盐。
• SWITCHABLE HYDROPHILICITY SOLVENTS AND METHODS OF USE THEREOF
  申请人：GreenCentre Canada

  公开号：US20140235908A1

  公开（公告）日：2014-08-21

  A solvent that reversibly converts from a hydrophobic liquid form to hydrophilic liquid form upon contact with water and a selected trigger, e.g., contact with CO 2 , is described. The hydrophilic liquid form is readily converted back to the hydrophobic liquid form and water. The hydrophobic liquid is an amidine or amine. The hydrophilic liquid form comprises an amidinium salt or an ammonium salt.

  描述了一种溶剂，它在与水和特定触发器（例如与CO2接触）接触时可逆地从疏水液体形式转变为亲水液体形式。亲水液体形式很容易转化回疏水液体形式和水。疏水液体是一种酰胺或胺。亲水液体形式包括酰胺盐或铵盐。
• Methods and systems for treating liquids using switchable solvents
  申请人：Wilson Aaron D.

  公开号：US10363336B2

  公开（公告）日：2019-07-30

  A method of treating a liquid. The method comprises providing a feed liquid comprising at least one solvent and at least one solute to a first side of a membrane. A single-phase draw solution comprising at least one of an aminium salt, an amidinium salt, and a guanidinium salt is provided to a second side of the membrane. The at least one solvent is osmosed across the membrane and into the single-phase draw solution to form a diluted single-phase draw solution. At least one of CO2, CS2, and COS is removed from the diluted single-phase draw solution to form a first multiple-phase solution comprising a first liquid phase comprising the at least one solvent, and a second liquid phase comprising at least one of an amine compound, an amidine compound, and a guanidine compound. A liquid purification system is also described.

  一种处理液体的方法。该方法包括向膜的第一侧提供由至少一种溶剂和至少一种溶质组成的进料液体。向膜的第二侧提供单相汲取溶液，该溶液包含铵盐、脒盐和胍盐中的至少一种。至少一种溶剂通过膜渗透到单相汲取液中，形成稀释的单相汲取液。从稀释的单相汲取溶液中去除 CO2、CS2 和 COS 中的至少一种，形成第一多相溶液，该溶液包括包含至少一种溶剂的第一液相，以及包含胺化合物、脒化合物和胍化合物中的至少一种的第二液相。还描述了一种液体纯化系统。
• METHOD OF SEPARATION EMPLOYING SWITCHABLE HYDROPHILICITY SOLVENTS
  申请人：Queen's University At Kingston

  公开号：EP2493849B1

  公开（公告）日：2021-12-08