p-cresyl phosphorodichloridite | 21719-85-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: p-cresyl phosphorodichloridite
• 英文别名: phosphorodichloridous acid p-tolyl ester；dichloro-p-tolyloxy-phosphine；Dichlor-p-tolyloxy-phosphin；Phosphorigsaeure-p-tolylester-dichlorid；Phosphorigsaeure-mono-p-tolylesterdichlorid；4-Methylphenoxydichlorphosphin；Phosphorodichloridous acid 4-methylphenyl ester；dichloro-(4-methylphenoxy)phosphane
• CAS: 21719-85-7
• 化学式: C₇H₇Cl₂OP
• 分子量: 209.012
• InChiKey: UCGNBRANESKILQ-UHFFFAOYSA-N

物化性质

• 沸点：
  118 °C(Press: 11 Torr)

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  11
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  p-cresyl phosphorodichloridite 在 磺酰氯 作用下， 以 四氯化碳 为溶剂， 生成 ethyl 4-methylphenyl chlorophosphate
  参考文献：
  名称：

  Maklyaev,F.L. et al., Journal of general chemistry of the USSR, 1962, vol. 32, p. 3357 - 3360

  摘要：

  DOI：
• 作为产物：
  描述：

  对甲酚 在 三氯化磷 作用下， 生成 p-cresyl phosphorodichloridite
  参考文献：
  名称：

  Strecker; Grossmann, Chemische Berichte, 1916, vol. 49, p. 75

  摘要：

  DOI：

文献信息

• Strecker; Grossmann, Chemische Berichte, 1916, vol. 49, p. 75
  作者：Strecker、Grossmann

  DOI：——

  日期：——
• Dismutation of Diamidoarylphosphites
  作者：Edward E. Nifantyev、Elena N. Rasadkina、Pavel V. Slitikov、Larisa K. Vasyanina

  DOI：10.1080/714040960

  日期：2003.11.1

  Some examples of spontaneous dismutation of diamidoarylphosphites in different solvents were studied, and features of the process were revealed.
• Dismutation of arylene phosphorodiamidites: Specific features and aspects of preparative use
  作者：E. N. Rasadkina、P. V. Slitikov、E. E. Nifant’ev

  DOI：10.1134/s1070363206020046

  日期：2006.2

  The dismutation ofarylene phosphorodiamidites derived from the simplest phenols and naphthols and of their dibasic analogs was studied. The main regular trends of this process and the limits of its synthetic applicability were determined.
• Ivanova,Zh.M., Journal of general chemistry of the USSR, 1964, vol. 34, # 3, p. 852 - 855
  作者：Ivanova,Zh.M.

  DOI：——

  日期：——
• ——
  作者：E. E. Nifant'ev、A. I. Zavalishina、E. I. Orzhekovskaya、N. M. Selezneva、L. K. Vasyanina、E. V. Vorontsov、A. I. Stash、V. K. Bel'skii

  DOI：10.1023/a:1015409231657

  日期：——

  A procedure was developed for preparing 4,5;7,8-dibenzo-1,3,2-diazaphosphocanes containing trivalent and pentavalent phosphorus atoms. The structure of the compounds was determined by NMR spectroscopy and single crystal X-ray diffraction. The conformational transitions of the diazaphosphocanes in solution were analyzed. First data were obtained on transformations of the obtained eight-membered heterocycles.