2-(苯基甲氧基甲基)萘 | 120375-98-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 中文名称: 2-(苯基甲氧基甲基)萘
• 英文名称: 2-((benzyloxy)methyl)naphthalene
• 英文别名: 2-(benzyloxymethyl)naphthalene；Naphthalene, 2-[(phenylmethoxy)methyl]-；2-(phenylmethoxymethyl)naphthalene
• CAS: 120375-98-6
• 化学式: C₁₈H₁₆O
• 分子量: 248.324
• InChiKey: ZODYAULMVLEVNV-UHFFFAOYSA-N

物化性质

• 沸点：
  384.4±11.0 °C(Predicted)
• 密度：
  1.111±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.2
• 重原子数：
  19
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  苄氧基三甲基硅烷 、 2-萘甲醛 在 三乙基硅烷 、 三氯化铁 作用下， 以 硝基甲烷 为溶剂， 反应 0.17h， 以95%的产率得到2-(苯基甲氧基甲基)萘
  参考文献：
  名称：

  氯化铁催化三乙基硅烷和烷氧基三甲基硅烷还原醚化羰基化合物的高效方法

  摘要：

  通过与三乙基硅烷和烷氧基三甲基硅烷在氯化铁 (III) 的催化下反应，可以方便地进行羰基化合物的还原性醚化。在温和的反应条件下，还原醇的相应烷基醚（包括苄基醚和烯丙基醚）以良好至极好的产率获得。

  DOI：

  10.1055/s-2004-834942

文献信息

• Reductive Etherification via Anion-Binding Catalysis
  作者：Chenfei Zhao、Christopher A. Sojdak、Wazo Myint、Daniel Seidel

  DOI：10.1021/jacs.7b05832

  日期：2017.8.2

  Reductive condensations of alcohols with aldehydes/ketones to generate ethers are catalyzed by a readily accessible thiourea organocatalyst that operates in combination with HCl. 1,1,3,3-tetramethyldisiloxane serves as a convenient reducing reagent. This strategy is applicable to challenging substrate combinations and exhibits functional group tolerance. Competing reductive homocoupling of the carbonyl

  醇与醛/酮的还原缩合生成醚是由易于获得的硫脲有机催化剂催化的，该催化剂与 HCl 结合使用。1,1,3,3-四甲基二硅氧烷用作方便的还原剂。该策略适用于具有挑战性的底物组合并表现出官能团耐受性。羰基组分的竞争性还原均偶联受到抑制。
• COMPOSITION, CURED PRODUCT AND LAMINATE
  申请人：DIC Corporation

  公开号：US20200109276A1

  公开（公告）日：2020-04-09

  An object of the invention is to provide a composition having excellent heat resistance and excellent adhesiveness. Moreover, another object is to provide a cured product obtained by curing the composition and a laminate containing the cured product. Furthermore, another object is to provide a heat-resistant material, a heat-resistant member, an electronic material and an electronic member each containing the composition. The objects are achieved by providing a composition including: a (meth)allyl group-containing maleimide compound having a structure having one or more benzene rings, one or more groups having a (meth)allyl group and one or more groups having a maleimide group; and a hydroxy group-containing maleimide compound having a structure having one or more benzene rings, one or more groups having a hydroxy group and one or more maleimide groups.
• [EN] PREPARING STERILE ARTICLES FROM CERTAIN POLYMERS<br/>[FR] FABRICATION D'ARTICLES STERILES A PARTIR DE CERTAINS POLYMERES
  申请人：OCCIDENTAL CHEM CO

  公开号：WO2002017973A2

  公开（公告）日：2002-03-07

  A method of preparing a sterile article is disclosed. An article is prepared from a polymer into which is incorporated a stabilizer having the general formula: where each A is independently selected from E, OR, SR, and CO-R, and can join the aromatic ring to form an additional ring, E is R or R(OCH2R'CH)n, G is E, CO-R, -C(E)H-O-R, C(OE)(H)-O-R, -C(E)(R')R''-OR, -C(E)(R')-R''-CO-OR, C(OE)(R')-E''-COOR, -C(OE)R''-O-R, -C(OE)HR, or -C(OE)R2, J is A, each R is independently selected from H, R', R''OR', R''COOR', R''C(OR')R', or R''C(OR')R''OR', each R' is independently selected from alkyl from C1 to C24, aryl from C6 to C24, alkaryl from C7 to C24, and aralkyl from C7 to C24, R' is H or R', R'' is alkylene from C1 to C24, arylene from C6 to C24, alkarylene from C7 to C24, or aralkylene from C7 to C24, m is 1 to 7, and n is 1 to 20. The article is exposed to gamma radiation; it yellows less after irradiation than it otherwise would.
• A Highly Efficient Method for the Reductive Etherification of Carbonyl Compounds with Triethylsilane and Alkoxytrimethylsilane Catalyzed by Iron(III) Chloride
  作者：Takeshi Oriyama、Katsuyuki Iwanami、Hana Seo、Yuki Tobita

  DOI：10.1055/s-2004-834942

  日期：——

  Facile reductive etherification of carbonyl compounds can be conveniently performed by reaction with triethylsilane and alkoxytrimethylsilane catalyzed by iron(III) chloride. The corresponding alkyl ethers, including benzyl and allyl ethers, of the reduced alcohols were obtained in good to excellent yields under mild reaction conditions.

  通过与三乙基硅烷和烷氧基三甲基硅烷在氯化铁 (III) 的催化下反应，可以方便地进行羰基化合物的还原性醚化。在温和的反应条件下，还原醇的相应烷基醚（包括苄基醚和烯丙基醚）以良好至极好的产率获得。