N~1~,N~1~-Bis(4-methoxyphenyl)-N~4~,N~4~-diphenylbenzene-1,4-diamine | 561329-62-2

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N~1~,N~1~-Bis(4-methoxyphenyl)-N~4~,N~4~-diphenylbenzene-1,4-diamine
• 英文别名: 4-N,4-N-bis(4-methoxyphenyl)-1-N,1-N-diphenylbenzene-1,4-diamine
• CAS: 561329-62-2
• 化学式: C₃₂H₂₈N₂O₂
• 分子量: 472.587
• InChiKey: GYBAIIWMTDYWLW-UHFFFAOYSA-N

物化性质

• 沸点：
  626.7±50.0 °C(Predicted)
• 密度：
  1.182±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  8.3
• 重原子数：
  36
• 可旋转键数：
  8
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  24.9
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  4,4'-二甲氧基二苯胺 、 4-溴三苯胺 在 tris-(dibenzylideneacetone)dipalladium(0) 、 三叔丁基膦 、 sodium t-butanolate 作用下， 以 甲苯 为溶剂， 反应 48.0h， 以86%的产率得到N~1~,N~1~-Bis(4-methoxyphenyl)-N~4~,N~4~-diphenylbenzene-1,4-diamine
  参考文献：
  名称：

  Multistate near-infrared electrochromism and electron transfer in different oligotriphenylamine systems

  摘要：

  Four oligomeric triarylamine compounds (diamine la, triamine lb, tetramine lc and pentamine 1d) were prepared and characterized by 1H NMR, mass spectrometry and elemental analysis. The combined results of cyclic voltammetry, square-wave voltammetry and UV vis NIR spectroelectrochemistry, as well as density functional theory, reveal that compounds la ld display two to five steps of oxidation processes, respectively, and the AE1/2 and Kc values were still remarkable for the relatively long pentamine, though they all decreased with an increase of the triphenylamine unit. These four compounds all exhibit fascinating redox-tuned multiple NIR absorption characteristics, and a completely reversible multicolor electrochromism for each of them could be synchronously realized. The associated mono cationic [1a]-[1d](+) could be classified as moderately-coupled Robin Day class H mixed-valence systems, which could be stabilized by spin delocalization over at least two adjacent amine units. (C) 2017 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2017.05.007

文献信息

• Composite material, light emitting element, light emitting device and electronic appliance using the composite material
  申请人：Semiconductor Energy Laboratory Co, Ltd.

  公开号：EP2423994A1

  公开（公告）日：2012-02-29

  A composite material includes an organic compound represented by the following general formula (2) and an inorganic compound, where, in the general formula (2), where in the general formula (2) X is selected from aromatic hydrocarbons represented by formulae (2-1) to (2-6) and R1 to R20 are identical or different from one another, and represent any of hydrogen, an alkyl group, an alkoxy group, an aryl group, and an arylalkyl group. A light emitting element includes the composite material and a light emitting device and an electronic appliance includes the light emitting element. The composite material has an excellent carrier transporting property and an excellent carrier injecting property with respect to the organic compound along with high visible light transmittance. By utilizing the composite material, a current excitation type light emitting element requiring low driving voltage and having excellent light emitting efficiency is obtained. By using the light emitting element, a light emitting device consuming low power and an electronic appliance including the light emitting device is provided.

  一种复合材料包括由以下通式（2）表示的有机化合物和无机化合物，其中，在通式（2）中，通式（2）中的X选自由式（2-1）至（2-6）表示的芳香烃，R1至R20彼此相同或不同，并代表氢、烷基、烷氧基、芳基和芳烷基中的任何一种。发光元件包括该复合材料，发光器件和电子设备包括该发光元件。相对于有机化合物而言，复合材料具有优异的载流子传输性能和优异的载流子注入性能，同时还具有较高的可见光透射率。利用这种复合材料，可以获得一种需要低驱动电压且发光效率极高的电流激发型发光元件。通过使用该发光元件，还可提供低功耗的发光器件和包括该发光器件的电子设备。
• Composite Material, Light Emitting Element, Light Emitting Device and Electronic Appliance Using the Composite Material
  申请人：Yamazaki Shunpei

  公开号：US20080136325A1

  公开（公告）日：2008-06-12

  A composite material includes an organic compound represented by the following general formula (1) and an inorganic compound, where, in the general formula (1), R 1 to R 24 is identical to or different from one another, and represent any of hydrogen, an alkyl group, an alkoxy group, an aryl group, and an arylalkyl group. A light emitting element includes the composite material and a light emitting device and an electronic appliance includes the light emitting element. The composite material has an excellent carrier transporting property and an excellent carrier injecting property with respect to the organic compound along with high visible light transmittance. By utilizing the composite material, a current excitation type light emitting element requiring low driving voltage and having excellent light emitting efficiency is obtained. By using the light emitting element, a light emitting device consuming low power and an electronic appliance including the light emitting device is provided.
• US8586197B2
  申请人：——

  公开号：US8586197B2

  公开（公告）日：2013-11-19
• Multistate near-infrared electrochromism and electron transfer in different oligotriphenylamine systems
  作者：Jing Zhang、Guotao Liu、Xiao-Yan Wang、Guang-Ao Yu、Jun Yin、Sheng-Hua Liu

  DOI：10.1016/j.dyepig.2017.05.007

  日期：2017.8

  Four oligomeric triarylamine compounds (diamine la, triamine lb, tetramine lc and pentamine 1d) were prepared and characterized by 1H NMR, mass spectrometry and elemental analysis. The combined results of cyclic voltammetry, square-wave voltammetry and UV vis NIR spectroelectrochemistry, as well as density functional theory, reveal that compounds la ld display two to five steps of oxidation processes, respectively, and the AE1/2 and Kc values were still remarkable for the relatively long pentamine, though they all decreased with an increase of the triphenylamine unit. These four compounds all exhibit fascinating redox-tuned multiple NIR absorption characteristics, and a completely reversible multicolor electrochromism for each of them could be synchronously realized. The associated mono cationic [1a]-[1d](+) could be classified as moderately-coupled Robin Day class H mixed-valence systems, which could be stabilized by spin delocalization over at least two adjacent amine units. (C) 2017 Elsevier Ltd. All rights reserved.