Oxalsaeure-methyl-(4-chlorphenylester) | 92403-47-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Oxalsaeure-methyl-(4-chlorphenylester)
• 英文别名: 2-O-(4-chlorophenyl) 1-O-methyl oxalate
• CAS: 92403-47-9
• 化学式: C₉H₇ClO₄
• 分子量: 214.605
• InChiKey: BQSXZHLGJCTMGY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  14
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  二氯甲氧基乙酸甲酯 、 对氯苯酚 生成 Oxalsaeure-methyl-(4-chlorphenylester)
  参考文献：
  名称：

  Ivashchenko,Ya.N. et al., Journal of general chemistry of the USSR, 1962, vol. 32, p. 3692 - 3695

  摘要：

  DOI：

文献信息

• Process for producing a diaryl carbonate
  申请人：UBE INDUSTRIES LIMITED

  公开号：EP0795539A1

  公开（公告）日：1997-09-17

  A diaryl carbonate with a high degree of purity is produced at a high yield by (A) subjecting (a) a diaryl oxalate and a phenol compound or (b) an alkylaryl oxalate to transesterification reaction in one or two stages in the presence of a catalyst to prepare a diaryl oxalate, while removing a by-product from the reaction system; (B) collecting the diaryl oxalate from the resultant reaction product mixture of the step (A); (C) subjecting the diaryl oxalate to a decarbonylation reaction, preferably in the presence of a phosphorous compound-containing catalyst, to convert the diaryl oxalate to a corresponding diaryl carbonate, while removing a reaction by-product comprising carbon monoxide from the reaction system; and (D) collecting the diaryl carbonate from the reaction product mixture of the step (C).

  高纯度碳酸二芳基酯的制备方法是：(A)在催化剂存在下，将(a)草酸二芳基酯和苯酚化合物或(b)草酸烷基芳基酯在一个或两个阶段中进行酯交换反应，制备草酸二芳基酯，同时从反应体系中除去副产物；(B)从步骤(A)的反应产物混合物中收集草酸二芳基酯；(C) 将草酸二芳基酯进行脱羰基反应，最好是在含磷化合物催化剂存在下进行，以将草酸二芳基酯转化为相应的碳酸二芳基酯，同时从反应体系中除去由一氧化碳组成的反应副产物；以及 (D) 从步骤(C)的反应产物混合物中收集碳酸二芳基酯。
• PROCESS FOR PREPARING DIARYL ESTERS OF OXALIC ACID
  申请人：UBE INDUSTRIES, LTD.

  公开号：EP0814074A1

  公开（公告）日：1997-12-29

  The present invention relates to a process for producing a diaryl oxalate, characterized in that an alkylaryl oxalate is subjected to a disproportionation reaction in the presence of a disproportionation catalyst, thereby to produce a diaryl oxalate while removing a by-product comprising a dialkyl oxalate. The production process of the present invention is advantageous in that the kinds of the by-products are fewer than that in conventional production process for diaryl oxalate, and thus can be practically utilized in industry, and the diaryl oxalates such as diphenyl oxalate, produced by the production process of the present invention are very important industrial materials for producing chemical products such as carbamates.

  本发明涉及一种草酸二芳基酯的生产工艺，其特征在于在歧化催化剂存在下，对草酸烷基芳基酯进行歧化反应，从而生产草酸二芳基酯，同时除去由草酸二烷基酯组成的副产品。 本发明生产工艺的优点在于副产品的种类比传统草酸二芳基酯生产工艺少，因此可在工业中实际利用，而且本发明生产工艺生产的草酸二芳基酯，如草酸二苯酯，是生产氨基甲酸酯等化工产品的非常重要的工业原料。
• US5731453A
  申请人：——

  公开号：US5731453A

  公开（公告）日：1998-03-24
• US6018072A
  申请人：——

  公开号：US6018072A

  公开（公告）日：2000-01-25
• Ivashchenko,Ya.N. et al., Journal of general chemistry of the USSR, 1962, vol. 32, p. 3692 - 3695
  作者：Ivashchenko,Ya.N. et al.

  DOI：——

  日期：——