1-n-butyl-3-methylimidazolium (2,4-dichlorophenoxy)acetate | 1379462-03-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-n-butyl-3-methylimidazolium (2,4-dichlorophenoxy)acetate
• 英文别名: 1-Butyl-3-methylimidazol-3-ium;2-(2,4-dichlorophenoxy)acetate；1-butyl-3-methylimidazol-3-ium;2-(2,4-dichlorophenoxy)acetate
• CAS: 1379462-03-9
• 化学式: C₈H₅Cl₂O₃*C₈H₁₅N₂
• 分子量: 359.252
• InChiKey: HBASMNHGSCWXMP-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  2.23
• 重原子数：
  23
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.38
• 拓扑面积：
  58.2
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  2,4-二氯苯氧乙酸 、 alkaline earth salt of/the/ methylsulfuric acid 在 Dowex-Monosphere 550A (OH) anion exchange resin 作用下， 反应 0.17h， 以90%的产率得到1-n-butyl-3-methylimidazolium (2,4-dichlorophenoxy)acetate
  参考文献：
  名称：

  2,4-D based herbicidal ionic liquids

  摘要：

  Herbicidal ionic liquids (HILs) with a 2,4-D anion were synthesized and characterized. These salts have chemical and thermal stability. HILs exhibited higher biological activity than currently used salts of 2,4-D. HILs are nonvolatile and showed substantially lower water solubility than starting herbicides. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2012.03.065

文献信息

• 2,4-D based herbicidal ionic liquids
  作者：Juliusz Pernak、Anna Syguda、Katarzyna Materna、Ewa Janus、Przemysław Kardasz、Tadeusz Praczyk

  DOI：10.1016/j.tet.2012.03.065

  日期：2012.6

  Herbicidal ionic liquids (HILs) with a 2,4-D anion were synthesized and characterized. These salts have chemical and thermal stability. HILs exhibited higher biological activity than currently used salts of 2,4-D. HILs are nonvolatile and showed substantially lower water solubility than starting herbicides. (C) 2012 Elsevier Ltd. All rights reserved.