(Z)-(1,2-diphenylvinyl)triethylgermane | 869795-36-8

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: (Z)-(1,2-diphenylvinyl)triethylgermane
• 英文别名: (Z)-triethyl(1,2-diphenylethenyl)germane；PhCHCPhGeEt3；[(Z)-1,2-diphenylethenyl]-triethylgermane
• CAS: 869795-36-8
• 化学式: C₂₀H₂₆Ge
• 分子量: 339.016
• InChiKey: JWIFQVZGBIWLJK-JZJYNLBNSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.27
• 重原子数：
  21
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.3
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  三乙基氯化锗 在 三(五氟苯基)硼烷 、 仲丁基锂 作用下， 以 四氢呋喃 、 环己烷 为溶剂， 反应 6.5h， 生成 (Z)-(1,2-diphenylvinyl)triethylgermane
  参考文献：
  名称：

  Access to Fully Alkylated Germanes by B(C₆F₅)₃-Catalyzed Transfer Hydrogermylation of Alkenes

  摘要：

  Various cyclohexa-2,5-dien-1-yl-substituted germanes are shown to serve as easy-to-handle surrogates of hydrogermanes, including gaseous MeGeH3 and Me2GeH2; The Ge-H functional group is liberated by treatment with catalytic amounts of B(C6F5)(3) and participates in situ in the B(C6F5)(3)-catalyzed hydrogermylation of alkenes. The range of suitable alkenes is broad, and the overall procedure provides a convenient access to tetraalkyl-substituted germanes at room temperature. Transfer hydrogermylation of internal alkynes works equally well and selectively forms the trans or cis diastereomer depending on the electronic bias of the C C bond.

  DOI：

  10.1021/acs.orglett.7b00672

文献信息

• Trans-selective hydrogermylation of alkynes promoted by methyliron and bis(germyl)hydridoiron complexes as a catalyst precursor
  作者：Masumi Itazaki、Masahiro Kamitani、Hiroshi Nakazawa

  DOI：10.1039/c1cc12530c

  日期：——

  internal alkynes was attained by a methyliron complex, CpFe(CO)(2)(Me), and a bis(germyl)hydridoiron(IV) complex as a catalyst precursor. The structures of (Z)-triphenyl-(2-phenylethenyl)germane and the bis(germyl)hydridoiron(IV) complexes CpFe(CO)(H)(GeR(3))(2) (R = Et, Ph) were confirmed by single crystal X-ray diffraction studies.

  末端和内部炔烃的催化反式选择性加氢羟甲基化反应是通过甲基铁络合物，CpFe（CO）（2）（Me）和作为催化剂前体的双（锗基）氢化铁（IV）络合物实现的。（Z）-三苯基-（2-苯基乙烯基）锗烷和双（锗烷基）氢化铁（IV）配合物CpFe（CO）（H）（GeR（3））（2）的结构为（R = Et，Ph）单晶X射线衍射研究证实。
• Access to Fully Alkylated Germanes by B(C₆F₅)₃-Catalyzed Transfer Hydrogermylation of Alkenes
  作者：Sebastian Keess、Martin Oestreich

  DOI：10.1021/acs.orglett.7b00672

  日期：2017.4.7

  Various cyclohexa-2,5-dien-1-yl-substituted germanes are shown to serve as easy-to-handle surrogates of hydrogermanes, including gaseous MeGeH3 and Me2GeH2; The Ge-H functional group is liberated by treatment with catalytic amounts of B(C6F5)(3) and participates in situ in the B(C6F5)(3)-catalyzed hydrogermylation of alkenes. The range of suitable alkenes is broad, and the overall procedure provides a convenient access to tetraalkyl-substituted germanes at room temperature. Transfer hydrogermylation of internal alkynes works equally well and selectively forms the trans or cis diastereomer depending on the electronic bias of the C C bond.