bis(diisobutyldithiophosphinato)nickel(II) | 83053-11-6

• 分子结构分类: 有机化合物 - 有机磷化合物 - 有机硫代磷化合物
• 英文名称: bis(diisobutyldithiophosphinato)nickel(II)
• 英文别名: Ni(iso-Bu2PS2)2；Nickel (II) bis(diisobutyldithiophosphinate)；bis(2-methylpropyl)-sulfanylidene-sulfido-λ5-phosphane;nickel(2+)
• CAS: 83053-11-6
• 化学式: C₁₆H₃₆NiP₂S₄
• 分子量: 477.363
• InChiKey: LLHLNSSKORWSHT-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  6.48
• 重原子数：
  23
• 可旋转键数：
  8
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  66.2
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  bis(diisobutyldithiophosphinato)nickel(II) 以 neat (no solvent) 为溶剂， 生成 nickel(II) sulfide 、 nickel phosphide
  参考文献：
  名称：

  Thermoanalytical and mass spectrometric study of Ni(iso-Bu2PS2)2 and NiL(iso-Bu2PS2)2 (L = 2,2′-Bipy, Phen). Saturation vapor pressure over the Ni(iso-Bu2PS2)2 chelate

  摘要：

  The thermal behaviors of the chelate Ni(iso-Bu2PS2)(2) (I) and the mixed-ligand complexes Ni(2,2'-Bipy)(iso-Bu2PS2)(2) (II) and Ni(Phen)(iso-Bu2PS2)(2) (III) in air are reported. These compounds can pass into the gas phase, as was demonstrated by vacuum sublimation for I and by vacuum distillation for II and III in a gradient furnace. The mass spectra of I-III are presented and discussed. The temperature dependence of the saturation vapor pressure over I and Delta H-T(0) and Delta S-T(0) of evaporation of I determined by the vapor transport method are reported.

  DOI：

  10.1134/s0036023610090172
• 作为产物：
  描述：

  ((.)S2P(i-Bu2))Ni(S2P(i-Bu)2)2 以 乙腈 为溶剂， 生成 bis(diisobutyldithiophosphinato)nickel(II)
  参考文献：
  名称：

  Spectroscopy and kinetics of dithiophosphinate radicals coordinated with dithiophosphinate Ni(II) complex

  摘要：

  The laser flash photolysis was used to study the mechanism of photochromic transformations for solutions of phosphinate disulfide ((S2P(i-Bu)(2))(2) equivalent to (S2PR2)(2)) and Ni(S2P(i-Bu)(2))(2)(Ni(S2PR2)(2)) complex in acetonitrile. Under the excitation of an XeCl excimer laser (308 nm), this system manifests transient absorption in the visible and UV ranges which vanishes over a millisecond time domain. The cycle of phototransformations can be repeated without degradation of the optical spectrum of the solution. The process is initiated by photodissociation of a disulfide molecule into two S-radicals ((S2P)-S-.(i-Bu)(2) equivalent to (S2PR2)-S-.). The radical with a constant of 2.5 x 10(9) M-1 s(-1) enters the coordination sphere of Ni(S2PR2)(2) complex to form the radical complex (R2PS2.)Ni(S2PR2)(2). When analyzing the kinetics of changes in the optical density of transient absorption, it is assumed that coordination of the second radical with a constant of 1.5 x 10(10) M-1 s(-1) results in the formation of the secondary or biradical complex (R2PS2.)(2)Ni(S2PR2)(2). The radical complexes dissociate with a radical escaping from the coordination sphere with rate constants equal to 7.5 x 10(3) s(-1) and 7 x 10(2) s(-1) for mono- and biradical particles, respectively. As a result. the system regains its initial state due to recombination of (S2PR2)-S-. radicals into initial disulfide. (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0301-0104(03)00065-x

文献信息

• LIGAND EXCHANGE THERMOCHROMIC SYSTEMS AND HIGH E LIGANDS FOR SAME
  申请人：Byker J. Harlan

  公开号：US20080105851A1

  公开（公告）日：2008-05-08

  Ligand exchange of thermochromic, LETC, systems exhibiting a reversible change in absorbance of electromagnetic radiation as the temperature of the system is reversibly changed are described. The described LETC systems include one or more than one transition metal ion, which experiences thermally induced changes in the nature of the complexation or coordination around the transition metal ion(s) and, thereby, the system changes its ability to absorb electromagnetic radiation as the temperature changes. In accordance with certain aspects of the present invention, a thermochromic system is disclosed comprising a transition metal ion and a ligand wherein the ligand comprises a nitrogen-containing five or six membered heterocyclic compound that coordinates through the nitrogen atom to the transition metal ion in a HεMLC formed between the transition metal ion and the ligand. In accordance with other aspects of the present invention, thermochromic systems are disclosed comprising a transition metal ion with particularly useful ligands, such as phosphine compounds, tridentate ligands that coordinate through three nitrogen atoms, bidentate ligands, or ortho hindered pyridine monodentate ligands.

  本文描述了具有热致变色性质的配体交换（LETC）系统，当系统的温度可逆变化时，电磁辐射吸收率也可逆变化。所述的LETC系统包括一个或多个过渡金属离子，其经历热诱导的配位或配位环境的变化，从而使系统随着温度变化而改变吸收电磁辐射的能力。根据本发明的某些方面，公开了包括过渡金属离子和配体的热致变色系统，其中配体包括通过氮原子与过渡金属离子形成的HεMLC（配体与过渡金属离子之间的配位键）的含氮五元或六元杂环化合物。根据本发明的其他方面，公开了包括具有特别有用的配体的过渡金属离子的热致变色系统，例如膦化合物、通过三个氮原子配位的三齿配体、双齿配体或邻位受阻的吡啶单齿配体。
• LIGAND EXCHANGE THERMOCHROMIC, (LETC), SYSTEMS
  申请人：Byker J. Harlan

  公开号：US20080100902A1

  公开（公告）日：2008-05-01

  Ligand exchange of thermochromic, LETC, systems exhibiting a reversible change in absorbance of electromagnetic radiation as the temperature of the system is reversibly changed are described. The described LETC systems include one or more than one transition metal ion, which experiences thermally induced changes in the nature of the complexation or coordination around the transition metal ion(s) and, thereby, the system changes its ability to absorb electromagnetic radiation as the temperature changes.

  本文介绍了一种热致变色（LETC）系统的配体交换方法，该系统在温度可逆变化时显示出电磁辐射吸收的可逆变化。所述LETC系统包括一个或多个过渡金属离子，其在过渡金属离子周围的配位或络合性质发生热诱导变化，从而使系统在温度变化时改变吸收电磁辐射的能力。
• Ligand exchange thermochromic systems and high ε ligands for same
  申请人：Pleotint, L.L.C.

  公开号：US08182718B2

  公开（公告）日：2012-05-22

  Ligand exchange of thermochromic, LETC, systems exhibiting a reversible change in absorbance of electromagnetic radiation as the temperature of the system is reversibly changed are described. The described LETC systems include one or more than one transition metal ion, which experiences thermally induced changes in the nature of the complexation or coordination around the transition metal ion(s) and, thereby, the system changes its ability to absorb electromagnetic radiation as the temperature changes. In accordance with certain aspects of the present invention, a thermochromic system is disclosed comprising a transition metal ion and a ligand wherein the ligand comprises a nitrogen-containing five or six membered heterocyclic compound that coordinates through the nitrogen atom to the transition metal ion in a HεMLC formed between the transition metal ion and the ligand. In accordance with other aspects of the present invention, thermochromic systems are disclosed comprising a transition metal ion with particularly useful ligands, such as phosphine compounds, tridentate ligands that coordinate through three nitrogen atoms, bidentate ligands, or ortho hindered pyridine monodentate ligands.

  描述了具有可逆吸收电磁辐射的变色性质的热致变色(LETC)系统的配体交换。所述的LETC系统包括一个或多个过渡金属离子，其在温度可逆变化时经历热诱导的配合物或配位环境的变化，因此系统随着温度变化而改变其吸收电磁辐射的能力。根据本发明的某些方面，公开了包括过渡金属离子和配体的热致变色系统，其中配体包括通过氮原子与过渡金属离子形成的HεMLC的含氮五元或六元杂环化合物。根据本发明的其他方面，公开了包括具有特别有用的配体的过渡金属离子的热致变色系统，例如膦化合物、通过三个氮原子配位的三齿配体、双齿配体或邻位受阻的吡啶单齿配体。
• Ligand exchange thermochromic, (LETC), systems
  申请人：Byker Harlan J.

  公开号：US09011734B2

  公开（公告）日：2015-04-21

  Ligand exchange of thermochromic, LETC, systems exhibiting a reversible change in absorbance of electromagnetic radiation as the temperature of the system is reversibly changed are described. The described LETC systems include one or more than one transition metal ion, which experiences thermally induced changes in the nature of the complexation or coordination around the transition metal ion(s) and, thereby, the system changes its ability to absorb electromagnetic radiation as the temperature changes.

  本文描述了一种热致变色（LETC）系统的配体交换，该系统在可逆改变温度时展现出电磁辐射吸收的可逆变化。所述的LETC系统包括一个或多个过渡金属离子，其在过渡金属离子周围的络合或配位性质发生热诱导变化，从而随着温度的变化，系统改变其吸收电磁辐射的能力。
• ——
  作者：S. V. Larionov、T. E. Kokina、L. A. Glinskaya、R. F. Klevtsova

  DOI：10.1023/a:1011341716651

  日期：——

  Diamagnetic [Ni(i-Bu2PS2)(2)] compound (I) in ethanol reacts with 2,2 ' -bipyridine or pyrazine to give the paramagnetic complexes [Ni(2,2 ' -Bipy)(i-Bu2PS2)(2)] (II), [Ni(Pz)(2)(i-Bu2PS2)(2)] (III), and [Ni(Pz)(i-Bu2PS2)(2)](n) (IV) (mu (eff) = 2.91-3.12 mu (B)). Single crystals of II were grown for X-ray diffraction study. The crystals are monoclinic, a = 14.669(3) Angstrom, b = 19.693(4) Angstrom, c = 12.155(2) Angstrom, beta = 107.51(3)degrees, V= 3348(1) Angstrom (3), Z = 4; rho (calcd) = 1.257 g/cm(3), space group P2(1)/c. The structure is built from monomeric molecules. The coordination polyhedron of the Ni atom is a distorted octahedron formed by four S atoms of two bidentate chelating i-BU2PS2- ligands and by two N atoms of bidentate cyclic 2,2 ' -Bipy. Preliminary data for complexes III and IV indicate that they also contain an octahedral NiN2S4 fragment. The structures of complexes I (square planar) and of II-IV (octahedral) were confirmed by data from electron spectroscopy. Electronic absorption spectra were used to determine the rankings of the i-Bu2PS2- ions and Pz on a spectrochemical scale.