The intricate paramagnetic state of [Os(Q)2(bpy)]+, Q = 4,6-di-tert-butyl-o-iminobenzoquinone
作者:Dipanwita Das、Thomas Michael Scherer、Amit Das、Tapan Kumar Mondal、Shaikh M. Mobin、Jan Fiedler、José Luis Priego、Reyes Jiménez-Aparicio、Wolfgang Kaim、Goutam Kumar Lahiri
DOI:10.1039/c2dt30903c
日期:——
third-row transition metal produces the title complex ion which was crystallised as [Os(Q)2(bpy)](ClO4)·C6H6 (Q = 4,6-di-tert-butyl-o-iminobenzoquinones, bpy = 2,2′-bipyridine) and could be structurally characterised to exhibit a tris-chelate situation at the metal with trans-positioned N and cis-positioned O donor atoms. The metrical ligand parameters are in agreement with two partially reduced ligands