allyl 3,4-epoxycyclohexane-1-carboxylate | 19900-47-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 氧杂环己烷
• 英文名称: allyl 3,4-epoxycyclohexane-1-carboxylate
• 英文别名: Prop-2-en-1-yl 7-oxabicyclo[4.1.0]heptane-3-carboxylate；prop-2-enyl 7-oxabicyclo[4.1.0]heptane-3-carboxylate
• CAS: 19900-47-1
• 化学式: C₁₀H₁₄O₃
• 分子量: 182.219
• InChiKey: WRGWYAZIVRHPFP-UHFFFAOYSA-N

物化性质

• 沸点：
  91-95 °C(Press: 2 Torr)
• 密度：
  1.0947 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  1.3
• 重原子数：
  13
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.7
• 拓扑面积：
  38.8
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  allyl 3,4-epoxycyclohexane-1-carboxylate 、 三乙氧基硅烷 在 铂(0)-1,3-二乙烯-1,1,3,3-四甲基二硅氧烷 作用下， 以 异丙醇 、 甲苯 为溶剂， 反应 10.0h， 以31%的产率得到3-(3,4-epoxycyclohexane-1-carboxylic acid)propyltriethoxysilane
  参考文献：
  名称：

  EPOXYSILICONE CONDENSATE, CURABLE COMPOSITION COMPRISING CONDENSATE, AND CURED PRODUCT THEREOF

  摘要：

  提供一种含环氧基硅烷缩合物，其产物具有优异的透明性、耐热性和气体阻隔性能的环氧基硅烷缩合物。一种环氧硅烷缩合物，是由式（1）所代表的含环氧基硅烷化合物的水解缩合产物：和式（2）所代表的硅烷化合物：Si（OR12）mR134-m（2）其中当含环氧基硅烷化合物（1）的摩尔数为x，硅烷化合物（2）的摩尔数为y时，0.2≦my/nx≦0.7，包括该缩合物的可固化组合物，以及该组合物的固化产物。

  公开号：

  US20130137795A1
• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 过氧乙酸 、 乙酸乙酯 作用下， 生成 allyl 3,4-epoxycyclohexane-1-carboxylate
  参考文献：
  名称：

  Synthesis of Some Epoxy Vinyl Monomers by Epoxidation with Peracetic Acid¹

  摘要：

  DOI：

  10.1021/ja01522a048

文献信息

• Epoxy compound and process for producing the epoxy compound
  申请人：Arai Yoshikazu

  公开号：US08426614B2

  公开（公告）日：2013-04-23

  An object of the present invention is to provide an epoxy compound which has a quick curing rate and is excellent in an etching durability and a selectivity and which is liquid at room temperature and a process for producing the above epoxy compound. The epoxy compound of the present application is represented by Formula (I): (YSiO3/2)n  (I) (in Formula (I), p (p is a natural number equal to n or less) groups of Y out of n groups thereof represent specific groups, and (n−p) groups of Y represent a hydrogen atom or —OSiR12H; and n represents an integer of 2 to 500).

  本发明的目的是提供一种具有快速固化速度、在蚀刻耐久性和选择性方面表现出色、并在室温下为液态的环氧化合物以及制备上述环氧化合物的方法。本申请的环氧化合物由式（I）表示：(YSiO3/2)n  (I)（在式（I）中，n个中的p个Y（p是小于或等于n的自然数）代表特定的基团，而（n-p）个Y代表氢原子或—OSiR12H；n表示2至500的整数）。
• LUBRICANT COMPOSITION
  申请人：JX NIPPON OIL & ENERGY CORPORATION

  公开号：US20150252281A1

  公开（公告）日：2015-09-10

  The present invention provides a lubricating oil composition comprising a lubricating base oil, and at least one ester additive selected from a first ester that is a fatty acid 3,4-epoxycyclohexyl alkyl ester and a second ester that is a 3,4-epoxycyclohexyl carboxylic acid alkyl ester, wherein a content of the ester additive is 0.01 to 5.0% by mass based on the total mass of the lubricating oil composition.

  本发明提供了一种润滑油组合物，包括润滑基础油和至少一种酯类添加剂，所述酯类添加剂选自第一种酯类，即脂肪酸3,4-环氧基环己基烷基酯和第二种酯类，即3,4-环氧基环己酸烷基酯，其中酯类添加剂的含量为润滑油组合物总质量的0.01至5.0%。
• CONDUCTIVE ADHESIVE, ANISOTROPIC CONDUCTIVE FILM AND ELECTRONIC DEVICES USING BOTH
  申请人：SHOWA DENKO K.K.

  公开号：US20160060490A1

  公开（公告）日：2016-03-03

  [Problem] To provide: a conductive adhesive which contains an epoxy (meth)acrylate resin and which can form a bonded zone that is not susceptible to being deteriorated by halogen; an anisotropic conductive film; and electronic devices using both. [Solution] A conductive adhesive and an anisotropic conductive film which each contain a conductive filler and a binder resin, wherein: the binder resin comprises an epoxy (meth)acrylate resin that is a product of addition reaction of (meth)acrylic acid and an epoxy compound having a sum of total chlorine atom concentration and total bromine atom concentration of 300 massppm or less, preferably 50 massppm or less; and the conductive filler is dispersed in the binder resin which comprises such an epoxy (meth)acrylate resin. The epoxy (meth)acrylate resin is preferably prepared by subjecting a starting compound (substrate) having a carbon-carbon double bond to epoxidation of the double bond with an oxidizing agent consisting of hydrogen peroxide, and then subjecting the obtained epoxy compound to addition reaction with (meth)acrylic acid.

  [问题] 提供一种导电粘合剂，其中包含环氧（甲基）丙烯酸酯树脂，可以形成一个不容易被卤素恶化的粘合区域；一种各向异性导电膜；以及同时使用两种的电子设备。 [解决方案] 一种导电粘合剂和一种各向异性导电膜，它们各自包含导电填料和粘合剂树脂，其中：粘合剂树脂包括环氧（甲基）丙烯酸酯树脂，是由（甲基）丙烯酸和总氯原子浓度和总溴原子浓度之和小于300质量ppm，优选小于50质量ppm的环氧化合物进行加成反应制得的；导电填料分散在包含这种环氧（甲基）丙烯酸酯树脂的粘合剂树脂中。环氧（甲基）丙烯酸酯树脂最好是通过将具有碳-碳双键的起始化合物（基质）经过过氧化氢的双键环氧化，然后将所得到的环氧化合物与（甲基）丙烯酸进行加成反应制备而成。
• PROCESS FOR PRODUCTION OF EPOXY COMPOUND
  申请人：Showa Denko K.K.

  公开号：EP2261219A1

  公开（公告）日：2010-12-15

  A novel process for producing a polyfunctional epoxy monomer is provided that facilitates separation of an aqueous layer catalyst from a reaction solution and has satisfactory hydrogen peroxide efficiency by reacting an aqueous hydrogen peroxide solution with a polyolefin without using an organic solvent and under mild conditions. The process as claimed in the present invention is a process for producing a corresponding epoxy compound by reacting an organic compound having a carbon-carbon double bond with hydrogen peroxide present in an aqueous hydrogen peroxide solution to epoxidate the double bond, wherein a tungsten compound and tertiary amine are used as reaction catalysts.

  本发明提供了一种生产多官能团环氧单体的新工艺，该工艺通过过氧化氢水溶液与聚烯烃在不使用有机溶剂和温和的条件下进行反应，便于从反应溶液中分离水层催化剂，并具有令人满意的过氧化氢效率。 本发明所述的工艺是通过使具有碳碳双键的有机化合物与存在于过氧化氢水溶液中的过氧化氢反应，使双键环氧化，从而生产相应的环氧化合物的工艺，其中使用钨化合物和叔胺作为反应催化剂。
• EPOXY-GROUP-CONTAINING COPOLYMER, EPOXY (METH)ACRYLATE COPOLYMER USING SAME, AND PROCESSES FOR PRODUCING THE COPOLYMERS
  申请人：Showa Denko K.K.

  公开号：EP2314634A1

  公开（公告）日：2011-04-27

  According to the present invention, a novel epoxy group-containing copolymer, including a production process thereof, and an epoxy (meth)acrylate copolymer starting from the epoxy group-containing copolymer, including a production process thereof are provided. The epoxy group-containing copolymer of the present invention contains a specific epoxy group-containing repeating unit and an olefin-based repeating unit. A novel epoxy (meth)acrylate copolymer of the present invention is produced by reacting the epoxy group-containing copolymer with (meth)acrylic acid.

  根据本发明，提供了一种新型含环氧基的共聚物，包括其生产工艺，以及一种以该含环氧基的共聚物为原料的环氧（甲基）丙烯酸酯共聚物，包括其生产工艺。本发明的含环氧基共聚物含有特定的含环氧基重复单元和烯烃基重复单元。本发明的新型环氧（甲基）丙烯酸酯共聚物是通过含环氧基的共聚物与（甲基）丙烯酸反应制得的。