4-[2 (triethoxysilyl) ethyl] triphenylamine | 190334-72-6

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 4-[2 (triethoxysilyl) ethyl] triphenylamine
• 英文别名: Benzenamine, N,N-diphenyl-4-[2-(triethoxysilyl)ethyl]-；N,N-diphenyl-4-(2-triethoxysilylethyl)aniline
• CAS: 190334-72-6
• 化学式: C₂₆H₃₃NO₃Si
• 分子量: 435.638
• InChiKey: OCUVZYLUHWVCCK-UHFFFAOYSA-N

物化性质

• 沸点：
  501.1±43.0 °C(Predicted)
• 密度：
  1.069±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.75
• 重原子数：
  31
• 可旋转键数：
  12
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.31
• 拓扑面积：
  30.9
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  三乙氧基硅烷 、 N,N-二苯基-4-乙烯基苯胺 以 甲苯 为溶剂， 生成 4-[2 (triethoxysilyl) ethyl] triphenylamine
  参考文献：
  名称：

  Method of manufacturing a polysiloxane charge transporting material

  摘要：

  公开号：

  EP0771809B1

文献信息

• Method of manufacturing a silicon-type charge transporting material
  申请人：Dow Corning Asia, Ltd.

  公开号：US05688961A1

  公开（公告）日：1997-11-18

  A method of manufacturing charge transporting materials which impart a charge transporting property to a polysiloxane resin, and which is soluble in the resin. The charge transporting material is an aromatic substituted tertiary amine with a plurality of aromatic groups, and a silyl group introduced via a hydrocarbon group, into at least one of the aromatic groups. The method is characterized by using an unsaturated aliphatic group bonded to an aromatic group which makes up the silicon-type charge transporting compound, or using a newly bonded unsaturated aliphatic group which is bonded to a silane in which the substituent for silicon is hydrogen or a hydrolyzable group. This is conducted in the presence of a platinum compound as catalyst by means of hydrosilylation. The silicon-type charge transporting material is then brought into contact with an adsorbent for the platinum compound, causing the platinum compound to be adsorbed onto the adsorbent. The platinum compound is removed along with the adsorbent, so that the concentration of residual platinum compound is less than 10 ppm.

  一种制造电荷传输材料的方法，该材料赋予聚硅氧烷树脂电荷传输性能，并且能够溶解在树脂中。电荷传输材料是一种含有多个芳香基团的芳基取代的三级胺，且通过碳氢基引入了一个硅基团，至少其中一个芳香基团中。该方法的特点在于，使用与构成硅型电荷传输化合物的芳香基团结合的不饱和脂肪基，或者使用新结合的与硅烷键合的不饱和脂肪基，其中硅的取代基是氢或可水解基。这是通过氢硅烷化反应，在铂化合物的存在下进行的。然后，将硅型电荷传输材料与铂化合物的吸附剂接触，使铂化合物被吸附到吸附剂上。然后将铂化合物与吸附剂一起移除，以使残留的铂化合物浓度小于10 ppm。
• Silicon containing charge transport compounds
  申请人：DOW CORNING ASIA, Ltd.

  公开号：EP0771806B1

  公开（公告）日：2002-02-27
• Method of manufacturing a cohydrolyzed polysiloxane charge transporting material
  申请人：DOW CORNING ASIA, Ltd.

  公开号：EP0771808B1

  公开（公告）日：2002-05-08
• Method of manufacturing a polysiloxane charge transporting material
  申请人：DOW CORNING ASIA, Ltd.

  公开号：EP0771809B1

  公开（公告）日：2003-04-02