1,5-(selenium)2(sulfur)6 | 75926-21-5

• 分子结构分类: 无机化合物 - 均质非金属化合物 - 其他非金属有机物
• 英文名称: 1,5-(selenium)2(sulfur)6
• 英文别名: 1,5-Se2S6；1,2,3,5,6,7,4,8-Hexathiadiselenocane
• CAS: 75926-21-5
• 化学式: S₆Se₂
• 分子量: 350.316
• InChiKey: XHXZYRZXIYIDIG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.13
• 重原子数：
  8
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  152
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  1,2-S6Se2 以 二硫化碳 为溶剂， 生成 庚硫杂硒杂环辛烷 、 1,5-(selenium)2(sulfur)6 、 1,4-(selenium)2(sulfur)6 、 1,3-(selenium)2(sulfur)6 、 1,2,3-Se3S5
  参考文献：
  名称：

  Chalcogenospecific Synthesis of 1,2-Se2S6 Using ZnS6(TMEDA)

  摘要：

  The recently reported hexasulfido complex ZnS6(TMEDA) is a potent polysulfide transfer agent as demonstrated by its ability to convert (C5H5)(2)TiCl2 into (C5H5)(2)-TiS5. More interesting is the use of the zinc complex to transfer an intact. S-6 Unit as established with the ''chalcogenospecific'' synthesis of 1,2-Se2S6. 1,2-Se2S6 is a rare example of easily prepared stable sulfur selenide available in isomeric purity.

  DOI：

  10.1021/ic00128a035

文献信息

• Maaninen, Arto; Chivers, Tristram; Parvez, Masood, Inorganic Chemistry, 1999, vol. 38, # 18, p. 4093 - 4097
  作者：Maaninen, Arto、Chivers, Tristram、Parvez, Masood、Pietikaeinen, Jarkko、Laitinen, Risto S.

  DOI：——

  日期：——
• 77Se-NMR and raman spectroscopic characterization of selenium dibromide (SeBr2) and its reaction with titanocene pentasulphide to give cyclic selenium sulphides of ring size 6, 7, 8, and 12
  作者：Ralf Steudel、Detlef Jensen、Frank Baumgart

  DOI：10.1016/s0277-5387(00)86896-5

  日期：1990.1
• Laitinen, Risto S.; Pakkanen, Tapani A., Inorganic Chemistry, 1987, vol. 26, # 16, p. 2598 - 2603
  作者：Laitinen, Risto S.、Pakkanen, Tapani A.

  DOI：——

  日期：——
• Chivers, Tristram; Laitinen, Risto S.; Schmidt, Kenneth J., Canadian Journal of Chemistry, 1992, vol. 70, # 3, p. 719 - 725
  作者：Chivers, Tristram、Laitinen, Risto S.、Schmidt, Kenneth J.

  DOI：——

  日期：——
• Chalcogenospecific Synthesis of 1,2-Se2S6 Using ZnS6(TMEDA)
  作者：Atul K. Verma、Thomas B. Rauchfuss

  DOI：10.1021/ic00128a035

  日期：1995.11

  The recently reported hexasulfido complex ZnS6(TMEDA) is a potent polysulfide transfer agent as demonstrated by its ability to convert (C5H5)(2)TiCl2 into (C5H5)(2)-TiS5. More interesting is the use of the zinc complex to transfer an intact. S-6 Unit as established with the ''chalcogenospecific'' synthesis of 1,2-Se2S6. 1,2-Se2S6 is a rare example of easily prepared stable sulfur selenide available in isomeric purity.