牛津郡克蔓磷 | 56362-05-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 牛津郡克蔓磷
• 中文别名: 抑草磷-OXON
• 英文名称: Butamifos oxon
• 英文别名: N-[ethoxy-(5-methyl-2-nitrophenoxy)phosphoryl]butan-2-amine
• CAS: 56362-05-1
• 化学式: C13H21N2O5P
• 分子量: 316.29
• InChiKey: KTBHXCBJYRPDHP-UHFFFAOYSA-N

物化性质

• 沸点：
  413.9±55.0 °C(Predicted)
• 密度：
  1.199±0.06 g/cm3(Predicted)
• 保留指数：
  2086

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  21
• 可旋转键数：
  7
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.54
• 拓扑面积：
  93.4
• 氢给体数：
  1
• 氢受体数：
  6

文献信息

• Herbicidal composition and herbicidal method
  申请人：Kaken Pharmaceutical Co., Ltd.

  公开号：EP0350880A2

  公开（公告）日：1990-01-17

  A herbicidal composition comprising at least one oxazolidinedione derivative expressed by the following formula: (wherein R¹, R² and R³ independently denote hydrogen atoms, halogen atoms, nitro groups, alkyl groups, alkoxy groups, alkenyloxy groups, alkynyloxy groups or cycloalkyloxy groups; R⁴ and R⁵ independently denote hydrogen atoms, alkyl groups or aryl groups or may be combined with each other to form a polymethylene chain; and said alkyl groups, alkoxy groups, alkenyloxy groups, alkynyloxy groups, cycloalkyloxy groups and aryl groups may be substituted); and at least one organic phosphorus herbicide, as acitve ingredients.

  一种除草组合物，包含至少一种由下式表示的噁唑烷二酮衍生物： (其中R¹、R²和R³独立地表示氢原子、卤素原子、硝基、烷基、烷氧基、烯氧基、炔氧基或环烷氧基；R⁴和R⁵独立地表示氢原子、烷基或芳基，或可相互结合形成多亚甲基链；和至少一种有机磷除草剂作为有效成分。
• Diphenyl ether derivative, herbicidal composition containing the derivative as active ingredient, and process for producing the derivative
  申请人：MITSUBISHI KASEI CORPORATION

  公开号：EP0403938A2

  公开（公告）日：1990-12-27

  This invention provides a diphenyl ether derivative represented by the formula (I): wherein X¹ represents a halogen atom or a C₁-C₃ haloalkyl group; X² and X³ represent independently a hydrogen atom, a halogen atom, a trifluoromethyl group, a nitro group or a cyano group; Y represents a nitro group, a cyano group, a halogen atom, a C₁-C₃ haloalkyl group or a hydrogen atom; A represents a direct bond, a group represented by the formula: -CO₂(CH(R¹)- wherein R¹ represents a hydrogen atom or a C₁-C₃ alkyl group, a group represented by the formula: -C(R²) = NOCH(R³)- wherein R² represents a hydrogen atom, a C₁-C₄ alkyl group which may be substituted with a C₁-C₄ alkoxy group, C₁-C₄ alkylthio group or halogen atom, or a C₁-C₃ alkoxy group, and R³ represents a hydrogen atom or a C₁-C₃ alkyl group, or a group represented by the formula: -C(=NOR⁴)OCH(R³)- wherein R³ is the same as defined above and R⁴ represents a C₁-C₃ alkyl group; and B represents a group represented by the formula: wherein R⁵ represents a halogen atom; a hydroxyl group; an acyloxy group having up to 6 carbon atoms which may be substituted with a halogen atom, C₁-C₆ alkoxy group, C₂-C₇ alkoxycarbonyl group, aryl group which may be substituted with 1 to 3 halogen atoms and/or 1 to 3 C₁-C₃ alkyl groups or aryloxy group which may be substituted with 1 to 3 halogen atoms and/or 1 to 3 C₁-C₃ alkyl groups; a C₄-C₉ cycloalkylcarbonyloxy group; a benzoyloxy group which may be substituted with a halogen atom, C₁-C₄ alkyl group or C₁-C₄ alkoxy group; a C₂-C₇ alkoxycarbonyloxy group; a C₁-C₄ alkylsufonyloxy group; or a carbamoyloxy group which may be substituted with a C₁-C₄ alkyl group and/or C₁-C₄ alkoxy group. A process for preparing the diphenyl ether derivative and a herbicidal composition containing the diphenyl ether derivative as active ingredient are also described. The compounds of this invention show a wide herbicidal spectrum against both annual and perennial weeds and also have a high degree of safety or harmlessness to crops.

  本发明提供了一种由式(I)表示的二苯醚衍生物： 其中 X¹ 代表卤素原子或 C₁-C₃ 卤代烷基；X² 和 X³ 独立地代表氢原子、卤素原子、三氟甲基、硝基或氰基；Y 代表硝基、氰基、卤素原子、C₁-C₃ 卤代烷基或氢原子；A 代表直接键、由式表示的基团： -CO₂(CH(R¹)-) 其中 R¹ 代表氢原子或 C₁-C₃ 烷基、由式表示的基团： -C(R²)=NOCH(R³)-，其中 R² 代表氢原子。 其中 R² 代表氢原子、可被 C₁-C₄ 烷氧基、C₁-C₄ 烷硫基或卤原子取代的 C₁-C₄ 烷基或 C₁-C₃ 烷氧基，而 R³ 代表氢原子或 C₁-C₃ 烷基，或由式表示的基团： -C(＝Nor⁴)OCH(R³)-。 其中 R³ 与上式定义相同，R⁴ 代表 C₁-C₃烷基；以及 B 代表由式表示的基团： 其中 R⁵ 代表卤素原子；羟基；可被卤素原子、C₁-C₆ 烷氧基、C₂-C₇ 烷氧基羰基、可被 1 至 3 个卤素原子和/或 1 至 3 个 C₁-C₃ 烷基取代的芳基或可被 1 至 3 个卤素原子和/或 1 至 3 个 C₁-C₃ 烷基取代的芳氧基取代的具有最多 6 个碳原子的酰氧基；可被卤素原子、C₁-C₄烷基或 C₁-C₄烷氧基取代的苯甲酰氧基；C₂-C₇ 烷氧基羰氧基； C₁-C₄ 烷基磺酰氧基；或可被 C₁-C₄ 烷基和/或 C₁-C₄ 烷氧基取代的氨基甲酰氧基。本发明还描述了制备二苯醚衍生物的工艺和含有二苯醚衍生物作为活性成分的除草组合物。本发明的化合物对一年生和多年生杂草具有广泛的除草谱，而且对作物高度安全或无害。
• Tetrahydrofuran derivative and herbicide containing the same as effective ingredient
  申请人：Mitsubishi Chemical Corporation

  公开号：EP0548593A1

  公开（公告）日：1993-06-30

  A tetrahydrofuran derivative represented by the following general formula [I]: [wherein A represents direct bonding or a group represented by -B-CHR¹- (wherein B represents oxygen atom, sulfur atom or imino group; R¹ represents hydrogen atom or an alkyl group); R represents hydrogen atom, halogen atom, hydroxyl group, an alkoxy group, benzyloxy group, an alkylsulfonyloxy group or a group represented by -O-COR² (wherein R² represents an alkyl group, a haloalkyl group, an alkenyl group, a cycloalkyl group, phenyl group, benzyl group, an alkoxy group, an alkylamino group or a dialkylamino group; X represents halogen atom; Y represents hydrogen atom or halogen atom) and the herbicide containing the same as the effective ingredient. The compound of the present invention has exceedingly high herbicidal activity, and furthermore, the compound is excellent than the known similar compounds in terms of safety on crops. Thus, the compound is useful as a herbicide.

  由以下通式[I]代表的四氢呋喃衍生物： [其中 A 代表直接键合或由 -B-CHR¹- 代表的基团（其中 B 代表氧原子、硫原子或亚氨基；R¹ 代表氢原子或烷基）；R代表氢原子、卤素原子、羟基、烷氧基、苄氧基、烷基磺酰氧基或由-O-COR²代表的基团（其中R²代表烷基、卤代烷基、烯基、环烷基、苯基、苄基、烷氧基、烷基氨基或二烷基氨基；X代表卤素原子；Y代表氢原子或卤素原子）和含有相同有效成分的除草剂。本发明的化合物具有极高的除草活性，此外，就对作物的安全性而言，该化合物比已知的同类化合物更为出色。因此，本发明化合物可用作除草剂。
• Sulfonamide and herbicide containing the same as active ingredient
  申请人：MITSUBISHI KASEI CORPORATION

  公开号：EP0326170B1

  公开（公告）日：1991-12-11
• N-[2-(pyridyl)propyl]-N-substituted sulfonamide, herbicide containing the same as an active ingredient and intermediate thereof
  申请人：MITSUBISHI KASEI CORPORATION

  公开号：EP0281110B1

  公开（公告）日：1994-09-07