dibenzhydryldiazene | 34863-14-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: dibenzhydryldiazene
• 英文别名: azobis(diphenylmethane)
• CAS: 34863-14-4
• 化学式: C₂₆H₂₂N₂
• 分子量: 362.474
• InChiKey: QYINCWYHJCTGRW-BYYHNAKLSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.02
• 重原子数：
  28.0
• 可旋转键数：
  6.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  24.72
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  dibenzhydryldiazene 以 苯 为溶剂， 反应 5.0h， 以100%的产率得到1,1,2,2-四苯基乙烷
  参考文献：
  名称：

  三重态二苯卡宾对1,2,3-苯并噻二唑中硫原子的反应性

  摘要：

  在1,2,3-苯并噻二唑（2）存在下于87°C在氯苯中热分解二苯基重氮甲烷（1），得到9-苯基噻吨黄酮（3），6-苯基-6 H-二苯并[ b，d ]硫代吡喃（ 4），6-苯甲酰基-6-苯基-6 H-二苯并[ b，d] thiopyran（5）和thianthren（6）。用三重态二苯碳烯对（2）的硫原子的攻击来解释反应产物，导致杂环核的分解和氮的损失，并形成双自由基中间体（7），由此生成产物（3）–（6 ）可能会出现。已有证据表明，苯并噻二唑（2）可以作为三重态二苯卡宾的有效自旋阱，从而防止单重态和三重态的可逆相互转化。

  DOI：

  10.1039/p19810001544

文献信息

• POLYMERIZATION ACCELERATOR, CURABLE COMPOSITION, CURED PRODUCT, AND PROCESS FOR PRODUCING THIOL COMPOUND
  申请人：Miyata Hideo

  公开号：US20100029876A1

  公开（公告）日：2010-02-04

  A polymerization accelerator includes a specific thiol compound. A curable composition of excellent thermal stability contains the polymerization accelerator. A cured product is obtained from the curable composition. The polymerization accelerator includes a thiol compound having two or more groups represented by Formula (1) below: wherein R 1 is a hydrogen atom or a C1-10 alkyl group, and m is an integer of 0, 1 or 2.

  一种聚合物化加速剂包括特定的硫醇化合物。具有优异热稳定性的可固化组合物中含有该聚合物化加速剂。从可固化组合物中得到固化产品。聚合物化加速剂包括具有以下式（1）所表示的两个或更多基团的硫醇化合物：其中R1是氢原子或C1-10烷基基团，m为0、1或2的整数。
• CURABLE COMPOSITION CONTAINING HYDROXYTHIOL COMPOUND, AND CURED PRODUCTS THEREOF
  申请人：MUROFUSHI Katsumi

  公开号：US20100047713A1

  公开（公告）日：2010-02-25

  Curable compositions have high sensitivity and excellent developability, and further have good storage properties as required. The compositions include a hydroxythiol compound represented by Formula (1) below and a compound with an ethylenically unsaturated double bond: wherein R 1 and R 2 are each independently a hydrogen atom, a C1-10 alkyl group or an aromatic ring; X is an aliphatic group, an aromatic ring-containing group or a heterocyclic ring-containing group; Y is an ester bond; k and l are each an integer ranging from 1 to 20; m is an integer of 0, 1 or 2; and n is 0 or 1.

  可治疗组合物具有高灵敏度和优异的显影性能，并且具有所需的良好储存性能。该组合物包括以下式(1)所表示的羟基硫醇化合物和具有乙烯不饱和双键的化合物：其中，R1和R2各自独立地表示氢原子、C1-10烷基或芳香环；X表示脂肪族基、含芳香环的基团或含杂环的基团；Y表示酯键；k和l各自为1至20之间的整数；m为0、1或2的整数；n为0或1。
• PROCESS FOR PREPARING LONG-CHAIN POLYMETHYLENE HALIDE TELOMERS
  申请人：Yang Yu

  公开号：US20090312517A1

  公开（公告）日：2009-12-17

  A process comprises combining in a batchwise, semi-continuous, or continuous manner, or a combination thereof, in the presence of at least one free radical initiator, and at a temperature sufficient to cause the initiator to fragment to form free radicals, (a) at least one telogen selected from (1) fluoroalkyl halides that comprise at least one halomethylene moiety (—CHX—) and, optionally, at least one non-fluorine heteroatom, and (2) perfluoroalkyl halides that comprise at least one halofluoromethylene moiety (—CFX—) and at least one non-halogen heteroatom, the halides being selected from iodides and bromides; and (b) ethylene; the telogen and the ethylene being combined in total amounts such that the number of moles of ethylene per mole of telogen is at least about 4.

  该过程包括在至少一种自由基引发剂的存在下，以批处理、半连续或连续的方式或其组合方式，以足以使引发剂裂解形成自由基的温度，将至少一种缩聚体选自（1）包含至少一个卤代亚甲基（—CHX—）和可选地至少一个非氟杂原子的氟烷基卤化物和（2）包含至少一个卤氟亚甲基（—CFX—）和至少一个非卤素杂原子的全氟烷基卤化物，卤化物选自碘化物和溴化物，与乙烯结合；缩聚体和乙烯的总量使得乙烯的摩尔数每摩尔缩聚体至少为4。
• Perfluoroalkyl-iodo norbornane compounds and their use as surfactants
  申请人：CIBA-GEIGY AG

  公开号：EP0002741A2

  公开（公告）日：1979-07-11

  Compounds of the formula and the anhydrides or imides thereof, wherein Rf is a perfluoroalkyl group, Y is oxygen or > NR and R is hydrogen or alkyl. These compounds can be prepared by a free radical catalyzed addition of a perfluoroalkyl iodide to a 5-norbornene diacid or its derivative. They are useful as surfactants.

  式中的化合物 及其酸酐或亚胺，其中 Rf 为全氟烷基，Y 为氧或 > NR，R 为氢或烷基。 这些化合物可以通过将全氟烷基碘化物与 5-降冰片烯二酸或其衍生物进行自由基催化加成来制备。它们可用作表面活性剂。
• A method of making vinyl-silicone copolymers using mercapto functional silicone chain-transfer agents and release coatings made therewith
  申请人：MINNESOTA MINING AND MANUFACTURING COMPANY

  公开号：EP0421588A2

  公开（公告）日：1991-04-10

  A method of preparing vinyl-silicone copolymers which involves the use of a mercapto-functional silicone compound as a macromolecular chain transfer agent. Release coatings and low adhesion backsizes comprising the vinyl-silicone copolymers.

  制备乙烯基-有机硅共聚物的方法，包括使用巯基官能团有机硅化合物作为大分子链转移剂。由乙烯基-硅氧烷共聚物组成的脱模涂层和低粘性背胶。