ammonium diisopropyldithiophosphinate | 82794-28-3

• 分子结构分类: 有机化合物 - 有机磷化合物 - 有机硫代磷化合物
• 英文名称: ammonium diisopropyldithiophosphinate
• 英文别名: ammonium di-i-propyldithiophosphate
• CAS: 82794-28-3
• 化学式: C₆H₁₄PS₂*H₄N
• 分子量: 199.321
• InChiKey: FGYWUXPQOLZWMT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.12
• 重原子数：
  10.0
• 可旋转键数：
  2.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  36.5
• 氢给体数：
  1.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  ammonium diisopropyldithiophosphinate 、 nickel diacetate 生成 diisopropyl-dithiophosphinic acid ; nickel (II)-salt
  参考文献：
  名称：

  Malatesta, L.; Pizzotti, R., Chimie et Industrie (Paris), 1945, vol. 27, p. 6 - 10

  摘要：

  DOI：

文献信息

• Dithiophosphinate complexes of the actinides. II. Preparation and characterisation of the compounds UO2(S2PR2)2 · R′OH,[Et4N][UO2(S2PR2)2Cl] and UO2(S2PR2)2 · Me3PO. The crystal structures of UO2(S2PR2)2 · EtOH, R = Ph and C6H11, [Et4N] [UO2(S2PR2)2Cl], R = Me and Ph, and Uo2(S2PMe2)2 · Me3PO
  作者：Anthony E. Storey、Frans Zonnevijlle、A.Alan Pinkerton、Dieter Schwarzenbach

  DOI：10.1016/s0020-1693(00)91196-4

  日期：1983.1

  2 ] 2 . When [UCl 6 ] 2− is employed, only the chlorocomplexes are obtained. The complexes for R = Me, Et, Pr i , OMe, OEt, OPr i , Ph and C 6 H 11 have been characterised by elemental analysis, IR and NMR spectroscopy. From one reaction of UVl 4 and NaS 2 PMe 2 , the complex UO 2 (S 2 PMe 2 ) 2 · Me 3 PO was obtained by an unknown route. The crystal structures have been determined for two alcohol adducts

  摘要二硫代次膦酸盐R 2 PS 2 H与UO 2 Cl 2在醇R'OH溶液中反应，生成配合物UO 2（S 2 PR 2）2·R'OH。在过量氯离子存在下，将醇置换形成阴离子氯配合物，可以将其分离为[Et 4 N] +盐。在空气中与UCl 4的相似反应在新颖的双氧化反应中产生相同的化合物。最初形成的U（IV）络合物在空气中迅速氧化，生成相应的铀酰化合物，同时，两个配体被氧化，形成二聚体[R 2 PS 2] 2。当使用[UCl 6] 2-时，仅获得氯配合物。R ＝ Me，Et，Pr 1，OMe，OEt，OPr 1，Ph和C 6 H 11的配合物已经通过元素分析，IR和NMR光谱表征。从UVl 4和NaS 2 PMe 2的一个反应中，通过未知途径获得了络合物UO 2（S 2 PMe 2）2·Me 3 PO。已经确定了两种醇加合物，两种氯配合物和氧化膦加合物的晶体结构。UO 2（S 2 PPh 2）2·EtOH：Triclinic，a
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Ni: MVol.C2, 8.21, page 1093 - 1102
  作者：

  DOI：——

  日期：——
• Synthesis and Characterization of Tp^<i>i</i>PrMoO(S₂PR₂) (R = Pr^<i>i</i>, Ph, OEt, OPr^<i>i</i>, (−)-Mentholate) and {HB(OMe)(Pr^<i>i</i>pz)₂}MoO(S₂PPr^<i>i</i>₂), Including Isomers of Known 1,2-Borotropically-Shifted Complexes
  作者：Charles G. Young、Michael S. Malarek、David J. Evans、Christian J. Doonan、Victor Wee Lin Ng、Jonathan M. White

  DOI：10.1021/ic8015518

  日期：2009.3.2

  Green/blue Tp(iPr)MoO(S2PR2) (Tp(iPr) = hydrotris(3-isopropylpyrazolyl)borate; R = Pr-i Ph, OEt, OPri (-)-mentholate) complexes were synthesized and characterized by elemental analysis, mass spectrometry, IR and NMR spectroscopy, and X-ray crystallography. The diamagnetic, six-coordinate, oxo-Mo(IV) complexes possess distorted octahedral geometries defined by terminal oxo, bidentate dithio acid, and tridentate Tp(iPr) ligands. The R = Pri and Ph derivatives are isomers of previously reported 1,2-borotropically shifted complexes, Tp(iPr)* MoO(S2PR2) (Tp(iPr)* = hydrobis(3-isopropylpyrazolyl)(5-isopropylpyrazolyl)borate; ref: Inorg. Chem. 1996, 35, 5368). Conversion of Tp(iPr)MoO (S2PPh2) into Tp(iPr)*MoO(S2PPh2) at elevated temperatures (>80 degrees C) showed that the borotropically shifted isomer was thermodynamically more stable than the unshifted species. Reaction with methanol converts Tp(iPr)MoO(S2PPr2i) into HB(OMe)(Pr(i)pz)(2))MoO(S2PPr2i) (Pr(i)pz = 3-isopropylpyrazolyl), which was characterized by spectroscopic and crystallographic methods.
• Dithiocarbamates of gallium(III) and indium(III): syntheses, spectroscopy, and structures
  作者：Dimple P. Dutta、Vimal K. Jain、Axel Knoedler、Wolfgang Kaim

  DOI：10.1016/s0277-5387(01)00990-1

  日期：2002.1

  Several complexes of the type, [MS2CNR}(3)] (1) (M = Ga or In; R = CH2CH2OCHCH2, CH2CH2N(Me)CH2CH2), [MCl2S2CN(CH2CH2)(2)O}] (2) (M = Ga or In), [MClS2CN(CH2CH2)(2)O}(2)] (3) (M = Ga or In), [GaS2CN(CH2CH2) O-2}S2P(OR)(2)}(2)] (4) (R = Et, Pr) and [MS2CNR}(SCH2CH2)(2)O}] (5) (M = Ga or In: R = CH2CH2OCH2CH2, CH2CH2N(Me)CH2CH2) have been prepared. All the complexes were characterized by elemental analysis, IR and NMR (H-1, C-13H-1}) spectroscopy. Ga-71 NMR chemical shifts and half line widths are influenced by the coordination number of gallium and the substituents on the ligand moiety. Single crystal X-ray structures of two complexes [MS2CN(CH2CH2)(2)O}(3)] (M = Ga. In) have been determined. (C) 2002 Published by Elsevier Science Ltd.
• Dithiophosphinate complexes of the UO22+ ion containing a coordinated water molecule — solid state structures and stereochemical rigidity in solution
  作者：A.Alan Pinkerton、Frank-Peter Ahlers、Horst F. Greiwing、Bernt Krebs

  DOI：10.1016/s0020-1693(96)05460-6

  日期：1997.4

  Complexes of formula [UO2S2P(Pr-i)(2)}(2).H2O] have been isolated either unsolvated (I) or as acetonitrile solvates (II and III). They have been characterized by X-ray crystallography and NMR spectroscopy. The UO3S4 core deformation from ideal geometry varies widely in the solid state and is shown to become stereochemically rigid at moderately low temperature in solution. Crystal data for complex I:[UO2S2P(Pr-i)(2)}(2).H2O], C12H30O3P2S4U, Mr=650.61. monoclinic, P2(1)/c, a=8.685(1), b=12.445(1), c=21.536(3) Angstrom, beta=94.78(1)degrees V=2320(1) Angstrom(3), Z=4, D-x=1.86 g cm(-3), R=0.028; complex II: [UO2S2P(Pr-i)(2)}(2).H2O].MeCN, C14H33NO3P2S4U, Mr=691.66, orthorhombic, Pbca, a=28.831(3), b=16.536(2), c=10.801(1) Angstrom, V=5149(2) Angstrom(3), Z=8, D-x=1.78 g cm(-3), R=0.042; complex III: [UO2S2P(Pr-i)(2)}(2).H2O].MeCN, C14H33NO3P2S4 U, Mr=691.66, monoclinic, P2(1)/c, a=14.626(2), b=16.468(2), c=10.873(2) Angstrom, beta=100.29(1)degrees, V=2577(i) Angstrom(3), Z=4, D-x=1.78 g cm(-3), R=0.054.