10-[2-[2-[2-[2-[[2-[4,5-Bis(hexylsulfanyl)-1,3-dithiol-2-ylidene]-1,3-dithiol-4-yl]sulfanyl]ethoxy]ethoxy]ethoxy]ethyl]-7,8-dimethylbenzo[g]pteridine-2,4-dione | 1240016-57-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 蝶啶及其衍生物
• 英文名称: 10-[2-[2-[2-[2-[[2-[4,5-Bis(hexylsulfanyl)-1,3-dithiol-2-ylidene]-1,3-dithiol-4-yl]sulfanyl]ethoxy]ethoxy]ethoxy]ethyl]-7,8-dimethylbenzo[g]pteridine-2,4-dione
• 英文别名: 10-[2-[2-[2-[2-[[2-[4,5-bis(hexylsulfanyl)-1,3-dithiol-2-ylidene]-1,3-dithiol-4-yl]sulfanyl]ethoxy]ethoxy]ethoxy]ethyl]-7,8-dimethylbenzo[g]pteridine-2,4-dione
• CAS: 1240016-57-2
• 化学式: C₃₈H₅₂N₄O₅S₇
• 分子量: 869.317
• InChiKey: ACYRLZFZCUCZTB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.8
• 重原子数：
  54
• 可旋转键数：
  25
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.58
• 拓扑面积：
  279
• 氢给体数：
  1
• 氢受体数：
  13

反应信息

• 作为产物：
  描述：

  四氧嘧啶 、 2-N-[2-[2-[2-[2-[[2-[4,5-bis(hexylsulfanyl)-1,3-dithiol-2-ylidene]-1,3-dithiol-4-yl]sulfanyl]ethoxy]ethoxy]ethoxy]ethyl]-4,5-dimethylbenzene-1,2-diamine 在 硼酸 作用下， 以 甲醇 为溶剂， 以4.3 mg的产率得到10-[2-[2-[2-[2-[[2-[4,5-Bis(hexylsulfanyl)-1,3-dithiol-2-ylidene]-1,3-dithiol-4-yl]sulfanyl]ethoxy]ethoxy]ethoxy]ethyl]-7,8-dimethylbenzo[g]pteridine-2,4-dione
  参考文献：
  名称：

  Tetrathiafulvalene–flavin dyads: electron transfer promoted by metal cations

  摘要：

  Tetrathiafulvalene-flavin dyads 1 and 2 are reported. Both absorption and ESR spectral studies show that the intramolecular electron transfer occurs from TTF to Flavin units in dyads 1 and 2 in the presence of Pb2+/Sc3+. But, the electron transfer is more efficient for dyad 1 in the presence of Pb2+/Sc3+. Electrochemical studies manifest that coordination of dyads 1 and 2 with Pb2+/Sc3+ play an important role in facilitating the electron transfer within dyads 1 and 2. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2010.06.095

文献信息

• Tetrathiafulvalene–flavin dyads: electron transfer promoted by metal cations
  作者：Lina Jia、Guanxin Zhang、Deqing Zhang、Daoben Zhu

  DOI：10.1016/j.tetlet.2010.06.095

  日期：2010.8

  Tetrathiafulvalene-flavin dyads 1 and 2 are reported. Both absorption and ESR spectral studies show that the intramolecular electron transfer occurs from TTF to Flavin units in dyads 1 and 2 in the presence of Pb2+/Sc3+. But, the electron transfer is more efficient for dyad 1 in the presence of Pb2+/Sc3+. Electrochemical studies manifest that coordination of dyads 1 and 2 with Pb2+/Sc3+ play an important role in facilitating the electron transfer within dyads 1 and 2. (C) 2010 Elsevier Ltd. All rights reserved.