2-[2,4-二-叔-戊基苯氧基]己酰氯 | 63059-55-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 2-[2,4-二-叔-戊基苯氧基]己酰氯
• 英文名称: 2-<2,4-Bis(1,1-dimethylpropyl)phenoxy>hexanoylchlorid
• 英文别名: 2-(2,4-Di-tert-pentylphenoxy)hexanoyl chloride；α-(2,4-bis-t-pentylphenoxy)-hexanoyl chloride；α-(2,4-ditert.-amylphenoxy)-hexanoylchloride；2-(2,4-di-t-pentylphenoxy)hexanoyl chloride；2-[2,4-bis(2-methylbutan-2-yl)phenoxy]hexanoyl chloride
• CAS: 63059-55-2
• 化学式: C₂₂H₃₅ClO₂
• 分子量: 366.972
• InChiKey: LRKLDHJJKJBSIP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.7
• 重原子数：
  25
• 可旋转键数：
  10
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.68
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

安全信息

• 海关编码：
  2918990090

反应信息

• 作为反应物：
  描述：

  2-[2,4-二-叔-戊基苯氧基]己酰氯 、 2-氨基-4-甲氧基苯酚 以 1,4-二氧六环 为溶剂， 反应 0.25h， 生成 2-<2,4-Bis(1,1-dimethylpropyl)phenoxy>hexansaeure(2-hydroxy-5-methoxyanilid)
  参考文献：
  名称：

  Selektive Spaltung von aromatischen Methylethern mit Lithiumiodid in Chinolin

  摘要：

  DOI：

  10.1002/prac.19953370186

文献信息

• 6-Acylamino-5-substituted-benzoxazol-2-one compounds and method for using them
  申请人：EASTMAN KODAK COMPANY

  公开号：EP1316550A1

  公开（公告）日：2003-06-04

  Disclosed is a 6-acylamino-5-substituted-benzoxazol-2-one compound having the structural formula I: wherein    Y is halogen or a substituent group linked to the rest of the compound by a hetero atom, and    R' is a group containing at least 8 carbon atoms. Also disclosed is a method for forming a cyan dye-forming coupler from the above compound. The method and intermediate provide a simplified manufacturing process.

  公开了一种具有结构式I的6-酰胺基-5-取代苯并噁唑-2-酮化合物，其中Y是卤素或通过杂原子连接到化合物其余部分的取代基，R'是含有至少8个碳原子的基团。还公开了一种从上述化合物形成青色染料形成偶联剂的方法。该方法和中间体提供了简化的制造过程。
• Cyan dye-forming couplers and photographic elements and processes
  申请人：Minnesota Mining and Manufacturing Company

  公开号：US04672013A1

  公开（公告）日：1987-06-09

  Cyan dye-forming 6-hydroxy-2H-1,4-benzoxazin-3-(4H)-one couplers, preferably cyan dye-forming couplers corresponding to the general formula: ##STR1## wherein R represents hydrogen or R"'--X--NH, R' represents hydrogen or a substituted or unsubstituted alkyl group, R" represents hydrogen or R.sup.iv --X--, X represents a member selected from the group consisting of --CO--, --SO.sub.2 --, --OCOCO--, --NHCO--, R"' and R.sup.iv represent a substituted or unsubstituted alkyl group or a substituted or unsubstituted aryl group and Y and Z, the same or different, represent hydrogen, halogen and a substituted or unsubstituted alkyl or alkoxy group, are described for use in silver halide color photographic processes and elements.

  青色染料形成6-羟基-2H-1,4-苯并噁嗪-3-(4H)-酮偶联剂，优选对应于以下一般式的青色染料形成偶联剂：##STR1## 其中，R代表氢或R"'--X--NH，R'代表氢或取代或未取代的烷基，R"代表氢或R.sup.iv --X--，X代表从--CO--，--SO.sub.2 --，--OCOCO--，--NHCO--中选择的一员，R"'和R.sup.iv代表取代或未取代的烷基或取代或未取代的芳基，Y和Z相同或不同，代表氢，卤素和取代或未取代的烷基或烷氧基。该偶联剂用于银卤化物彩色摄影过程和元素。
• 5-acylamino-2-arylazo, nitro, or nitroso-4-substituted-phenol compounds and method of using them
  申请人：Eastman Kodak Company

  公开号：US06476202B1

  公开（公告）日：2002-11-05

  Disclosed is a 5-acylamino-2-arylazo, nitro, or nitroso-4-substituted-phenol having the structural formula I: wherein: R* is an arylazo, nitro, or nitroso group, Y is a coupling-off group, and R′ is a substituent group. Also disclosed is a method of using the compound in a simplified process for making a photographic coupler.

  本发明公开了一种结构式I的5-酰胺基-2-芳基偶氮基，硝基或亚硝基-4-取代酚，其中：R*是芳基偶氮基，硝基或亚硝基，Y是偶联离去基团，R′是取代基团。本发明还公开了一种使用该化合物的方法，用于制备摄影偶联剂的简化工艺。
• 4-acylamino-2-hydroxy-5-substituted-acylanilide compounds and method of using them
  申请人：Eastman Kodak Company

  公开号：US20030109753A1

  公开（公告）日：2003-06-12

  Disclosed is a 4-acylamino-2-hydroxy-5-substituted-acylanilide compound having the structural formula I: 1 wherein R is hydrogen or an alkyl group, Y is a group linked to the rest of the compound by a —O—, —S—, or —N— atom; and R′ is a substituent group. Also disclosed is a method of using the compound in making a cyan dye-forming photographic coupler.

  公开了一种具有结构式I：1的4-酰基氨基-2-羟基-5-取代酰基苯酰胺化合物，其中R为氢或烷基，Y是通过-O-，-S-或-N-原子与化合物的其余部分连接的基团；R'是取代基团。还公开了一种使用该化合物制备青色染料形成的照相偶合剂的方法。
• Photographic couplers, emulsions, materials and processes
  申请人：EASTMAN KODAK COMPANY (a New Jersey corporation)

  公开号：EP0028099A1

  公开（公告）日：1981-05-06

  Phenolic cyan dye-forming couplers of the general formula: wherein X is hydrogen or a coupling-off group and R is a ballast group, are useful in photographic emulsions, matenals and processes. The cyan dyes prepared when such couplers are reacted with oxidized aromatic primary amino colour developing agents such as p-phenylenediamines have little or no absorption in the green region of the spectrum and have relatively pure hues.

  通式为：其中 X 为氢或偶联基团，R 为镇流器基团的酚类青色染料形成耦合剂可用于感光乳剂、母料和工艺中。 当此类耦合剂与氧化芳香族伯氨基显色剂（如对苯二胺）反应时，所制备的青色染料在光谱的绿色区域几乎没有吸收，且色调相对纯正。