1,2,3,4-tetrafluoro-5,8-dimethoxynaphthalene | 853649-36-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 1,2,3,4-tetrafluoro-5,8-dimethoxynaphthalene
• CAS: 853649-36-2
• 化学式: C₁₂H₈F₄O₂
• 分子量: 260.188
• InChiKey: XMGMZGNNSCUBDH-UHFFFAOYSA-N

物化性质

• 熔点：
  142-145 °C
• 沸点：
  323.8±37.0 °C(Predicted)
• 密度：
  1.381±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  18
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  1,2,3,4-tetrafluoro-5,8-dimethoxynaphthalene 、 3,4,5,6-四氟苯酐 在 aluminum (III) chloride 、 sodium chloride 作用下， 反应 1.0h， 生成 1,2,3,4,7,8,9,10-octafluoro-6,11-dihydroxy-5,12-naphthacenedione
  参考文献：
  名称：

  全氟烯烃的合成，电化学性质和晶体堆积

  摘要：

  报道了全氟化红荧烯的合成。电化学分析表明，与未改性的红荧烯相比，全氟烯烃的电子亲和力显着提高。晶体学研究显示两种多晶型物和一种溶剂化物，每个...

  DOI：

  10.1039/c6cc03259a
• 作为产物：
  描述：

  2-呋甲醚 、 溴五氟苯 、 硫酸二甲酯 在 正丁基锂 、 potassium carbonate 作用下， 以 乙醚 、 正己烷 、 丙酮 为溶剂， 反应 3.0h， 以18%的产率得到1,2,3,4-tetrafluoro-5,8-dimethoxynaphthalene
  参考文献：
  名称：

  Synthesis, Crystal Structure, and Electron-Accepting Property of the BF₂ Complex of a Dihydroxydione with a Perfluorotetracene Skeleton

  摘要：

  A BF2 complex containing an octafluorotetracene moiety was synthesized as a new type of electron acceptor. This compound exhibits a long-wavelength absorption based on the perfluorotetracene skeleton and high electron affinity due to its quadrupolar structure enhanced by fluorination. In the crystal, the molecules are arranged with short F...pi and F...F contacts affording a dense crystal packing. The BF2 complex exhibited n-type semiconducting behavior.

  DOI：

  10.1021/ol901633q

文献信息

• Organic thin-film transistor and fabrication method thereof and organic thin-film device
  申请人：Inoue Youji

  公开号：US20070194302A1

  公开（公告）日：2007-08-23

  An organic thin-film transistor having a higher carrier-mobility, a method of fabricating the organic thin-film transistor and an organic thin-film device including the organic thin-film transistor are provided. In an organic thin-film transistor having an organic semiconductor layer, the organic semiconductor layer contains a fluorinated acene compound which is represented by a formula of C 4n+2 F 2n+4 , wherein n is an integer of 2 or greater. The fluorinated acene compound is preferably tetradecafluoropentacene or dodecafluoronaphthacene.

  提供了一种具有更高载流子迁移率的有机薄膜晶体管、制造该有机薄膜晶体管的方法以及包括该有机薄膜晶体管的有机薄膜器件。在具有有机半导体层的有机薄膜晶体管中，所述有机半导体层包含一种由C4n+2F2n+4表示的氟化蒽化合物，其中n为2或更大的整数。所述氟化蒽化合物优选为十四氟五环戊二烯或十二氟萘蒽。
• Synthesis, Crystal Structure, and Electron-Accepting Property of the BF₂ Complex of a Dihydroxydione with a Perfluorotetracene Skeleton
  作者：Katsuhiko Ono、Junko Hashizume、Hiroyuki Yamaguchi、Masaaki Tomura、Jun-ichi Nishida、Yoshiro Yamashita

  DOI：10.1021/ol901633q

  日期：2009.10.1

  A BF2 complex containing an octafluorotetracene moiety was synthesized as a new type of electron acceptor. This compound exhibits a long-wavelength absorption based on the perfluorotetracene skeleton and high electron affinity due to its quadrupolar structure enhanced by fluorination. In the crystal, the molecules are arranged with short F...pi and F...F contacts affording a dense crystal packing. The BF2 complex exhibited n-type semiconducting behavior.
• Synthesis, electrochemical properties, and crystal packing of perfluororubrene
  作者：Zhuoran Zhang、William A. Ogden、Victor G. Young、Christopher J. Douglas

  DOI：10.1039/c6cc03259a

  日期：——

  A synthesis of perfluorinated rubrene is reported. Electrochemical analysis revealed the significantly increased electron affinity of perfluororubrene compared with non-modified rubrene. Crystallographic investigation revealed two polymorphs and a solvate, each...

  报道了全氟化红荧烯的合成。电化学分析表明，与未改性的红荧烯相比，全氟烯烃的电子亲和力显着提高。晶体学研究显示两种多晶型物和一种溶剂化物，每个...