diethyl-diallyl-ammonium; bromide | 14764-65-9

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: diethyl-diallyl-ammonium; bromide
• 英文别名: Diaethyl-diallyl-ammonium; Bromid；Diallyl diethyl ammonium bromide；diethyl-bis(prop-2-enyl)azanium;bromide
• CAS: 14764-65-9
• 化学式: Br*C₁₀H₂₀N
• 分子量: 234.179
• InChiKey: HVUHISUXSQCUHS-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -0.78
• 重原子数：
  12
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  diethyl-diallyl-ammonium; bromide 在 potassium tert-butylate 作用下， 以 乙腈 为溶剂， 以74%的产率得到N,N-diethylhexa-1,5-dien-3-amine
  参考文献：
  名称：

  A Tandem Amino-Cope Rearrangement/Enamine Alkylation Reaction

  摘要：

  热诱导的3-氨基-1,5-二烯底物的[3,3]-σ-转位重排反应生成相应的烯胺产物，产率高且具有优良的反式:顺式烯胺选择性。在氨基-科普重排反应中产生的烯胺已被直接衍生化，代表了串联氨基-科普重排/烯胺烷基化反应的首次报道。概述了这一新型合成策略的潜力。

  DOI：

  10.1055/s-1997-3248
• 作为产物：
  描述：

  N,N-二乙基烯丙胺 、 3-溴丙烯 在 丙酮 作用下， 生成 diethyl-diallyl-ammonium; bromide
  参考文献：
  名称：

  Preparation and Polymerization of Unsaturated Quaternary Ammonium Compounds. VIII. A Proposed Alternating Intramolecular-Intermolecular Chain Propagation¹

  摘要：

  DOI：

  10.1021/ja01569a037

文献信息

• Process for preparing waterfastness additive
  申请人：Xerox Corporation

  公开号：US20030027948A1

  公开（公告）日：2003-02-06

  Disclosed is a process which comprises (a) reacting allyl bromide with diethyl amine in a molar ratio of at least about 1 mole of allyl bromide per about 1.15 moles of diethyl amine and in a molar ratio of no more than about 1 mole of allyl bromide per about 2 moles of diethyl amine, thereby generating allyl diethyl amine in a monomer reaction mixture; (b) subsequently filtering the monomer reaction mixture to remove impurities; (c) subsequently reacting the allyl diethyl amine with allyl bromide, thereby generating solid diallyl diethyl ammonium bromide; (d) subsequently isolating the solid diallyl diethyl ammonium bromide; (e) subsequently dissolving the diallyl diethyl ammonium bromide in a solvent and adding thereto a polymerization initiator to form a polymerization reaction mixture; (f) subsequently heating the polymerization reaction mixture in a vessel equipped with a reflux condenser to a temperature of from about 90 to about 100° C., thereby generating poly(diallyl diethyl ammonium bromide); and (g) subsequently optionally isolating the poly(diallyl diethyl ammonium bromide) from the polymerization reaction mixture.

  公开了一种方法，其包括：（a）以至少约1摩尔的丙烯基溴与约1.15摩尔的二乙基胺的摩尔比反应，并以不超过约2摩尔的二乙基胺对丙烯基溴的摩尔比，从而在单体反应混合物中生成丙烯基二乙基胺；（b）随后过滤单体反应混合物以除去杂质；（c）随后将丙烯基二乙基胺与丙烯基溴反应，从而生成固体的二烯丙基二乙基铵溴；（d）随后分离固体的二烯丙基二乙基铵溴；（e）随后将二烯丙基二乙基铵溴溶解在溶剂中，并加入一种聚合引发剂以形成聚合反应混合物；（f）随后在带有回流冷凝器的容器中将聚合反应混合物加热至约90至约100℃的温度，从而生成聚（二烯丙基二乙基铵溴）；（g）随后可选择从聚合反应混合物中分离聚（二烯丙基二乙基铵溴）。
• Polyelectrolyte toner processes
  申请人：Xerox Corporation

  公开号：US06110636A1

  公开（公告）日：2000-08-29

  A surfactant free process for the preparation of toner comprising heating a mixture of an emulsion latex, a colorant, and a polyelectrolyte.

  一种无表面活性剂的调色剂制备工艺，包括加热乳液、着色剂和多电解质混合物的混合物。
• Highly Selective Preparation and Depolymerization of Chemically Recyclable Poly(cyclopentene carbonate) Enabled by Organoboron Catalysts
  作者：Guan‐Wen Yang、Yuhui Wang、Huan Qi、Yao‐Yao Zhang、Xiao‐Feng Zhu、Chenjie Lu、Li Yang、Guang‐Peng Wu

  DOI：10.1002/anie.202210243

  日期：2022.11.14

  The first metal-free access to poly(cyclopentene carbonate) and its chemical recycling to monomer were achieved by using a dinuclear bifunctional organoboron catalyst, enriching the portfolio of the circular plastic economy.

  通过使用双核双功能有机硼催化剂，首次实现了对聚（环戊烯碳酸酯）的无金属访问及其对单体的化学回收，丰富了循环塑料经济的产品组合。
• Process for detackification of paint spray operation wastes using melamine formaldehyde
  申请人：CALGON CORPORATION

  公开号：EP0293129A1

  公开（公告）日：1988-11-30

  An improved method for killing over-sprayed paints which requires a) alkalinity adjustment of paint spray booth water to at least about 50 ppm, preferably about 200-600 ppm, on a calcium carbonate basis; b) addition of a melamine-formaldehyde polymer to paint spray booth water; c) addition of a polymeric coagulant to paint spray booth water; and d) separation of the resulting floc.

  一种杀灭过喷涂料的改进方法，要求 a) 将喷漆室水的碱度调整到至少约 50 ppm，最好约 200-600 ppm（以碳酸钙为基础）；b) 在喷漆室水中添加三聚氰胺-甲醛聚合物；c) 在喷漆室水中添加聚合凝结剂；d) 分离产生的絮凝物。
• Process for preparing quaternary maleic anhydride polymers
  申请人：CALGON CORPORATION

  公开号：EP0344841A2

  公开（公告）日：1989-12-06

  This invention is directed to a solution polymerization process for manufacturing maleic anhydride/quaternary ammonium-type polymers.

  本发明涉及一种制造马来酸酐/季铵型聚合物的溶液聚合工艺。