ethyl 1-naphthyl xanthate | 88220-33-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: ethyl 1-naphthyl xanthate
• 英文别名: 1-naphtyl ethyl xanthate；O-ethyl naphthalen-1-ylsulfanylmethanethioate
• CAS: 88220-33-1
• 化学式: C₁₃H₁₂OS₂
• 分子量: 248.37
• InChiKey: IOKZJULPHKYPOO-UHFFFAOYSA-N

物化性质

• 沸点：
  388.4±15.0 °C(Predicted)
• 密度：
  1.24±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.8
• 重原子数：
  16
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.15
• 拓扑面积：
  66.6
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  ethyl 1-naphthyl xanthate 在 lithium aluminium tetrahydride 作用下， 以 乙醚 为溶剂， 反应 3.5h， 生成 1-奈硫酚
  参考文献：
  名称：

  Photochemical anion-promoted carbon-sulfur cleavage reactions of diaryl sulfides, alkyl aryl sulfides and related sulfoxides and sulfones

  摘要：

  Diaryl sulfides and the related sulfoxides and sulfones react with substances such as diethyl phosphite anion, pinacolone enolate, and diphenylphosphide anion under irradiation to cleave one carbon-sulfur bond and form diethyl arylphosphonates, arylmethyl tert-butyl ketones, and aryldiphenylphosphines. Alkyl aryl sulfides and the related sulfones also experience carbon-sulfur bond cleavage under these conditions to produce arenethiols. Generally, these reactions occur in synthetically useful yields. The reactions of the anions with these sulfides, sulfoxides, and sulfones all require irradiation, but it is notable that the reactions of diphenylphosphide anion occur in the visible region of the spectrum. Several lines of evidence suggest that the reaction proceeds via the familiar S(RN)1 pathway and that the photochemically-induced electron transfer occurs in an arene-anion complex. Thermochemical considerations dictate the cleavage direction in the anion radicals of unsymmetrical sulfides.

  DOI：

  10.1021/jo00007a034
• 作为产物：
  描述：

  1-碘萘 、 potassium ethyl xanthogenate 在 copper(II) oxide 作用下， 以 二甲基亚砜 为溶剂， 反应 15.0h， 生成 ethyl 1-naphthyl xanthate
  参考文献：
  名称：

  在无配体条件下用黄原酸钾钾和可循环使用的铜催化剂合成不对称硫化物

  摘要：

  通过使用可回收的CuO纳米粒子在无配体的条件下通过交叉偶联反应与廉价的黄原酸乙基钾黄原酸酯进行不对称硫化物的合成，具有良好的收率，并且可以回收并重复使用多达五个循环而不会失去活性。

  DOI：

  10.1021/jo200793k

文献信息

• Copper nanoparticles supported on polyaniline-functionalized multiwall carbon nanotubes: An efficient and recyclable catalyst for synthesis of unsymmetric sulfides using potassium ethyl xanthogenate in water
  作者：Abdol R. Hajipour、Saeideh Jajarmi、Zahra Khorsandi

  DOI：10.1002/aoc.3697

  日期：2017.9

  polyaniline‐functionalized carbon nanotube‐supported copper(II) nanoparticle catalyst was successfully prepared and evaluated as a heterogeneous catalyst for the one‐pot synthesis of unsymmetric thioethers by coupling of aryl, alkyl and benzyl halides using potassium ethyl xanthogenate as source of sulfur in water. All of these reactions gave the desired products in good to excellent yields. The catalyst is available

  成功地制备了一种新型且功能强大的聚苯胺官能化碳纳米管负载的铜（II）纳米粒子催化剂，并将其评估为通过以黄原酸钾为原料偶联芳基，烷基和苄基卤化物来单锅合成不对称硫醚的多相催化剂。水中的硫。所有这些反应以良好至优异的产率提供了所需的产物。该催化剂是空气稳定的，可以重复使用多次，而不会显着降低其催化活性。
• Biomedical devices
  申请人：Nunez Ivan M.

  公开号：US20100315588A1

  公开（公告）日：2010-12-16

  Biomedical devices such as contact lenses formed from a polymerization product of a mixture comprising (a) a hydrophilic polymer comprising one or more hydrophilic units and one or more thio carbonyl thio fragments of a reversible addition fragmentation chain transfer (“RAFT”) agent; and (b) one or more biomedical device-forming monomers are disclosed.

  本发明涉及一种生物医学设备，例如由聚合产物形成的隐形眼镜，所述聚合产物包括（a）一种亲水性聚合物，包括一种或多种亲水基团和一种或多种可逆加成断裂链转移（RAFT）剂的硫代羰基硫醚片段；以及（b）一种或多种生物医学设备形成单体。
• Tedjamulia, Marvin L.; Tominaga, Yoshinori; Castle, Raymond N., Journal of Heterocyclic Chemistry, 1983, vol. 20, p. 1143 - 1148
  作者：Tedjamulia, Marvin L.、Tominaga, Yoshinori、Castle, Raymond N.、Lee, Milton L.

  DOI：——

  日期：——
• TEDJAMULIA, M. L.;TOMINAGA, YOSHINORI;CASTLE, R. N.;LEE, M. L., J. HETEROCYCL. CHEM., 1983, 20, N 5, 1143-1148
  作者：TEDJAMULIA, M. L.、TOMINAGA, YOSHINORI、CASTLE, R. N.、LEE, M. L.

  DOI：——

  日期：——
• BIOMEDICAL DEVICES
  申请人：Bausch & Lomb Incorporated

  公开号：EP2443482A2

  公开（公告）日：2012-04-25