(2,4-dimethylphenyl)-pyridin-2-ylmethylene-amine | 22870-07-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (2,4-dimethylphenyl)-pyridin-2-ylmethylene-amine
• 英文别名: 2,4-dimethyl-N-pyridin-2-ylmethylene-aniline；N-(2,4-dimethylphenyl)-1-pyridin-2-ylmethanimine
• CAS: 22870-07-1
• 化学式: C₁₄H₁₄N₂
• 分子量: 210.279
• InChiKey: MRCVANKAFJFEHU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  16
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  25.2
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  (2,4-dimethylphenyl)-pyridin-2-ylmethylene-amine 、 tetrakis(acetonitrile)copper(I) perchlorate 以 乙腈 为溶剂， 以86%的产率得到[Cu((2,4-dimethylphenyl)-pyridin-2-ylmethylene-amine)2]ClO4
  参考文献：
  名称：

  Synthesis, spectral characterization, properties and structures of copper(I) complexes containing novel bidentate iminopyridine ligands

  摘要：

  Four new ligands, (4-methyl-phenyl)-pyridin-2-ylmethylene-amine (A), (2,3-dimethyl-phenyl)-pyridin-2-ylmethylene-amine (B), (2,4-dimethyl-phenyl)-pyridin-2-ylmethylene-amine (C) and (2,5-dimethyl-phenyl)-pyridin-2-ylmethylene-amine (D), and their corresponding copper(I) complexes, [Cu(A)(2)]ClO4 (1a), [Cu(B)(2)]ClO4 (1b), [Cu(C)(2)]ClO4 (1c), [Cu(D)(2)]ClO4 (1d), [Cu(A)(PPh3)(2)]ClO4 (2a), [Cu(B)(PPh3)(2)]ClO4 (2b), [Cu(C)(PPh3)(2)]ClO4 (2c) and [Cu(D)(PPh3)(2)]ClO4 (2d), have been synthesized and characterized by CHN analyses, H-1 and C-13 NMR, IR and UV-Vis spectroscopy. The crystal structures of [Cu(B)(2)]ClO4 (1b), [Cu(C)(2)]ClO4 (1c) and [Cu(A)(PPh3)(2)]ClO4 center dot 1/2CH(3)CN (2a) were determined from single crystal X-ray diffraction. The coordination polyhedron about the copper(I) center in the three complexes is best described as a distorted tetrahedron. A quasireversible redox behavior is observed for the complexes. (c) 2006 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2006.08.011

文献信息

• Synthesis and characterization of some new half-sandwich ruthenium(II) complexes with bidentate N,N′-ligands and their application in alcohol oxidation
  作者：Joel M. Gichumbi、Holger B. Friedrich、Bernard Omondi

  DOI：10.1016/j.ica.2016.11.014

  日期：2017.2

  Abstract A series of eight new (η 6 -arene)ruthenium(II) complexes were prepared by the reaction of pyridyl-imine ligands and the ruthenium(II) precursors of the general formula [(η 6 -arene)Ru(μ-Cl)Cl] 2 , where arene = p -cymene ( 1 ) and C 6 H 6 ( 2 ), to form the complexes [(η 6 -arene)RuCl(C 5 H 4 N-2-CH N -Ar)]PF 6 (where Ar = 2,4,6-trimethylphenyl ( a ), 2,4-dimethylphenyl ( b ), 2-methoxyphenyl

  摘要通过吡啶亚胺配体与通式[（η6-芳烃）Ru（μ-Cl）的钌（II）前体反应，制备了八种新的（η6-芳烃）钌（II）配合物。 ）Cl] 2，其中芳烃=对苯甲基（1）和C 6 H 6（2），形成配合物[（η6-芳烃）RuCl（C 5 H 4 N-2-CH N -Ar）] PF 6（其中Ar = 2,4,6-三甲基苯基（a），2,4-二甲基苯基（b），2-甲氧基苯基（c），2,6-二异丙基苯基（d））。这些复合物使用1H NMR，13C NMR，31P NMR，IR，UV-Vis，HRMS和TGA进行表征。配合物1a，1d，2a和2d的分子结构通过单晶晶体学确定，揭示了伪八面体钢琴凳的几何形状。在这种布置中，钌金属以一个氯化物和N，N-配体为碱与粪便顶点处的芳烃配体配位。
• Synthesis, spectral characterization, properties and structures of copper(I) complexes containing novel bidentate iminopyridine ligands
  作者：Saeed Dehghanpour、Nouri Bouslimani、Richard Welter、Fresia Mojahed

  DOI：10.1016/j.poly.2006.08.011

  日期：2007.1

  Four new ligands, (4-methyl-phenyl)-pyridin-2-ylmethylene-amine (A), (2,3-dimethyl-phenyl)-pyridin-2-ylmethylene-amine (B), (2,4-dimethyl-phenyl)-pyridin-2-ylmethylene-amine (C) and (2,5-dimethyl-phenyl)-pyridin-2-ylmethylene-amine (D), and their corresponding copper(I) complexes, [Cu(A)(2)]ClO4 (1a), [Cu(B)(2)]ClO4 (1b), [Cu(C)(2)]ClO4 (1c), [Cu(D)(2)]ClO4 (1d), [Cu(A)(PPh3)(2)]ClO4 (2a), [Cu(B)(PPh3)(2)]ClO4 (2b), [Cu(C)(PPh3)(2)]ClO4 (2c) and [Cu(D)(PPh3)(2)]ClO4 (2d), have been synthesized and characterized by CHN analyses, H-1 and C-13 NMR, IR and UV-Vis spectroscopy. The crystal structures of [Cu(B)(2)]ClO4 (1b), [Cu(C)(2)]ClO4 (1c) and [Cu(A)(PPh3)(2)]ClO4 center dot 1/2CH(3)CN (2a) were determined from single crystal X-ray diffraction. The coordination polyhedron about the copper(I) center in the three complexes is best described as a distorted tetrahedron. A quasireversible redox behavior is observed for the complexes. (c) 2006 Elsevier Ltd. All rights reserved.