N,N-bis-oxiranylmethyl-p-toluidine | 19614-68-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N,N-bis-oxiranylmethyl-p-toluidine
• 英文别名: N,N-Bis-oxiranylmethyl-p-toluidin；N,N-diglycidyltoluidine；NoName_3845；4-methyl-N,N-bis(oxiran-2-ylmethyl)aniline
• CAS: 19614-68-7
• 化学式: C₁₃H₁₇NO₂
• 分子量: 219.283
• InChiKey: GTYAMROJMXVPHD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  16
• 可旋转键数：
  5
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.54
• 拓扑面积：
  28.3
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  N,N-bis-oxiranylmethyl-p-toluidine 在 盐酸 作用下， 生成 N,N-bis-(3-chloro-2-hydroxy-propyl)-p-toluidine
  参考文献：
  名称：

  Notes

  摘要：

  DOI：

  10.1039/jr9500003690
• 作为产物：
  描述：

  N,N-bis-(3-chloro-2-hydroxy-propyl)-p-toluidine 在 sodium hydroxide 作用下， 生成 N,N-bis-oxiranylmethyl-p-toluidine
  参考文献：
  名称：

  Chezlov, I. G.; Zavlin, P. M.; Kuznetsov, L. L., Russian Journal of Applied Chemistry, 1998, vol. 71, # 1, p. 155 - 161

  摘要：

  DOI：

文献信息

• [EN] IMPROVEMENTS IN OR RELATING TO CURATIVES<br/>[FR] AMÉLIORATIONS APPORTÉES OU SE RAPPORTANT À DES AGENTS DE DURCISSEMENT
  申请人：HEXCEL COMPOSITES LTD

  公开号：WO2020216688A1

  公开（公告）日：2020-10-29

  The host compound in a clathrate is an amino or hydroxyl containing aromatic phosphorous compound, clathrates containing a resin curative and their use in curable resin compositions to produce moulded articles particularly fibre reinforced articles.

  在蛛网状化合物中的宿主化合物是一种含氨基或羟基的芳香磷化合物，这些蛛网状化合物含有树脂固化剂，可用于可固化树脂组合物中，以生产模塑制品，特别是纤维增强制品。
• CLATHRATE COMPOUND, CURING CATALYST, COMPOSITION FOR FORMING CURED RESIN, AND CURED RESIN
  申请人：KANEKO Masami

  公开号：US20120088920A1

  公开（公告）日：2012-04-12

  A curing catalyst (clathrate compound) for which the curing reaction is suppressed at low temperatures, allowing an improvement in the one-pot stability, but which can effectively cure a resin upon heat treatment. The clathrate compound includes at least an isophthalic acid compound represented by Formula (I), where R 1 represents a C1 to C6 alkyl group, a C1 to C6 alkoxy group, a nitro group, or a hydroxyl group, and an imidazole compound represented by a Formula (II) where R 2 represents a hydrogen atom, a C1 to C10 alkyl group, a phenyl group, a benzyl group, or a cyanoethyl group, and R 3 to R 5 each independently represents a hydrogen atom, a nitro group, or a halogen atom, or a C1 to C20 alkyl group, phenyl group, benzyl group, or C1 to C20 acyl group that may have a substituent.

  一种治疗催化剂（包合物），其在低温下抑制固化反应，从而提高一锅稳定性，但可以在热处理时有效固化树脂。包合物至少包含一个由式（I）表示的异苯二甲酸化合物，其中R1代表C1至C6烷基，C1至C6烷氧基，硝基或羟基，以及由式（II）表示的咪唑化合物，其中R2代表氢原子，C1至C10烷基，苯基，苄基或氰乙基，R3至R5各自独立地代表氢原子，硝基或卤素原子，或C1至C20烷基，苯基，苄基或可能具有取代基的C1至C20酰基。
• SECONDARY AMINOSILANES
  申请人：SIKA TECHNOLOGY AG

  公开号：US20130281562A1

  公开（公告）日：2013-10-24

  The present disclosure invention relates to novel secondary aminosilanes, a method for producing same, and the use thereof. The secondary aminosilanes can be produced from readily available reactants in a simple manner. The secondary aminosilanes are characterized for example by a low viscosity and are well suited for producing silane-functional polymers that have a low viscosity, fast curing, and good thermal stability.

  本公开的发明涉及新型二次氨基硅烷、其生产方法以及应用。这些二次氨基硅烷可以从易得的反应物中简单地生产出来。这些二次氨基硅烷具有低粘度等特点，非常适合用于生产具有低粘度、快速固化和良好热稳定性的硅烷功能聚合物。
• [EN] 1-IMIDAZOLYMETHYL-SUBSTITUTED-2-NAPHTOLS AND THEIR USE AS ACCELERATORS FOR LOW-TEMPERATURE CURING<br/>[FR] 1-IMIDAZOLYMETHYLE-SUBSTITUTE-2-NAPHTOLS ET LEUR UTILISATION EN TANT QU'ACCELERATEURS POUR UN DURCISSEMENT A FAIBLE TEMPERATURE
  申请人：HUNTSMAN ADV MAT SWITZERLAND

  公开号：WO2004092141A1

  公开（公告）日：2004-10-28

  Compounds of the general formulae (I) and (II): where R1, R2 and R3 each independently of one another are H; C1-17alkyl; C3-12cycloalkyl, optionally substituted by C1-4alkyl groups; C4-20cycloalkyl-alkyl, optionally substituted by C1-4alkyl groups; C6-10, aryl, optionally substituted by 1-3 C1-4alkyl groups, -CN, Hal, OH, or C1-10alkoxy; C7-15phenylalkyl, optionally substituted by 1-3 C1-­4alkyl groups; C3-12alkenyl; C3-12alkynyl; or aromatic or aliphatic C3-12acyl; R4, R5, R6, R7, R8, and R9 each independently of one another are H; C1-17alkyl; C3-12Ccycloalkyl, optionally substituted by C1-4alkyl groups; C4-­20cycloalkyl-alkyl, optionally substituted by C1-4alkyl groups; C6-10aryl, optionally substituted by 1-3 C1-4alkyl groups; C7-15phenylalkyl, optionally substituted by 1-3 C1-4alkyl groups; C3-17alkenyl; C3-12alkynyl; C1-12alkoxy; or OH; for formula (1) R is C1-12alkyl; C3-12cycloalkyl, optionally substituted by C1-4alkyl groups; C4-20cycloalkyl­alkyl, optionally substituted by C1-4alkyl groups; C6-10aryl, optionally substituted by 1-3 C1-4alkyl groups; C7­-15phenylalkyl, optionally substituted by 1-3 C1-4alkyl groups; C3-12alkenyl; or C3-12alkynyl; and for formula (II) n = 2 - 12; as accelerators in curable epoxy resin compositions which are used as a compression moulding compound, sinter powder, encapsulating system, or casting resin, or for producing prepregs and laminates having very good interlaminar shear strength values using the resin infusion method, wet layup method and injection methods, for producing components, especially components of large surface area.

  通式(I)和(II)的化合物：其中R1、R2和R3各自独立地为H；C1-17烷基；C3-12环烷基，可选地被C1-4烷基基团取代；C4-20环烷基-烷基，可选地被C1-4烷基基团取代；C6-10芳基，可选地被1-3个C1-4烷基基团，-CN，Hal，OH或C1-10烷氧基取代；C7-15苯基烷基，可选地被1-3个C1-4烷基基团取代；C3-12烯基；C3-12炔基；或芳香或脂肪C3-12酰基；R4、R5、R6、R7、R8和R9各自独立地为H；C1-17烷基；C3-12环烷基，可选地被C1-4烷基基团取代；C4-20环烷基-烷基，可选地被C1-4烷基基团取代；C6-10芳基，可选地被1-3个C1-4烷基基团取代；C7-15苯基烷基，可选地被1-3个C1-4烷基基团取代；C3-17烯基；C3-12炔基；C1-12烷氧基；或OH；对于式(1)，R为C1-12烷基；C3-12环烷基，可选地被C1-4烷基基团取代；C4-20环烷基烷基，可选地被C1-4烷基基团取代；C6-10芳基，可选地被1-3个C1-4烷基基团取代；C7-15苯基烷基，可选地被1-3个C1-4烷基基团取代；C3-12烯基；或C3-12炔基；对于式(II)，n = 2-12；作为可固化环氧树脂组合物的催化剂，该组合物用作压缩成型复合材料、烧结粉末、封装系统或浇注树脂，或用于使用树脂渗透法、湿层压法和注射法制备具有非常好的层间剪切强度值的预浸料和层压板，用于制造特别是大面积构件。
• [EN] UREA DERIVATIVES AND THEIR USE AS CURATIVES AND CURATIVE ACCELERATORS FOR RESIN SYSTEMS<br/>[FR] DÉRIVÉS D'URÉE ET LEUR UTILISATION EN TANT QU'AGENTS DE DURCISSEMENT ET ACCÉLÉRATEURS DE DURCISSEMENT POUR DES SYSTÈMES DE RÉSINE
  申请人：HEXCEL COMPOSITES LTD

  公开号：WO2022034201A1

  公开（公告）日：2022-02-17

  Bisorthohydroxy aromatic urones and their use as curatives and cure accelerators in resin systems particularly epoxy resin systems provide formulations with good outlife, low curing temperatures and desirable glass transition temperatures after curing, they are particularly useful in prepregs used in the production of components for the aerospace and wind turbine industries.

  Bisorthohydroxy芳香族尿酮及其在树脂体系中作为治疗剂和治疗加速剂的应用，特别是环氧树脂体系，提供具有良好使用寿命，低固化温度和固化后理想的玻璃转移温度的配方，它们在用于航空航天和风力涡轮机行业零部件生产的预浸料中特别有用。