2-hex-1-enyl-thiophene | 73350-61-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 杂芳族化合物
• 英文名称: 2-hex-1-enyl-thiophene
• 英文别名: 2-Hex-1-enyl-thiophen；2-[(E)-hex-1-enyl]thiophene
• CAS: 73350-61-5
• 化学式: C₁₀H₁₄S
• 分子量: 166.287
• InChiKey: SQUMLJZLJQVYOB-FNORWQNLSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.2
• 重原子数：
  11
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  28.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 aluminum oxide 作用下， 250.0 ℃ 、6.67 kPa 条件下， 生成 2-hex-1-enyl-thiophene
  参考文献：
  名称：

  Condensations of Aldehydes with 2-Thienyllithium, 2-Thienylsodium and 2-Thienylmagnesium Bromide

  摘要：

  DOI：

  10.1021/ja01590a053

文献信息

• 2,2’‐Biquinoline‐Based Recyclable Electroauxiliaries for the Generation of Alkyl Radicals via C−C Bond Cleavage
  作者：Shahilan Ratnam、Shreya Unone、Daniel Janssen‐Müller

  DOI：10.1002/chem.202301685

  日期：2023.9.6

  electroauxiliaries have successfully been developed as suitable reagents for the site-selective generation of alkyl radicals. Primary, secondary and tertiary alkyl radicals could be generated and several free radical reactions could be studied. The platform has the advantage of recyclability, which makes these alkyl radical precursors superior compared to previous N-heterocyclic electroauxiliaries.

  基于 2,2'-联喹啉的电助剂已成功开发为适合位点选择性生成烷基自由基的试剂。可以产生伯、仲和叔烷基自由基，并且可以研究几种自由基反应。该平台具有可回收性的优势，这使得这些烷基自由基前体比以前的N-杂环电助剂更加优越。
• Photoelectric conversion element, dye-sensitized solar cell, metal complex dye, dye composition, and oxide semiconductor electrode
  申请人：FUJIFILM Corporation

  公开号：US11094474B2

  公开（公告）日：2021-08-17

  A photoelectric conversion element includes a conductive support, a photoconductor layer including an electrolyte, a charge transfer layer including an electrolyte, and a counter electrode, in which the photoconductor layer has semiconductor fine particles carrying a metal complex dye represented by a specific formula.

  一种光电转换元件包括导电支架、包括电解质的光电导体层、包括电解质的电荷转移层和对电极，其中光电导体层具有携带以特定公式表示的金属络合染料的半导体微粒。
• An Amphiphilic Resin-Supported Palladium Catalyst for High-Throughput Cross-Coupling in Water
  作者：Yasuhiro Uozumi、Yasushi Nakai

  DOI：10.1021/ol0264298

  日期：2002.8.1

  The Suzuki-Miyaura coupling of aryl halides (8 varieties) and aryl- or vinylboronic acids (12 varieties) took place in water in the presence of a palladium complex of an amphiphilic polystyrene-poly(ethylene glycol) copolymer resin-supported N-anchored 2-aza-1,3-bis(diphenylphosphino)propane ligand and potassium carbonate to give uniform and quantitative yields of the corresponding biaryls (96 varieties).
• Carbon-carbon bond formation via opening of epoxysilanes with organometals containing lithium and copper
  作者：Yantao Zhang、Joseph A. Miller、Eiichi Negishi

  DOI：10.1021/jo00270a009

  日期：1989.4
• ZHANG, Y.;MILLER, J. A.;NEGISHI, EI-ICHI, J. ORG. CHEM., 54,(1989) N, C. 2043-2044
  作者：ZHANG, Y.、MILLER, J. A.、NEGISHI, EI-ICHI

  DOI：——

  日期：——