1-cyano-1-cyclohexyl dithiobenzoate | 220182-89-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-cyano-1-cyclohexyl dithiobenzoate
• 英文别名: (1-cyanocyclohexyl) benzenecarbodithioate
• CAS: 220182-89-8
• 化学式: C₁₄H₁₅NS₂
• 分子量: 261.412
• InChiKey: FYUMHHFLRJERAM-UHFFFAOYSA-N

物化性质

• 沸点：
  427.1±47.0 °C(Predicted)
• 密度：
  1.20±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  17
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  81.2
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  双(硫代苯甲酰基)二硫化物 、 1,1'-偶氮(氰基环己烷) 以 乙酸乙酯 为溶剂， 反应 48.0h， 生成 1-cyano-1-cyclohexyl dithiobenzoate
  参考文献：
  名称：

  Synthesis of dithioester chain transfer agents and use of bis(thioacyl) disulfides or dithioesters as chain transfer agents

  摘要：

  本发明涉及通过双(硫酰基)二硫化物、硫代乙醇或乙烯基二硫醚与自由基（可选地在单体存在下）反应合成二硫代羧酸酯的方法。本发明还涉及利用这些二硫代酯作为聚合调节剂（链转移剂）合成聚合物的方法或利用双(硫酰基)二硫化物在原位产生二硫代酯链转移剂的方法。

  公开号：

  US06512081B1

文献信息

• POLYMERISATION USING CHAIN TRANSFER AGENTS
  申请人：Perrier Sebastian

  公开号：US20090215965A1

  公开（公告）日：2009-08-27

  The invention provides a process for synthesising functionalised chain transfer polymers of Formula (1) or Formula (2) using thiocarbonyl thio compounds as chain transfer agents. Why R1 is a moiety comprising a functional group; Q is obtained from an olefinically unsaturated monomer; R′ is selected from the group consisting of alkyl, substituted alkyl, alkoxy, substituted alkoxy, an aromatic saturated or unsaturated carbocyclic or heterocyclic ring, optionally substituted with one or more substituents, amino alkyl, cyanoalkyl, hydroxylalkyl, saturated and unsaturated amido; an organometallic species, a polymer chain and any of the foregoing substituted with one or more CN or OH groups; q=an integer of at least 2; p=an integer of at least 1. Chain transfer agents and polymers produced by the method are also provided.

  该发明提供了一种合成功能化链转移聚合物的方法，使用硫代羰基硫化合物作为链转移剂，其化学式为(1)或(2)。其中，R1是包含功能基团的基团；Q是从烯烃不饱和单体获得的；R′选自包括烷基、取代烷基、烷氧基、取代烷氧基、芳香饱和或不饱和碳环或杂环环，可选地取代一个或多个取代基，氨基烷基、氰基烷基、羟基烷基、饱和和不饱和酰胺的基团；有机金属物种、聚合物链和上述任何一种基团，其中取代有一个或多个CN或OH基团；q至少为2的整数；p至少为1的整数。该方法还提供了链转移剂和由该方法产生的聚合物。
• RESIST COMPOSITION AND PATTERN-FORMING METHOD USING SAME
  申请人：Kamimura Sou

  公开号：US20080241737A1

  公开（公告）日：2008-10-02

  A resist composition comprises (A) at least two kinds of resins each of which decomposes by the action of an acid to undergo an increase in its solubility for an alkali developer, wherein at least one kind of the resins (A) is a resin synthesized by living radical polymerization using a chain transfer agent represented by formula (I): wherein: A represents an organic group not containing hetero atoms; and Y represents an organic group capable of releasing a radical.

  一种抗蚀性组合物包括（A）至少两种树脂，每种树脂通过酸的作用分解，以增加其对碱性显影剂的溶解度，其中至少一种树脂（A）是通过使用由式（I）表示的链转移剂合成的活性自由基聚合树脂：其中：A代表不含杂原子的有机基团；Y代表能够释放自由基的有机基团。
• Synthesis of dithioester chain transfer agents and use of bis(thioacyl) disulfides or dithioesters as chain transfer agents
  申请人：E.I. DuPont Nemours and Company

  公开号：US06512081B1

  公开（公告）日：2003-01-28

  This invention relates to the synthesis of dithiocarboxylic acid esters by reaction of bis(thioacyl) disulphides, thioacetals or vinylidane bis(thioether) with free-radicals (optionally in the presence of monomers). The invention also relates to processes for the synthesis of polymers utilising these dithioesters as polymerisation regulators (chain transfer agents) or to the use of bis(thioacyl) disulphides to generate dithioester chain transfer agents in situ.

  本发明涉及通过双(硫酰基)二硫化物、硫代乙醇或乙烯基二硫醚与自由基（可选地在单体存在下）反应合成二硫代羧酸酯的方法。本发明还涉及利用这些二硫代酯作为聚合调节剂（链转移剂）合成聚合物的方法或利用双(硫酰基)二硫化物在原位产生二硫代酯链转移剂的方法。
• Resist composition and pattern-forming method using same
  申请人：FUJIFILM Corporation

  公开号：EP1972641A2

  公开（公告）日：2008-09-24

  A resist composition comprises (A) at least two kinds of resins each of which decomposes by the action of an acid to undergo an increase in its solubility for an alkali developer, wherein at least one kind of the resins (A) is a resin synthesized by living radical polymerization using a chain transfer agent represented by formula (I): wherein: A represents an organic group not containing hetero atoms; and Y represents an organic group capable of releasing a radical.

  一种抗蚀剂组合物包括 (A) 至少两种树脂，每种树脂在酸的作用下分解，对碱显影剂的溶解度增加，其中至少一种树脂 (A) 是使用由式 (I) 表示的链转移剂通过活自由基聚合合成的树脂： 其中 A 代表不含杂原子的有机基团；以及 Y 代表能够释放自由基的有机基团。
• SYNTHESIS OF DITHIOESTER CHAIN TRANSFER AGENTS AND USE OF BIS(THIOACYL) DISULFIDES OR DITHIOESTERS AS CHAIN TRANSFER AGENTS
  申请人：E.I. DU PONT DE NEMOURS AND COMPANY

  公开号：EP1149075A1

  公开（公告）日：2001-10-31