bis-dimethylamino-1,1 methyl-2 propane | 122713-59-1

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: bis-dimethylamino-1,1 methyl-2 propane
• 英文别名: tetra-N-methyl-isobutylidenediamine；Tetra-N-methyl-isobutylidendiamin；1,1-Bis-dimethylamino-2-methyl-propan；1-N,1-N,1-N',1-N',2-pentamethylpropane-1,1-diamine
• CAS: 122713-59-1
• 化学式: C₈H₂₀N₂
• 分子量: 144.26
• InChiKey: KRJQJLFUYCRVPM-UHFFFAOYSA-N

物化性质

• 沸点：
  128.6±8.0 °C(Predicted)
• 密度：
  0.820±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  10
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  6.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  bis-dimethylamino-1,1 methyl-2 propane 、 二甲基三甲硅基膦酸酯 以 二氯甲烷 为溶剂， 反应 1.0h， 生成 Dimethyl-1-(dimethylamino)-2-methylpropylphosphonat
  参考文献：
  名称：

  A CONVENIENT DIRECT SYNTHESIS OF α-N,N-DIALKYLAMINOPHOSPHONATES UNDER APROTIC CONDITIONS

  摘要：

  A general one-pot synthesis of N,N-dialkylaminophosphonates under aprotic conditions is proposed using aromatic, heteroaromatic or aliphatic aldehydes and N,N-dialkyl-aminosilanes under trimethylsilyltriflate catalysis.

  DOI：

  10.1080/10426509608046402
• 作为产物：
  描述：

  N,N-二甲基三甲基硅胺 、 异丁醛 在 四丁基氟化铵 溴 作用下， 以 四氯化碳 为溶剂， 反应 2.0h， 生成 bis-dimethylamino-1,1 methyl-2 propane
  参考文献：
  名称：

  Aube, Philippe; Christot, Isabelle; Combret, Jean-Claude, Bulletin de la Societe Chimique de France, 1988, # 6, p. 1009 - 1014

  摘要：

  DOI：

文献信息

• NOVEL HETEROLEPTIC IRIDIUM COMPLEXE
  申请人：Ma Bin

  公开号：US20130181190A1

  公开（公告）日：2013-07-18

  Novel heteroleptic iridium complexes are disclosed. The complexes contain a phenyl pyridine ligand and another ligand containing a dibenzofuran, dibenzothiophene, dibenzoselenophene, or carbazole linked to an imidazole or benzimidazole fragment. These complexes are useful materials when incorporated into OLED devices.

  披露了新型的异配位铱络合物。这些络合物含有一个苯基吡啶配体和另一个含有二苯并呋喃、二苯并噻吩、二苯并硒吩或咔唑的配体，该配体与咪唑或苯并咪唑片段相连。当这些络合物被纳入OLED设备时，它们是有用的材料。
• ORGANIC ELECTROLUMINESCENT MATERIALS AND DEVICES
  申请人：Universal Display Corporation

  公开号：US20160233424A1

  公开（公告）日：2016-08-11

  A compound including a ligand L 1 of Formula I, is described. In Formula I: rings A and B each independently represent a 5-membered or 6-membered carbocyclic or heterocyclic ring; X, Y, Z, and W are either carbon or nitrogen; R 1 to R 6 are selected from a variety of substituents, where adjacent substituents can be joined to form a fused ring; ligand L 1 is coordinated to a metal M by X-M and Y-M bonds; and ligand L 1 is optionally linked with other ligands to produce a tridentate, tetradentate, pentadentate or hexadentate ligand. Formulations and devices, such as an OLEDs, that include the compound that include a ligand L 1 of Formula I are also described.

  描述了一种包括化合物的配体L1的化合物。在公式I中：环A和环B分别独立表示5元或6元碳环或杂环；X、Y、Z和W为碳或氮；R1至R6从各种取代基中选择，其中相邻的取代基可以连接形成融合环；配体L1通过X-M和Y-M键与金属M配位；配体L1还可选择与其他配体连接以产生三齿、四齿、五齿或六齿配体。还描述了包含配体L1的公式I的化合物的配方和器件，例如OLEDs。
• Boehme et al., Chemische Berichte, 1959, vol. 92, p. 1608,1612
  作者：Boehme et al.

  DOI：——

  日期：——
• Benzing,E., Diss. <Marburg 1956> S. 56
  作者：Benzing,E.

  DOI：——

  日期：——
• OLEFIN OLIGOMERIZATION CATALYST AND METHOD FOR PRODUCING OLEFIN OLIGOMER IN THE PRESENCE OF THE SAME CATALYST
  申请人：MITSUI CHEMICALS, INC.

  公开号：US20200222886A1

  公开（公告）日：2020-07-16

  A method for producing an olefin oligomer is disclosed, in which an olefin oligomerization reaction is performed in the presence of an olefin oligomerization catalyst comprising (A) a chromium compound, (B) an amine compound of the general formula (1): (R 1 to R 4 represent a group such as a hydrocarbon group, Y represents a structure represented by —CR 5 R 6 —, R 5 and R 6 represent a group such as a hydrogen atom, and Z represents an integer of 1 to 10), and (C) a compound such as an organometal compound; and the olefin oligomerization catalyst.