N-benzyl-N,N'N'-tris(3-methylpyridin-2-ylmethyl)ethylene-1,2-diamine | 260395-28-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-benzyl-N,N'N'-tris(3-methylpyridin-2-ylmethyl)ethylene-1,2-diamine
• 英文别名: N-benzyl-N,N',N'-tris[(3-methylpyridin-2-yl)methyl]ethane-1,2-diamine
• CAS: 260395-28-6
• 化学式: C₃₀H₃₅N₅
• 分子量: 465.641
• InChiKey: AQWLQPOKOMKMPI-UHFFFAOYSA-N

物化性质

• 沸点：
  582.7±45.0 °C(Predicted)
• 密度：
  1.126±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  35
• 可旋转键数：
  11
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.3
• 拓扑面积：
  45.2
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  (3-甲基吡啶-2-基)甲醇 、 N-苄基乙二胺 生成 N-benzyl-N,N'N'-tris(3-methylpyridin-2-ylmethyl)ethylene-1,2-diamine
  参考文献：
  名称：

  Bleach and oxidation catalyst

  摘要：

  公开号：

  EP1001009B1

文献信息

• Bleaching and dye transfer inhibiting composition and method for laundry fabrics
  申请人：Unilever Home & Personal Care USA, Division of Conopco, Inc.

  公开号：US20020010121A1

  公开（公告）日：2002-01-24

  A bleaching composition for laundry fabrics is provided, comprising: hydrogen peroxide or a source of hydrogen peroxide; a bleach catalyst comprising a ligand which forms a complex with a transition metal, the complex catalysing bleaching of stains in the presence of peroxygen bleach or a peroxy-based or -generating bleach system; and a dye transfer inhibiting agent. The bleaching composition provides effective bleaching performance on fabric stains without unacceptable transfer of dyes between fabrics.

  提供了一种用于洗衣织物的漂白组合物，包括：过氧化氢或过氧化氢源；漂白催化剂，包括与过渡金属形成配合物的配体，该配合物在过氧化物漂白剂或过氧基漂白剂系统存在下催化漂白污渍；和染料转移抑制剂。该漂白组合物在不会出现织物之间不可接受的染料转移的情况下，能够有效漂白织物上的污渍。
• Composition and method for bleaching a substrate
  申请人：Unilever Home & Personal Care USA, Division of Conopco, Inc.

  公开号：US20030045442A1

  公开（公告）日：2003-03-06

  The invention relates to a liquid bleaching composition for catalytically bleaching substrates, especially laundry fabrics, with atmospheric oxygen or air. A liquid bleaching composition is provided comprising an organic substance which forms a complex with a transition metal, the complex catalysing bleaching of a substrate by atmospheric oxygen, and a liquid carrier or solvent, wherein the composition is substantially devoid of peroxygen bleach or a peroxy-based or -generating bleach system. Also provided is a method of bleaching a substrate comprising applying the liquid bleaching composition to the substrate. Also provided is a method of treating a textile by contacting the textile with the liquid bleaching composition, whereby the complex catalyses bleaching of the textile by atmospheric oxygen after the treatment.

  本发明涉及一种用于催化漂白基材，特别是洗涤织物，使用大气氧气或空气的液体漂白组合物。提供了一种液体漂白组合物，其中包括一种有机物质，该有机物质与过渡金属形成复合物，该复合物通过大气氧气催化基材的漂白，以及液体载体或溶剂，其中该组合物基本上不含过氧化物漂白剂或过氧化物基或生成漂白系统。还提供了一种漂白基材的方法，包括将液体漂白组合物应用于基材。还提供了一种通过将液体漂白组合物接触织物来处理纺织品的方法，在处理后，复合物通过大气氧气催化织物的漂白。
• Enzymatic detergent compositions
  申请人：Unilever Home & Personal Care USA, Division of Conopco, Inc.

  公开号：US20030050211A1

  公开（公告）日：2003-03-13

  There is provided an enzymatic detergent composition which comprises: (a) surfactant; (b) 10-20,000 LU per gram of the detergent composition of a lipolytic enzyme obtainable from Humicola lanuginosa, Pseudomonas pseudoalcaligenes, Rhizomucor miehei and (c) a non-cross-bridged polydentate N-donor ligand capable of forming a complex with a transition metal, wherein said complex is capable of catalysing the bleaching of stains on fabrics by means of atmospheric oxygen.

  提供了一种酶性洗涤剂组合物，其包括：（a）表面活性剂；（b）每克洗涤剂组合物10-20,000 LU的脂肪水解酶，可从Humicola lanuginosa，Pseudomonas pseudoalcaligenes，Rhizomucor miehei中获得；以及（c）一种非交联多齿N-给体配体，能够与过渡金属形成配合物，该配合物能够通过大气氧气催化漂白织物上的污渍。
• Support-fixed bleaching catalyst complex compounds suitable as catalysts for peroxygen compounds
  申请人：——

  公开号：US20040266641A1

  公开（公告）日：2004-12-30

  The present invention relates to support-fixed bleaching catalyst(s)suitable or the catalysis of peroxide compounds, characterized in that the support-fixed bleaching catalyst(s) is/are covalently bonded to a support by means of at least one organic ligand of the bleaching catalyst. The bleaching catalyst(s) form(s) a complex with at least on transition metal. The invention further relates to support-fixed bleaching catalysts for the catalysis of peroxide compounds, where at least one ligand, covalently bonded to a support, is a transition-metal-free ligand, which chelates with transition metal, derived from another source, preferably from the bleaching composition and/or added water and thus forms the complex with a transition metal.

  本发明涉及适用于过氧化物催化的支撑固定漂白催化剂，其特征在于通过漂白催化剂的至少一个有机配体与支撑物共价键合而将支撑固定漂白催化剂共价键合到支撑物上。漂白催化剂与至少一种过渡金属形成复合物。本发明还涉及适用于过氧化物催化的支撑固定漂白催化剂，其中至少一个共价键合到支撑物上的配体是无过渡金属配体，它与来自另一来源的过渡金属螯合，优选地来自漂白组合物和/或加入的水，并因此形成与过渡金属的复合物。
• Targeted moieties for use in bleach catalysts
  申请人：Unilever Home & Personal Care USA, Division of Conopco, Inc.

  公开号：US20020049146A1

  公开（公告）日：2002-04-25

  There is provided a targeted bleaching composition comprising an organic substance which forms a complex with a transition metal, the complex catalyzing bleaching of a substrate by a precursor selected from atmospheric oxygen and/or a peroxyl species. The complex is bound to a recognizing portion having a high binding affinity for stains present on fabrics.

  提供了一种有针对性的漂白组合物，包括一种有机物质，该有机物质与过渡金属形成配合物，该配合物通过来自大气氧气和/或过氧基物质的前体催化基质的漂白。该配合物与具有高亲和力的识别部分结合，以便于对织物上的污渍进行识别。