9,10-dihydro-9,10-dioxo-1,5-anthracenedicarboxylic acid | 10254-93-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 9,10-dihydro-9,10-dioxo-1,5-anthracenedicarboxylic acid
• 英文别名: 9,10-dioxo-9,10-dihydroanthracene-1,5-dicarboxylic acid；9,10-anthraquinone-1,5-dicarboxylic acid；9,10-antraquinone-1,5-dicarboxylic acid；9,10-dioxo-9,10-dihydro-anthracene-1,5-dicarboxylic acid；9,10-Dioxo-9,10-dihydro-anthracen-1,5-dicarbonsaeure；Anthrachinon-dicarbonsaeure-(1.5)；Anthrachinon-1.5-dicarbonsaure；9,10-dioxoanthracene-1,5-dicarboxylic acid
• CAS: 10254-93-0
• 化学式: C₁₆H₈O₆
• 分子量: 296.236
• InChiKey: NPJWMYCZWPHPIC-UHFFFAOYSA-N

物化性质

• 熔点：
  >390 °C
• 沸点：
  647.3±55.0 °C(Predicted)
• 密度：
  1.608±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  22
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  109
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  9,10-dihydro-9,10-dioxo-1,5-anthracenedicarboxylic acid 在 sodium hydroxide 、 sodium dithionite 作用下， 生成 9-hydroxy-anthracene-1,5-dicarboxylic acid
  参考文献：
  名称：

  Scholl; Boettger, Chemische Berichte, 1930, vol. 63, p. 2440,2445

  摘要：

  DOI：
• 作为产物：
  描述：

  1,5-dicyano-9,10-anthraquinone 在 sodium hydroxide 作用下， 生成 9,10-dihydro-9,10-dioxo-1,5-anthracenedicarboxylic acid
  参考文献：
  名称：

  Scholl; Hass; Meyer, Chemische Berichte, 1929, vol. 62, p. 113

  摘要：

  DOI：

文献信息

• Aluminum Metal Organic Framework Materials
  申请人：TEXAS A&M UNIVERSITY SYSTEM

  公开号：US20150152123A1

  公开（公告）日：2015-06-04

  The invention relates to monocrystalline single crystals of metal-organic framework materials comprising at least one aluminium metal ion, processes for preparing the same, methods for employing the same, and the use thereof. The invention also relates to monocrystalline aluminium metal-organic frameworks.

  该发明涉及至少含有一种铝金属离子的金属-有机框架材料的单晶单晶体，以及其制备方法、使用方法和用途。该发明还涉及单晶铝金属-有机框架。
• Optically Active Triptycenes, V. Synthesis, Optical Resolution and Absolute Configuration of 2,7-Disubstituted Triptycenes.
  作者：Masaaki Kuritani、Yoshiteru Sakata、Fumio Ogura、Masazumi Nakagawa

  DOI：10.1246/bcsj.46.605

  日期：1973.2

  retaining C2-axis of symmetry was synthesized from 1,5-dichloroanthraquinone. Optical resolution of the triptycene afforded (+)- and (−)-enantiomers. The absolute configuration of (+)-2,7-dicarboxytriptycene was determined as 1R,6R by chemical correlation with (+)-2-methoxy-7-methoxycarbonyltriptycene which has 1R,6S configuration as confirmed by chemical transformation and X-ray structure analysis using

  保留 C2 对称轴的 2,7-Dicarboxytriptycene 由 1,5-二氯蒽醌合成。三苯乙烯的光学拆分提供了 (+)- 和 (-)- 对映异构体。(+)-2,7-dicarboxytriptycene 的绝对构型通过化学相关确定为 1R,6R 与具有 1R,6S 构型的 (+)-2-methoxy-7-methoxycarbonyltriptycene 经化学转化和 X 射线结构确认使用 Bijvoet 方法进行分析。以(+)-2,7-二羧基三烯为原料，制备了一系列具有1R,6R构型的2,7-二取代三烯。
• MODIFIER FOR AROMATIC POLYESTER AND AROMATIC POLYESTER RESIN COMPOSITION COMPRISING THE SAME
  申请人：TABATA Masayoshi

  公开号：US20110224343A1

  公开（公告）日：2011-09-15

  The present invention provides a modifier for aromatic polyesters which enhances the melt fluidity of aromatic polyesters without a significant decrease in the heat resistance of the aromatic polyesters, and an aromatic polyester resin composition including the modifier for aromatic polyesters. The present invention relates to a modifier for aromatic polyesters comprising polyhydric phenol residues and residues of aromatic polycarboxylic acid, acid halide or acid anhydride thereof, and the modifier comprises a material having a structure composed of a first residue selected from the group consisting of divalent residues represented by Formula (I): —Ar—W 1 x —Ar— and by Formula (II): —Ar—, the first residues being bonded to two identical or different second residues selected from the group consisting of monovalent residues represented by Formula (III): and monovalent residues represented by Formula (IV): —O—C(O)—R 7 —.

  本发明提供了一种用于芳香族聚酯的改性剂，可以增强芳香族聚酯的熔融流动性，而不明显降低芳香族聚酯的耐热性，以及包括该改性剂的芳香族聚酯树脂组合物。本发明涉及一种用于芳香族聚酯的改性剂，包括多羟基酚残基和芳香族多羧酸、酸卤或其酸酐残基，该改性剂包括具有以下结构的材料：第一残基，选择自由式(I)所代表的二价残基：—Ar—W1x—Ar—和自由式(II)所代表的：—Ar—，第一残基与选择自由式(III)所代表的单价残基：和自由式(IV)所代表的单价残基：—O—C(O)—R7—的两个相同或不同的第二残基结合。
• Syntheses, crystal structures and properties of complexes with two anthracene-based bulky backbone ligands
  作者：Jun-Jie Wang、Dao-Jun Zhang、Ren-Chun Zhang、Xiao-Li Lu、Er-Ni Wang、Feng Jin、Yun-Feng Shi

  DOI：10.1007/s11243-014-9891-0

  日期：2015.2

  bis-monodentate bridging mode in complex 1, whereas HL2 adopts monodentate and bidentate bridging modes in 2 and a tridentate bridging mode in 3. The chelating ligands phen and pp give rise to a 1D zigzag chain in complexes 1 and 3, and a binuclear structure in 2, by preventing the formation of higher-dimensional structures. Notably, the anions play an important role in the structure of complex 3. In addition, the

  摘要 三种金属有机配合物与两个蒽基庞大的骨架配体 9,10-dioxo-9,10-dihydroanthracene-1,5-二羧酸 (H2L1) 和 2-苯基喹啉-4-羧酸 (HL2)，即 [Mn(L1)0.5(L1)0.5(phen)(H2O)2](H2O)1.5}∞ (1), [Mn2(L2)4(phen)2(H2O)2](H2O)2 (2)和 [Cd3(L2)2(pp)2Cl4]∞ (3) (phen = 1,10-菲咯啉, pp = 3-(2-pyridyl)pyrazole)，已被合成和表征。X 射线单晶衍射表明 H2L1 在配合物 1 中采用双单齿桥接模式，而 HL2 在配合物 2 中采用单齿和双齿桥接模式，在 3 中采用三齿桥接模式。螯合配体 phen 和 pp 产生一维通过阻止高维结构的形成，复合物 1 和 3 中的锯齿形链和 2 中的双核结构。尤其，阴离子在配合物 3
• [EN] PROCESS FOR THE PREPARATION OF A METAL-ORGANIC COMPOUND<br/>[FR] PROCÉDÉ DE PRÉPARATION D'UN COMPOSÉ ORGANOMÉTALLIQUE
  申请人：UNIV BELFAST

  公开号：WO2014191725A1

  公开（公告）日：2014-12-04

  A process for the preparation of a metal-organic compound, said metal- organic compound comprising at least one metal ion and at least one organic ligand, wherein said organic ligand is capable of associating with said metal ion, comprising at least the steps of; providing a first reactant comprising at least one metal in ionic form; providing a second reactant comprising at least one organic ligand capable of associating with said metal in ionic form; and admixing said first and second reactants under conditions of prolonged and sustained pressure and shear sufficient to synthesise said metal-organic compound.

  一种制备金属有机化合物的方法，所述金属有机化合物包括至少一个金属离子和至少一个有机配体，其中所述有机配体能够与所述金属离子结合，包括至少以下步骤：提供包含至少一种金属的离子形式的第一反应物；提供包含至少一种能够与所述离子形式的金属结合的有机配体的第二反应物；并在持续和持续的压力和剪切条件下混合所述第一和第二反应物，以合成所述金属有机化合物。