p-(1,1-Dimethyl-pentyl)-phenol | 30784-31-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: p-(1,1-Dimethyl-pentyl)-phenol
• 英文别名: 2-Methyl-2-(4-hydroxy-phenyl)-hexan；4-(1,1-Dimethyl-pentyl)-phenol；4-Hydroxy-1-(1.1-dimethyl-pentyl)-benzol；4-(1,1-Dimethylpentyl)phenol；4-(2-methylhexan-2-yl)phenol
• CAS: 30784-31-7
• 化学式: C₁₃H₂₀O
• 分子量: 192.301
• InChiKey: MVUXIDLUKLKIEJ-UHFFFAOYSA-N

物化性质

• 沸点：
  270-272 °C
• 密度：
  0.9522 g/cm3(Temp: 420 °C)

计算性质

• 辛醇/水分配系数(LogP)：
  4.9
• 重原子数：
  14
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.54
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  p-(1,1-Dimethyl-pentyl)-phenol 在 乙醇 、 potassium chloride 、 三氯氧磷 作用下， 生成 phosphoric acid diethyl ester-[4-(1,1-dimethyl-pentyl)-phenyl ester]
  参考文献：
  名称：

  Katyshkina; Kraft, Zhurnal Obshchei Khimii, 1956, vol. 26, p. 3060,3062

  摘要：

  DOI：
• 作为产物：
  描述：

  1-(1,1-dimethyl-pentyl)-4-nitro-benzene 生成 p-(1,1-Dimethyl-pentyl)-phenol
  参考文献：
  名称：

  Revision of species of the “Oligia” semicana group (Lepidoptera: Noctuidae) with descriptions of a new genus and 12 new species

  摘要：

  AbstractThe name Neoligiagen.nov. is proposed for the "Oligia" semicana (Walker) species group in North America and 12 species, N. rubirena sp.nov., N. pagosa sp.nov., N. hardwicki sp.nov、N. inermis sp.nov.、N. invenusta sp.nov.、N. albirena sp.nov.、N. lancea sp.nov.、N. elephas sp.nov.、N. lillooet sp.nov.、N. surdirena sp.nov.、N. canadensis sp.nov.和 N. atlantica sp.nov.等 12 个种。Hadenella laevigata Smith 与 Hadena tonsa Grote 同源（同义恢复），Hadena hausta Grote 与 Miana semicana Walker 同源（同义恢复）。所有物种的成体以及已知的雄性和雌性生殖器均附有插图。

  DOI：

  10.4039/ent134157-2

文献信息

• The Conversion of Phenols to the Corresponding Aryl Halides Under Mild Conditions
  作者：John Huffman、Alicia Thompson、George Kabalka、Murthy Akula

  DOI：10.1055/s-2005-861791

  日期：——

  Mild, novel procedures have been developed for the syntheses of aryl halides from the corresponding phenols in modest to good yields via boronate ester intermediates.

  已经开发了温和、新颖的方法，用于通过硼酸酯中间体从相应的酚类以适度至良好的产率合成芳基卤化物。
• Mechanism of the solvolysis of allylic diphenyl phosphates in phenol
  作者：J. A. Miller

  DOI：10.1039/j29680001427

  日期：——

  by solvolysis of allylic diphenyl phosphates in phenol is shown to be a carbonium ion process, and to be autocatalysed by diphenyl hydrogen phosphate. The products obtained in these solvolyses have been compared with those obtained from the alkylation of phenol by diphenyl hydrogen phosphate and olefins, under comparable conditions. These studies have shown that alkylation on carbon is favoured with

  通过烯丙基磷酸二苯酯在苯酚中的溶剂分解，苯酚的烷基化被证明是一个碳离子过程，并且被磷酸二苯氢酯自动催化。在可比较的条件下，将这些溶剂分解中获得的产物与由苯酚通过磷酸二苯氢酯和烯烃烷基化获得的产物进行了比较。这些研究表明，碳原子上的烷基化有利于更稳定的碳原子离子，例如叔或3,3-二甲基烯丙基，而氧原子上的烷基化则有利于仲碳原子离子。烯丙基磷酸二苯酯溶剂分解的初始烷基化产物的酸催化重排至2-甲基香豆素已显示在分子内。
• DIBENZORYLENETETRACARBOXIMIDES AS INFRARED ABSORBERS
  申请人：Koenemann Martin

  公开号：US20100048904A1

  公开（公告）日：2010-02-25

  Dibenzorylenetetracarboximides of the general formula I in which the variables are each defined as follows: R′ are identical or different radicals: hydrogen; optionally substituted aryloxy, arylthio, hetaryloxy or hetarylthio; R are identical or different radicals: hydrogen; optionally substituted C 1 -C 30 -alkyl, C 3 -C 8 -cycloalkyl, aryl or hetaryl; m, n are each independently 0 or 1.

  一般式I的二苯并咔唑四羧酰亚胺中，变量定义如下：R′为相同或不同的基团：氢；可选择取代的芳氧基、芳硫基、杂芳氧基或杂芳硫基；R为相同或不同的基团：氢；可选择取代的C1-C30烷基、C3-C8环烷基、芳基或杂芳基；m，n各自独立地为0或1。
• Controlling solar radiation in safety glass laminates
  申请人：——

  公开号：US20020182422A1

  公开（公告）日：2002-12-05

  Plasticized polyvinyl butyral sheet containing dispersed therein, an infrared-absorbing effective amount of at least one quaterrylenetetracarboxylic diimide infrared-absorbing additive of formula I in the specification. A glass laminate having visible light transmitting and infrared light absorbing properties contains such sheet sandwiched between glass layers.

  塑化聚乙烯醇缩丁醛片材，其中分散有有效量的至少一种本规范中式 I 的季戊四羧酸二亚胺红外线吸收添加剂。具有可见光透射和红外线吸收特性的玻璃层压板包含夹在玻璃层之间的这种薄片。
• Tert alkylphenoxy substituted polycyclic compounds
  申请人：——

  公开号：US20040049030A1

  公开（公告）日：2004-03-11

  tert-Alkylphenoxy-substituted polycyclic compounds of the general formula I 1 where P is a conjugated polycyclic radical which is stable to bases and nucleophiles, optionally bears aryl substituents and contains no group from the group consisting of —CO—NH—CO—, —COOH and —CO—O—CO—; R is C 1 -C 8 -alkyl, whose carbon chain may be interrupted by one or more groups selected from the group consisting of —O—, —S—, —NR 1 —, —CO— and/or —SO 2 — and which may be monosubstituted or polysubstituted by C 1 -C 6 -alkoxy or by a 5 - to 7 -membered heterocyclic radical which is attached via a nitrogen atom and may contain further heteroatoms and be aromatic; C 5 -C 8 -cycloalkyl whose carbon chain may be interrupted by one or more groups selected from the group consisting of —O—, —S—, —NR 1 —, —CO— and/or —SO 2 — and which may be monosubstituted or polysubstituted by C 1 -C 6 -alkyl; R 1 is hydrogen or C 1 -C 6 -alkyl; Hal is chlorine and/or bromine; m is from 0 to 15; n is from 1 to 16 , subject to the proviso that the sum m+n is ≦ 16, are prepared and used. tert-alkylphenoxy substituted polycyclic compounds of general formula (I), in which the variables have the following meanings: P=a conjugated polycyclic group, optionally aryl substituted, stable to base and acid and not containing residues from the group —CO—NH—CO—, —COOH and —CO—O—CO—; R═C1-C8 alkyl, the carbon chain of which may be interrupted by one or several groups of —O—, —S—, —NR1—, —CO— and/or —SO2— and which may be mono- or serially-substituted by C1-C6 alkoxy or 5- to 7-membered heterocyclic group, bonded by means of a nitrogen atom, which can contain further heteroatoms and can be aromatic, C5-C8 cycloalkyl. the carbon skeleton of which may be interrupted by one or several groups of —O—, —S—, —NR1—, —CO— and/or —SO2— and may optionally be substituted with C1-C6 alkyl R1═H or C1-C6 alkyl; Hal=chlorine and/or bromine; m=a number from 0 to 15; n=a number from 1 to 16, whereby the sum m+n≦16, production and use thereof.

  通式 I 的叔烷基苯氧基取代多环化合物 1 其中 P 是对碱和亲核物稳定的共轭多环基，可选择带有芳基取代基，且不含由 -CO-NH-CO-、-COOH 和 -CO-O-CO- 组成的基团； R 是 C 1 -C 8 -烷基，其碳链可被一个或多个基团打断，这些基团选自 -O-、-S-、-NR 1 -、-CO- 和/或-SO 2 - 可被 C 1 -C 6 -烷氧基或 5 - 至 7 -通过一个氮原子连接的 5 至 7 元杂环基，该杂环基可能含有更多的杂原子和芳香基； C 5 -C 8 -环烷基，其碳链可被一个或多个基团打断，这些基团选自 -O-、-S-、-NR 1 -、-CO- 和/或-SO 2 - 可被 C 1 -C 6 -烷基； R 1 是氢或 C 1 -C 6 -烷基； Hal 是氯和/或溴； m 从 0 至 15; n 从 1 至 16 ，条件是 m+n 的和为 &lE； 16, 制备和使用通式（I）的叔烷基苯氧基取代的多环化合物，其中变量的含义如下：P=a conjugated polycyclic group, optionally aryl substituted, stable to base and acid and not containing residues from the group -CO-NH-CO-, -COOH and -CO-O-CO-; R&boxH；C1-C8烷基，其碳链可被一个或多个-O-、-S-、-NR1-、-CO-和/或-SO2-基团打断，可被C1-C6烷氧基或5-7元杂环基团单取代或连续取代，通过一个氮原子键合，可含有更多的杂原子，可以是芳香族的C5-C8环烷基。R1═H或C1-C6烷基；Hal=氯和/或溴;m=0至15；n=1至16，其中m+n≦16的总和。