2-乙基-2-甲基-1,3-恶唑烷 | 17026-89-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑烷类
• 中文名称: 2-乙基-2-甲基-1,3-恶唑烷
• 英文名称: 2-ethyl-2-methyloxazolidine
• 英文别名: 2-methyl-2-ethyl-2,3,4,5-tetrahydroisoxazole；2-Methyl-2-ethyloxazolidin；Oxazolidine, 2-ethyl-2-methyl-；2-ethyl-2-methyl-1,3-oxazolidine
• CAS: 17026-89-0
• 化学式: C₆H₁₃NO
• 分子量: 115.175
• InChiKey: QNXSRVCJDFTLOI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.7
• 重原子数：
  8
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  21.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-乙基-2-甲基-1,3-恶唑烷 在 sodium tetrahydroborate 作用下， 以 乙醇 为溶剂， 反应 0.08h， 生成 2-(丁烷-2-基氨基)乙醇
  参考文献：
  名称：

  Reductive alkylation of .beta.-alkanolamines with carbonyl compounds and sodium borohydride

  摘要：

  DOI：

  10.1021/jo00213a014
• 作为产物：
  描述：

  C.I.酸性橙108 、 丁酮 以 乙醇 为溶剂， 反应 0.5h， 生成 2-乙基-2-甲基-1,3-恶唑烷
  参考文献：
  名称：

  Reductive alkylation of .beta.-alkanolamines with carbonyl compounds and sodium borohydride

  摘要：

  DOI：

  10.1021/jo00213a014

文献信息

• Multifunctional water-dispersible crosslink agents
  申请人：Stahl Holland B.V.

  公开号：EP0507407A1

  公开（公告）日：1992-10-07

  The invention describes a new type of multi-functional water-dispersible crosslinking agents. These crosslinking agents are products consisting of oligomeric and compounds containing carbodiimide functions and other reactive functional groups. Further the invention describes aqueous dispersions, emulsions or solutions with such crosslinking agents. Finally the invention comprises a process for the preparation of the crosslinking agent according to the invention.

  本发明描述了一种新型多功能水分散性交联剂。这些交联剂是由含有碳二亚胺官能团和其他活性官能团的低聚物和化合物组成的产品。此外，本发明还描述了含有此类交联剂的水性分散体、乳液或溶液。最后，本发明还包括根据本发明制备交联剂的工艺。
• Ye, Fei; Li, Na; Zhao, Li-Xia, Indian Journal of Heterocyclic Chemistry, 2016, vol. 26, # 3-4, p. 127 - 131
  作者：Ye, Fei、Li, Na、Zhao, Li-Xia、Gao, Shuang、Fu, Ying

  DOI：——

  日期：——
• Carbon suboxide and some of its reactions
  作者：L. B. Dashkevich、F. G. Shepel

  DOI：10.1007/bf00472690

  日期：——
• Acetylation of oxazolidines with ketene
  作者：L. B. Dashkevich、F. G. Shepel

  DOI：10.1007/bf00469913

  日期：——
• Design, Synthesis And Biological Activity Of Novel Sulfonylurea Oxazolidines
  作者：Fei Ye、Ying Fu、Jing-Xin Kang、Yun-Kai Wang、Jing Liu、Li-Xia Zhao、Shuang Gao

  DOI：10.3987/com-16-13412

  日期：——

  A series of N-[(p-methylphenyl)sulfonyl]-1,3-oxazolidine-3-carboxamide 4 was synthesized by cycloaddition and acylation reaction with alkamine, ketones, and p-methylbenzenesulfonyl isocyanate as the starting materials. The structures of all the compounds were characterized by IR, H-1 NMR, C-13 NMR, MS, and elemental analysis. The configuration of 4d was determined by X-ray crystallography. The preliminary biological test showed that all compounds could protect maize against injury caused by chlorsulfuron to certain extent. The sulfonylurea oxazolidines were possible acted as antagonists of sulfonylureas herbicides at target enzyme pocket site by docking analysis.