4′,4′,4′-nitrilotris([1,1′-biphenyl]-4-ol) | 1011734-83-0

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 4′,4′,4′-nitrilotris([1,1′-biphenyl]-4-ol)
• 英文别名: tris(4'-hydroxybiphenyl-4-yl)amine；Tris-(4'-hydroxybiphenyl-4-yl)-amine；4-[4-[4-(4-hydroxyphenyl)-N-[4-(4-hydroxyphenyl)phenyl]anilino]phenyl]phenol
• CAS: 1011734-83-0
• 化学式: C₃₆H₂₇NO₃
• 分子量: 521.615
• InChiKey: NRGDKYVWNHBWKN-UHFFFAOYSA-N

物化性质

• 沸点：
  759.6±60.0 °C(Predicted)
• 密度：
  1.266±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  9
• 重原子数：
  40
• 可旋转键数：
  6
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  63.9
• 氢给体数：
  3
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  溴化氰 、 4′,4′,4′-nitrilotris([1,1′-biphenyl]-4-ol) 在 三乙胺 作用下， 以 丙酮 为溶剂， 反应 2.0h， 以78%的产率得到tris(4'-cyanatobiphenyl-4-yl)amine
  参考文献：
  名称：

  Microporous Cyanate Resins: Synthesis, Porous Structure, and Correlations with Gas and Vapor Adsorptions

  摘要：

  Three silicon and nitrogen-centered cyanate monomers tetrakis(4-cyanatophenyl)silane, tetrakis(4-cyanato-biphenyl)silane, and tris(4-cyanatobiphenyl)amine were designed and synthesized, which were then polymerized via thermal cyclotrimerization reaction to create highly porous cyanate resin networks with systematically varied nodes and linking struts. The chemical structures of monomers and polymers were confirmed by H-1 NMR, FTIR, solid-state C-13 CP/MAS NMR spectra, and elemental analysis. The products are amorphous with 5% weight-loss temperatures over 428 degrees C. The results based on N-2 and CO2 adsorption isotherms show that the pores in these polymers mainly locate in the microporous region, and the BET surface areas are up to 960 m(2) g(-1), which is the highest value for the porous cyanate resin reported to date. The nitrogen- and oxygen-rich characteristics of cyanate resins lead to the networks strong affinity for CO2 and thereby high CO2 adsorption capacity of 11.1 wt % at 273 K and 1.0 bar. The adsorption behaviors of H-2, CO2, benzene, n-hexane, and water vapors were investigated by correlating with the chemical composition and porosity parameters of the networks as well as the physicochemical nature of adsorbates.

  DOI：

  10.1021/ma3008652
• 作为产物：
  描述：

  三(4-溴苯基)胺 在 四(三苯基膦)钯 、 三溴化硼 作用下， 以 二氯甲烷 为溶剂， 反应 36.0h， 生成 4′,4′,4′-nitrilotris([1,1′-biphenyl]-4-ol)
  参考文献：
  名称：

  Self-assembled flexible metallo-supramolecular film based on Fe(II) ion and triphenylamine-subsituted alkyl terpyridine towards electrochromic application

  摘要：

  DOI：

  10.1016/j.dyepig.2021.109623

文献信息

• Cross Linked Organic Conductive Layer
  申请人：Gough Neil

  公开号：US20110245429A1

  公开（公告）日：2011-10-06

  The present invention provides various compounds, compositions, methods, and processes for forming a cross-linked conductive polymeric layer in an electronic device.

  本发明提供了各种化合物、组合物、方法和过程，用于在电子设备中形成交联导电聚合层。
• Vibration‐Regulated Multi‐State Long‐Lived Emission from Star‐Shaped Molecules
  作者：Yiran Li、Glib V. Baryshnikov、Farhan Siddique、Peng Wei、Hongwei Wu、Tao Yi

  DOI：10.1002/anie.202213051

  日期：2022.11.25

  Multi-state long-lived emission has been obtained by regulating the molecular motions of star-shaped molecules. Reverse intersystem crossing assisted by the T2 state of the star-shaped molecules leads to thermally activated delayed fluorescence in solution and the solid state. Suppressing the molecular motions of the dye in a polymer leads to ultralong room-temperature phosphorescence.

  通过调节星形分子的分子运动，获得了多态长寿命发射。由星形分子的 T 2状态辅助的反向系统间穿越导致溶液和固态中的热激活延迟荧光。抑制聚合物中染料的分子运动会导致超长室温磷光。
• COMPOSITION FOR USE IN ORGANIC DEVICE, POLYMER FILM, AND ORGANIC ELECTROLUMINESCENT ELEMENT
  申请人：Mitsubishi Chemical Corporation

  公开号：EP3173456A1

  公开（公告）日：2017-05-31

  The present invention relates to a composition for use in an organic device, comprising at least two cross-linking compounds, wherein each of the at least two cross-linking compounds is a polymer that has a hole-transporting site and constitutional repeating units, the at least two polymers having different average numbers of cross-linking groups per constitutional repeating unit and/or different numbers of cross-linking groups in portions other than the constitutional repeating units, and wherein the cross-linking compounds are compounds having a partial structure of the following formula [109]: The present invention further pertains to an organic electroluminescent element that comprises an anode and a cathode on a substrate and at least one organic layer disposed between the anode and the cathode, wherein at least one organic layer is a layer that is produced by forming a film of the composition for use in an organic device above.

  本发明涉及一种用于有机器件的组合物，该组合物包含至少两种交联化合物，其中 至少两种交联化合物中的每一种都是具有空穴传输位点和构型重复单元的聚合物，至少两种聚合物在每个构型重复单元中具有不同的平均交联基团数和/或在构型重复单元以外的部分中具有不同的交联基团数，以及 其中交联化合物是具有下式[109]部分结构的化合物： 本发明还涉及一种有机电致发光元件，该元件包括基底上的阳极和阴极以及设置在阳极和阴极之间的至少一个有机层，其中至少一个有机层是通过形成用于上述有机器件的组合物薄膜而产生的层。
• COMPOSITION FOR ORGANIC DEVICE, POLYMER MEMBRANE AND ORGANIC ELECTROLUMINESCENT DEVICE
  申请人：Mitsubishi Chemical Corporation

  公开号：EP2117062B1

  公开（公告）日：2017-01-18
• [EN] CROSS LINKED ORGANIC CONDUCTIVE LAYER<br/>[FR] COUCHE ORGANIQUE CONDUCTRICE RÉTICULÉE
  申请人：HCF PARTNERS L P

  公开号：WO2010068205A1

  公开（公告）日：2010-06-17

  The present invention provides various compounds, compositions, methods, and processes for forming a cross-linked conductive polymeric layer in an electronic device.