N-(2,4-dimethylphenyl)-2,4-dimethyl-N-phenylaniline | 159946-78-8

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N-(2,4-dimethylphenyl)-2,4-dimethyl-N-phenylaniline
• 英文别名: bis-(2,4-dimethylphenyl)phenylamine
• CAS: 159946-78-8
• 化学式: C₂₂H₂₃N
• 分子量: 301.431
• InChiKey: YKILHTKSSQZNAR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.6
• 重原子数：
  23
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  N-(2,4-dimethylphenyl)-2,4-dimethyl-N-phenylaniline 在 N-溴代丁二酰亚胺(NBS) 、 四(三苯基膦)钯 、 potassium acetate 、 palladium diacetate 、 potassium carbonate 、 双(2-二苯基磷苯基)醚 作用下， 以 1,4-二氧六环 、 二氯甲烷 、 水 为溶剂， 反应 3.0h， 生成 N-(2,4-dimethylphenyl)-2,4-dimethyl-N-(4-(5-(4-(1-phenyl-1H-benzo[d]imidazol-2-yl)phenyl)pyrazin-2-yl)phenyl)aniline
  参考文献：
  名称：

  [EN] ORGANIC LIGHT EMITTING POLYAROMATIC AND POLYHETEROAROMATIC HOST MATERIALS
  [FR] MATIÈRES HÔTES POLYAROMATIQUES ET POLYHÉTÉROAROMATIQUES ÉMETTANT DE LA LUMIÈRE ORGANIQUE

  摘要：

  杂环芳基-芳基化合物，例如由下式表示的化合物，可用于电子设备，如有机发光器件。例如，这些化合物可用作发射层中的发射材料。

  公开号：

  WO2014093353A1
• 作为产物：
  描述：

  2,4-二甲基溴苯 在 palladium bis[bis(diphenylphosphino)ferrocene] dichloride 、 三叔丁基膦 、 palladium diacetate 、 sodium t-butanolate 作用下， 以 甲苯 为溶剂， 反应 16.0h， 生成 N-(2,4-dimethylphenyl)-2,4-dimethyl-N-phenylaniline
  参考文献：
  名称：

  [EN] ORGANIC LIGHT EMITTING POLYAROMATIC AND POLYHETEROAROMATIC HOST MATERIALS
  [FR] MATIÈRES HÔTES POLYAROMATIQUES ET POLYHÉTÉROAROMATIQUES ÉMETTANT DE LA LUMIÈRE ORGANIQUE

  摘要：

  杂环芳基-芳基化合物，例如由下式表示的化合物，可用于电子设备，如有机发光器件。例如，这些化合物可用作发射层中的发射材料。

  公开号：

  WO2014093353A1

文献信息

• SUBSTITUTED OR UNSUBSTITUTED ALLYL GROUP-CONTAINING MALEIMIDE COMPOUND, PRODUCTION METHOD THEREFOR, AND COMPOSITION AND CURED PRODUCT USING SAID COMPOUND
  申请人：DIC CORPORATION

  公开号：US20200325101A1

  公开（公告）日：2020-10-15

  Bismaleimides (BMI) exhibit excellent heat resistance (high Tg and high resistance to thermal decomposition) compared to epoxy resins and phenolic resins, and therefore, in recent years, more attention is paid to bismaleimides as a resin material for the next-generation devices represented by SiC power semiconductors, in addition to the investigation on the use of bismaleimides for electronic material applications. As such, conventional BMI's are known as highly heat-resistant resins; however, there is a demand for a resin having higher heat resistance for advanced material applications and the like. Thus, an object of the invention is to provide a novel maleimide compound having superior heat resistance. Disclosed is a substituted or unsubstituted allyl group-containing maleimide compound having a structure with three or more benzene rings, having one or more groups each having a substituted or unsubstituted allyl group, and having one or more maleimide groups.

  亚苯基马来酰亚胺化合物，具有三个或更多苯环的结构，含有一个或多个取代或未取代的烯丙基团，以及一个或多个马来酰亚胺基团，具有卓越的耐热性。
• NOVEL COMPOUND, CORE-SHELL DYE, PHOTOSENSITIVE RESIN COMPOSITION INCLUDING THE SAME, AND COLOR FILTER
  申请人：SAMSUNG SDI CO., LTD.

  公开号：US20200308099A1

  公开（公告）日：2020-10-01

  A compound represented by specific chemical formula, a core including the same, and core-shell dye including a shell surrounding the core, a photosensitive resin composition including the same, and a color filter manufactured using the photosensitive resin composition are disclosed.

  本发明公开了一种由特定化学配方表示的化合物，包括相同核心的核心和包围核心的壳层染料，包括该核心的光敏树脂组合物，以及使用该光敏树脂组合物制造的彩色滤光片。
• ORGANIC LIGHT EMITTING HOST MATERIALS
  申请人：NITTO DENKO CORPORATION

  公开号：US20140159015A1

  公开（公告）日：2014-06-12

  Heteroaryl-aryl compounds such as compounds represented by Formula may be used in electronic devices such as organic light-emitting devices. For example, the compounds may be used as an emissive material in an emissive layer.

  杂环芳基-芳基化合物，如公式所表示的化合物，可用于电子设备，例如有机发光器件。例如，这些化合物可用作发射层中的发射材料。
• Organic light emitting host materials
  申请人：NITTO DENKO CORPORATION

  公开号：US09263681B2

  公开（公告）日：2016-02-16

  Heteroaryl-aryl compounds such as compounds represented by the Formula: HT-[Ph1]r-Py-Het-ET may be used in electronic devices such as organic light-emitting devices. For example, the compounds may be used as an emissive material in an emissive layer.

  杂环芳基-芳基化合物，例如由公式表示的化合物：HT-[Ph1]r-Py-Het-ET，可用于电子设备，例如有机发光器件。例如，这些化合物可用作发射层中的发射材料。
• High efficient copper-promoted N-arylation of secondary and primary amines with triarylbismuth reagents under mild conditions
  作者：Xuehao Zhou、Huifang Ma、Jianwei Xie

  DOI：10.1016/j.molstruc.2023.136437

  日期：2023.12

  Triarylbismuths were found to be highly efficient arylating reagents for copper-promoted N-arylation of secondary and some heteroaryl and aliphatic primary amines with over 49 examples. A variety of sterically diverse tertiary and secondary amines could be obtained in good to excellent yields with good functional group compatibility. The operational simplicity, mild reaction conditions as well as the

  三芳基铋被发现是高效的芳基化试剂，可用于铜促进的仲胺、一些杂芳基和脂肪族伯胺的 N-芳基化，有超过 49 个实例。可以以良好至优异的产率获得各种空间不同的叔胺和仲胺，并且具有良好的官能团相容性。操作简单、反应条件温和以及有效的克级制备选项使该工艺更加实用。