(3-oxo-butyl)-phosphonic acid diphenyl ester | 27562-93-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (3-oxo-butyl)-phosphonic acid diphenyl ester
• 英文别名: (3-Oxo-butyl)-phosphonsaeure-diphenylester；4-Diphenoxyphosphorylbutan-2-one；4-diphenoxyphosphorylbutan-2-one
• CAS: 27562-93-2
• 化学式: C₁₆H₁₇O₄P
• 分子量: 304.282
• InChiKey: PDYKIBGMTKXOCF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  21
• 可旋转键数：
  7
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.19
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  亚磷酸三苯酯 、 4-羟基-2-丁酮 在 sodium 作用下， 生成 (3-oxo-butyl)-phosphonic acid diphenyl ester
  参考文献：
  名称：

  Reaction of keto alcohols with organophosphorus compounds

  摘要：

  DOI：

  10.1007/bf01084311

文献信息

• Drake; Marvel, Journal of Organic Chemistry, 1937, vol. 2, p. 396
  作者：Drake、Marvel

  DOI：——

  日期：——
• Esters of gamma oxophosphonic acids
  申请人：MARVEL CARL S

  公开号：US02268158A1

  公开（公告）日：1941-12-30
• Photosensitive Compounds, Photopolymerizable Compositions Including the Same, and Methods of Making and Using the Same
  申请人：Jacobine Anthony F.

  公开号：US20090030106A1

  公开（公告）日：2009-01-29

  The present invention is directed to reaction products prepared from at least one Michael addition donor material including two or more active methylene hydrogens; and at least one material capable of reacting with a Michael addition donor, the material having one Michael addition acceptor and at least one functional group selected from the group consisting of hydroxy, hydroxyalkyl, vinyl ether, amino, aminoalkyl, carboxy, carboxyalkyl, cyano, and cyanoalkyl groups; or reaction products prepared from (a) at least one Michael addition donor material comprising at least one Michael Addition donor group selected from the group consisting of cyano functional groups and phosphono functional groups; and (b) at least one material capable of reacting with the at least one Michael addition donor group, the material having at least one Michael addition acceptor, wherein the above reaction products are capable of forming free radicals upon exposure to actinic radiation; as well as compositions, and processes for making and using the same.
• US7705064B2
  申请人：——

  公开号：US7705064B2

  公开（公告）日：2010-04-27
• [EN] PHOTOSENSITIVE COMPOUNDS, PHOTOPOLYMERIZABLE COMPOSITIONS INCLUDING THE SAME, AND METHODS OF MAKING AND USING THE SAME<br/>[FR] COMPOSÉS PHOTOSENSIBLES, COMPOSITIONS PHOTOPOLYMÉRISABLES LES COMPRENANT ET LEURS PROCÉDÉS DE FABRICATION ET D'UTILISATION
  申请人：HENKEL CORP

  公开号：WO2009014689A2

  公开（公告）日：2009-01-29

  The present invention is directed to reaction products prepared from at least one Michael addition donor material including two or more active methylene hydrogens; and at least one material capable of reacting with a Michael addition donor, the material having one Michael addition acceptor and at least one functional group selected from the group consisting of hydroxy, hydroxyalkyl, vinyl ether, amino, aminoalkyl, carboxy, carboxyalkyl, cyano, and cyanoalkyl groups; or reaction products prepared from (a) at least one Michael addition donor material comprising at least one Michael Addition donor group selected from the group consisting of cyano functional groups and phosphono functional groups; and (b) at least one material capable of reacting with the at least one Michael addition donor group, the material having at least one Michael addition acceptor, wherein the above reaction products are capable of forming free radicals upon exposure to actinic radiation; as well as compositions, and processes for making and using the same.