(R)-2,2'-(1,4-butylenedioxy)-1,1'-binaphthalene | 38896-37-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: (R)-2,2'-(1,4-butylenedioxy)-1,1'-binaphthalene
• 英文别名: (S)-2,2'-(1,4-butylenedioxy)-1,1'-binaphthalene；2,2'-(1,4-butylenedioxy)-1,1'-binaphthalene；12,17-Dioxapentacyclo[16.8.0.02,11.03,8.021,26]hexacosa-1(18),2(11),3,5,7,9,19,21,23,25-decaene
• CAS: 38896-37-6；86289-53-4；87728-95-8
• 化学式: C₂₄H₂₀O₂
• 分子量: 340.422
• InChiKey: YQCZVETWUBHRNG-UHFFFAOYSA-N

物化性质

• 沸点：
  563.7±20.0 °C(Predicted)
• 密度：
  1.184±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.5
• 重原子数：
  26
• 可旋转键数：
  0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  (R)-2,2'-(1,4-butylenedioxy)-1,1'-binaphthalene 在 硝酸 、 溶剂黄146 作用下， 反应 16.0h， 以24%的产率得到2,2'-(1,4-butylenedioxy)-6,6'-dinitro-1,1'-binaphthalene
  参考文献：
  名称：

  Synthesis and characterization of optically active cyclic 6,6′-dinitro-1,1′-binaphthyl-2,2′-diethers

  摘要：

  A series of racemic and enantiomerically pure 6,6'-dinitro-1,1'-binaphthyl-2,2'-diethers 1 have been synthesized by the nitration of the corresponding cyclic ethers and both the reactivity of nitration and the (chir)optical properties proved to be very sensitive for the chain length of the ether bridge. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0957-4166(97)00185-7
• 作为产物：
  描述：

  1,4-二溴丁烷 、 S-1,1'-联-2-萘酚 在 potassium carbonate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 16.0h， 以76%的产率得到(R)-2,2'-(1,4-butylenedioxy)-1,1'-binaphthalene
  参考文献：
  名称：

  Synthesis and characterization of optically active cyclic 6,6′-dinitro-1,1′-binaphthyl-2,2′-diethers

  摘要：

  A series of racemic and enantiomerically pure 6,6'-dinitro-1,1'-binaphthyl-2,2'-diethers 1 have been synthesized by the nitration of the corresponding cyclic ethers and both the reactivity of nitration and the (chir)optical properties proved to be very sensitive for the chain length of the ether bridge. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0957-4166(97)00185-7

文献信息

• Substituent effects of bridged binaphthyl-type chiral dopants on the helical twisting power in dopant-induced chiral liquid crystals
  作者：Yu Narazaki、Hiroya Nishikawa、Hiroki Higuchi、Yasushi Okumura、Hirotsugu Kikuchi

  DOI：10.1039/c7ra12465a

  日期：——

  A new series of chiral dopants, (R)-6,6′-halogenated (1b–1e, X = F, Cl, Br and I) and -methylated (1f) binaphthyl compounds, were designed and synthesized to create chiral liquid crystals by doping them into an achiral nematic liquid crystal (NLC). The influence of halogen (X = F, Cl, Br and I) and methyl substituent factors, such as steric, polar, and polarizability properties, on the helical twisting

  设计并合成了一系列新的手性掺杂剂 ( R )-6,6'-卤代 ( 1b–1e , X = F, Cl, Br 和 I) 和甲基化 ( 1f ) 联萘化合物，以制造手性液晶通过将它们掺杂到非手性向列液晶（NLC）中。卤素（X = F、Cl、Br 和 I）和甲基取代基因素（如空间位阻、极​​性和极化率特性）对螺旋扭曲能力 (HTP) 的影响及其对手性掺杂剂的温度依赖性在两个方面进行了研究宿主具有不同特征的 NLC，氟化 JC-1041XX 和N-(4-甲氧基亚苄基)-4-丁基苯胺(MBBA)。具有较少空间位阻和较大极化因子的手性掺杂剂增加了HTP值。手性掺杂剂和 NLC 分子之间的结构相似性和静电芳烃 - 芳烃相互作用也对这些值产生重要影响。HTP (HTP t.d. ) 值的温度依赖性也与两个宿主 NLC 中的空间位阻和极化率取代基因素密切相关。它们的相关系数 ( R 2 ) 取决于手性掺杂剂和
• Circular dichroism in excited triplet states. 2. Chiral dimer-like molecules in the binaphthyl and spirobifluorene series
  作者：Catherine Tetreau、Daniel Lavalette、Daniel Cabaret、Niall Geraghty、Zoltan Welvart

  DOI：10.1021/j100240a014

  日期：1983.8
• ARMSTRONG, D. W.;WARD, T. J.;CZECH, A.;CZECH, B. P.;BARTSCH, R. A., J. ORG. CHEM., 1985, 50, N 26, 5556-5559
  作者：ARMSTRONG, D. W.、WARD, T. J.、CZECH, A.、CZECH, B. P.、BARTSCH, R. A.

  DOI：——

  日期：——
• Sensitized photochemical switching for cholesteric liquid crystal displays
  申请人：Shukla Deepak

  公开号：US20070243342A1

  公开（公告）日：2007-10-18

  The present invention relates to photo-tunable dopant compositions comprising a photo-reactive chiral compound capable of undergoing a photochemical reaction resulting in the loss of chirality, and a triplet sensitizer. The present invention also relates to a display comprising a substrate, a liquid crystalline layer thereon, wherein the liquid crystalline layer comprises a nematic host, at least one chiral dopant, a photo-reacted compound, and a triplet sensitizer, and at least one transparent conductive layer. The present invention also relates to a method of tuning a cholesteric liquid crystal material comprising providing at least one mesogenic compound, at least one triplet sensitizer, and at least one photo-reactive chiral compound; combining the at least one mesogenic compound, at least one triplet sensitizer, and at least one photo-reactive chiral compound to form a mixture; and irradiating the mixture for a period of time.
• Sensitized Photochemical Switching for Cholesteric Liquid Crystal Displays
  申请人：Shukla Deepak

  公开号：US20100068418A1

  公开（公告）日：2010-03-18

  The present invention relates to photo-tunable dopant compositions comprising a photo-reactive chiral compound capable of undergoing a photochemical reaction resulting in the loss of chirality, and a triplet sensitizer. The present invention also relates to a display comprising a substrate, a liquid crystalline layer thereon, wherein the liquid crystalline layer comprises a nematic host, at least one chiral dopant, a photo-reacted compound, and a triplet sensitizer, and at least one transparent conductive layer. The present invention also relates to a method of tuning a cholesteric liquid crystal material comprising providing at least one mesogenic compound, at least one triplet sensitizer, and at least one photo-reactive chiral compound; combining the at least one mesogenic compound, at least one triplet sensitizer, and at least one photo-reactive chiral compound to form a mixture; and irradiating the mixture for a period of time.