6,6'-dioctyl-3,3'-dibromo-2,2'-dimethoxy-1,1'-binaphthyl | 128532-27-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 6,6'-dioctyl-3,3'-dibromo-2,2'-dimethoxy-1,1'-binaphthyl
• 英文别名: 3-bromo-1-(3-bromo-2-methoxy-6-octylnaphthalen-1-yl)-2-methoxy-6-octylnaphthalene
• CAS: 128532-27-4
• 化学式: C₃₈H₄₈Br₂O₂
• 分子量: 696.606
• InChiKey: UYDKFELRUYXEGA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  15.5
• 重原子数：
  42
• 可旋转键数：
  17
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.47
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  6,6'-dioctyl-3,3'-dibromo-2,2'-dimethoxy-1,1'-binaphthyl 、 phenylmagnesium bromide 以38%的产率得到
  参考文献：
  名称：

  SHINBO, TOSHIO;YAMAGUCHI, TOMOHIKO;TACHIBANA, KOUZOU

  摘要：

  DOI：
• 作为产物：
  描述：

  6,6'-dioctyl-2,2'-dimethoxy-1,1'-binaphthyl 以55%的产率得到
  参考文献：
  名称：

  SHINBO, TOSHIO;YAMAGUCHI, TOMOHIKO;TACHIBANA, KOUZOU

  摘要：

  DOI：

文献信息

• Crown ether compound and separating agent
  申请人：Director-General of Agency of Industrial Science and Technology

  公开号：US04942149A1

  公开（公告）日：1990-07-17

  A crown ether compound is shown below and useful as a separating agent for chemical compounds. ##STR1## (In the formula, A and B represent hydrogen atoms, straight chain or branched alkyl groups having 1-6 carbon atoms, allyl groups having 6-10 carbon atoms, or aralkyl groups having 7-9 carbon atoms. Although A and B may be different groups, it is preferable that they be the same. R.sub.1 represents a hydrogen atom, a straight chain or branched alkyl group having 1-20 carbon atoms, or preferably an alkyl group having 6-16 carbon atoms. R.sub.1 may be bonded to any carbon atom on the cyclical ester group and its number is 1-12, and preferably 1-3. n represents an integer from 3-10, and preferably 4-8, with 5 or 6 being even more preferable. In addition R.sub.2 and R.sub.3 represent straight chain or branched alkyl groups having 1-30, and preferably 6-20 carbon atoms, or aryl groups having 6-18 carbon atoms, or aralkyl groups having 7-30 carbon atoms. The location of R.sub.2 and R.sub.3 may be anywhere other than the A and B substitution positions on the condensed ring, and although one of each of R.sub.2 and R.sub.3 is satisfactory, a maximum of 5 groups may be substituted. In addition, R.sub.2 and R.sub.3 may also be different.)

  下面展示了一种冠醚化合物，可用作化学化合物的分离剂。## STR1 ##（在公式中，A和B代表氢原子，直链或支链烷基，其具有1-6个碳原子，具有6-10个碳原子的烯丙基，或具有7-9个碳原子的芳基烷基。虽然A和B可以是不同的基团，但最好它们是相同的。R.sub.1代表氢原子，具有1-20个碳原子的直链或支链烷基，或者更好的是具有6-16个碳原子的烷基。R.sub.1可以连接到环状酯基上的任何碳原子上，其编号为1-12，最好为1-3。n表示从3-10的整数，最好为4-8，其中5或6更为理想。此外，R.sub.2和R.sub.3代表直链或支链烷基，其具有1-30个碳原子，或具有6-18个碳原子的芳基或具有7-30个碳原子的芳基烷基。R.sub.2和R.sub.3的位置可以是除了A和B取代位置以外的任何位置，尽管每个R.sub.2和R.sub.3中的一个是令人满意的，但最多可以替换5个基团。此外，R.sub.2和R.sub.3也可以不同。)
• New Crown ether compound and separating agent
  申请人：Director General, Agency of Industrial Science and Technology

  公开号：EP0358129A1

  公开（公告）日：1990-03-14

  A crown ether compound is shown below and useful as a separating agent for chemical compounds. (In the formula, A and B represent hydrogen atoms, straight chain or branched alkyl groups having 1-6 carbon atoms, allyl groups having 6-10 carbon atoms, or aralkyl groups having 7-9 carbon atoms. Although A and B may be different groups, it is preferable that they be the same. R₁ represents a hydrogen atom, a straight chain or branched alkyl group having 1-20 carbon atoms, or preferably an alkyl group having 6-16 carbon atoms. R₁ may be bonded to any carbon atom on the cyclical ester group and its number is 1-12, and preferably 1-3. n represents an integer from 3-10, and preferably 4-8, with 5 or 6 being even more preferable. In addition, R₂ and R₃ represent straight chain or branched alkyl groups having 1-30, and preferably 6-20 carbon atoms, or aryl groups having 6-18 carbon atoms, or aralkyl groups having 7-30 carbon atoms. The location of R₂ and R₃ may be anywhere other than the A and B substitution positions on the condensed ring, and although one of each of R₂ and R₃ is satisfactory, a maximum of 5 groups may be substituted. In addition, R₂ and R₃ may also be different.)

  一种冠醚化合物如下所示，可用作化合物的分离剂。 (式中，A 和 B 代表氢原子、具有 1-6 个碳原子的直链或支链烷基、具有 6-10 个碳原子的烯丙基或具有 7-9 个碳原子的芳烷基。虽然 A 和 B 可以是不同的基团，但最好是相同的基团。 R₁ 代表氢原子、具有 1-20 个碳原子的直链或支链烷基，或最好是具有 6-16 个碳原子的烷基。R₁ 可与环酯基团上的任意碳原子键合，其数目为 1-12，优选 1-3。n 代表 3-10 之间的整数，优选 4-8，更优选 5 或 6。 此外，R₂ 和 R₃ 代表具有 1-30 个（优选 6-20 个）碳原子的直链或支链烷基，或具有 6-18 个碳原子的芳基，或具有 7-30 个碳原子的芳烷基。R₂ 和 R₃ 的位置可以是缩合环上 A 和 B 取代位置以外的任何位置，虽然 R₂ 和 R₃ 中各有一个是令人满意的，但最多可以取代 5 个基团。此外，R₂ 和 R₃ 也可以是不同的）。
• SHINBO, TOSHIO;YAMAGUCHI, TOMOHIKO;TACHIBANA, KOUZOU
  作者：SHINBO, TOSHIO、YAMAGUCHI, TOMOHIKO、TACHIBANA, KOUZOU

  DOI：——

  日期：——
• US4942149A
  申请人：——

  公开号：US4942149A

  公开（公告）日：1990-07-17