1-phenyl-3-decyne | 88733-61-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-phenyl-3-decyne
• 英文别名: 3-Decynylbenzene；dec-3-ynylbenzene
• CAS: 88733-61-3
• 化学式: C₁₆H₂₂
• 分子量: 214.351
• InChiKey: HLMQZCCWCVQHTO-UHFFFAOYSA-N

物化性质

• 沸点：
  316.3±21.0 °C(Predicted)
• 密度：
  0.902±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.9
• 重原子数：
  16
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  [(E)-3-(benzenesulfinyl)-1-phenyldec-3-en-4-yl] trifluoromethanesulfonate 以94%的产率得到
  参考文献：
  名称：

  Satoh Tsuyoshi, Itoh Norifumi, Watanabe Shizue, Matsuno Haruko, Yamakawa +, Chem. lett, (1994) N 3, S 576-570

  摘要：

  DOI：

文献信息

• Ligand Exchange Reaction of Sulfoxides in Organic Synthesis. A Novel Method for Synthesizing Acetylenes from Carbonyl Compounds through β-Trifluoromethanesulfonyloxy Vinyl Sulfoxides
  作者：Tsuyoshi Satoh、Norifumi Itoh、Shizue Watanabe、Haruko Matsuno、Koji Yamakawa

  DOI：10.1246/cl.1994.567

  日期：1994.3

  α-Sulfinyl ketones were prepared by the reaction of alkyl phenyl sulfoxide or chloromethyl p-tolyl sulfoxide with aldehydes or methyl esters in high yields, and were converted to acetylenes through β-trifluoromethanesulfonyloxy vinyl sulfoxides by the ligand exchange reaction of the sulfinyl group.

  α-亚磺酰基酮是由烷基苯亚砜或氯甲基对甲苯基亚砜与醛或甲酯以高收率反应制备的，并通过亚磺酰基的配体交换反应通过β-三氟甲磺酰氧基乙烯基亚砜转化为乙炔。
• Ligand exchange reaction of sulfoxides in organic synthesis: A novel method for synthesizing acetylenes and allenes from carbonyl compounds through sulfoxides having a trifluoro-methanesulfonyloxy group on the β-carbon
  作者：Tsuyoshi Satoh、Norifumi Itoh、Shizue Watanabe、Hirofumi Koike、Haruko Matsuno、Kenji Matsuda、Koji Yamakawa

  DOI：10.1016/0040-4020(95)00520-i

  日期：1995.8

  A novel method for synthesizing acetylenes and allenes from carbonyl compounds is described. Ligand exchange reaction of alkenylsulfoxides having a trifluoromethanesulfonyloxy group on the β-carbon, which were derived from α-alkyl β-ketosulfoxides, with n-BuLi gave disubstituted acetylenes in good yields. In the case of alkenylsulfoxides having both the trifluoromethanesulfonyloxy and aryl groups on

  描述了一种由羰基化合物合成乙炔和丙二烯的新方法。由α-烷基β-酮亚砜衍生的在β-碳上具有三氟甲磺酰氧基的烯基亚砜与n-BuLi的配体交换反应以良好的收率得到了二取代的乙炔。在β-碳上同时具有三氟甲磺酰氧基和芳基的烯基亚砜的情况下，无需用正丁基锂处理就可得到芳基乙炔。另一方面，由α，α-二烷基β-酮亚砜衍生的烯醇三氟甲磺酸酯在用正丁基锂处理时得到三取代的烯丙基。该程序用于合成氯乙炔，大环乙炔和大环丙烯。
• A convenient synthesis of unsymmetrical bibenzyls homoallylarenes, and homopropargylarenes via palladium-catalyzed cross coupling
  作者：Ei-ichi Negishi、Hajime Matsushita、Makoto Kobayashi、Cynthia L Rand

  DOI：10.1016/s0040-4039(00)94284-9

  日期：1983.1
• NEGISHI, EI-ICHI;MATSUSHITA, HAJIME;KOBAYASHI, MAKOTO;RAND, CYNTHIA, L., TETRAHEDRON LETT., 1983, 24, N 36, 3823-3824
  作者：NEGISHI, EI-ICHI、MATSUSHITA, HAJIME、KOBAYASHI, MAKOTO、RAND, CYNTHIA, L.

  DOI：——

  日期：——