(N,N-diethylcarbamoylmethyl)diphenylphosphine sulfide | 138200-01-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (N,N-diethylcarbamoylmethyl)diphenylphosphine sulfide
• 英文别名: Acetamide, 2-(diphenylphosphinothioyl)-N,N-diethyl-；2-diphenylphosphinothioyl-N,N-diethylacetamide
• CAS: 138200-01-8
• 化学式: C₁₈H₂₂NOPS
• 分子量: 331.419
• InChiKey: ZSEKMLMMPIPAFQ-UHFFFAOYSA-N

物化性质

• 沸点：
  470.0±47.0 °C(Predicted)
• 密度：
  1.15±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  22
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.28
• 拓扑面积：
  52.4
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  (N,N-diethylcarbamoylmethyl)diphenylphosphine sulfide 在 劳森试剂 作用下， 以 乙腈 为溶剂， 反应 6.0h， 以81%的产率得到(N,N-diethylthiocarbamoylmethyl)diphenylphosphine sulfide
  参考文献：
  名称：

  Complexation of (N, N-diethylthiocarbamoylmethyl) diphenylphosphine sulfide with silver nitrate. The structure of the [Ag{Ph2P(S)CH2C(S)NEt2}2]NO3 complex

  摘要：

  (N,Diethylthiocarbamoylmethyl)diphenylphosphine sulfide, Ph2P(S)CH2C(S)NEt2, forms a distorted tetragonal bisligand complex [AgL2]NO3 with Ag+. The stability constant of the complex in acetonitrile was estimated by spectrophotometry (logK=3.7).

  DOI：

  10.1007/bf02495219
• 作为产物：
  描述：

  diphenylphosphane sulfide 、 alkaline earth salt of/the/ methylsulfuric acid 在 氢氧化钾 作用下， 以 二氯甲烷 为溶剂， 以65%的产率得到(N,N-diethylcarbamoylmethyl)diphenylphosphine sulfide
  参考文献：
  名称：

  Aladzheva, I. M.; Odinets, I. L.; Mastryukova, T. A., Journal of general chemistry of the USSR, 1992, vol. 62, # 5.2, p. 968 - 969

  摘要：

  DOI：

文献信息

• The complexation of (N,N-diethylcarbamoylmethyl)diphenylphosphine sulfide with silver nitrate
  作者：M. P. Pasechnik、I. M. Aladzheva、E. I. Matrosov、A. P. Pisarevskii、Yu. T. Struchkov、T. A. Mastryukova、M. I. Kabachnik

  DOI：10.1007/bf00699844

  日期：1994.4

  The crystalline complex [Ag(L1)NO3]2 (A) was isolated by the interaction of (N,N-diethylcaibamoylmethyl)diphenylphosphine sulfide Ph2P(S)CH2C(O)NEt2 (L1) with AgNO3 in different solvents at the ratios of metal:ligand = 1∶1 and 1∶2. According to the X-ray data, complexA is a center-symmetric dimer with bridge sulfur atoms. The cations of the metal are in a tetrahedral environment formed by two S atoms

  结晶络合物[Ag(L1)NO3]2 (A)是通过(N,N-二乙基caibamoylmethyl)二苯基硫化膦Ph2P(S)CH2C(O)NEt2 (L1)与AgNO3在不同溶剂中以金属：配体 = 1∶1 和 1∶2。根据X射线数据，complexA是一个中心对称的带有桥硫原子的二聚体。金属的阳离子处于由两个 S 原子和 CO 和 NO3 基团的 O 原子形成的四面体环境中。用红外光谱研究了L1与AgNO3在溶液中的相互作用，并讨论了所形成配合物的结构。
• Photothermographic materials containing silver halide sensitized with combination of compounds
  申请人：Simpson M. Sharon

  公开号：US20060078833A1

  公开（公告）日：2006-04-13

  Photothermographic materials are designed with increased photospeed by chemical sensitizing the photosensitive silver halide grains with a combination of compounds. A first chemical sensitizer is a specific gold(III)-containing compound and a second chemical sensitizer is a sulfur-containing compound that is a diphenylphosphine sulfide. The molar ratio of the gold (III)-containing compound to the sulfur-containing compound is at least 1:1.

  光热材料是通过化学增敏光敏银卤化物晶粒的组合设计，以增加其光速度。第一种化学增敏剂是一种特定的含金(III)化合物，第二种化学增敏剂是一种含硫化合物，即二苯基膦硫化物。金(III)化合物与含硫化合物的摩尔比至少为1:1。
• Aladzheva, I. M.; Odinets, I. L.; Petrovskii, P. V., Russian Journal of General Chemistry, 1993, vol. 63, # 3.2, p. 431 - 437
  作者：Aladzheva, I. M.、Odinets, I. L.、Petrovskii, P. V.、Mastryukova, T. A.、Kabachnik, M. I.

  DOI：——

  日期：——
• Aladzheva, I. M.; Odinets, I. L.; Mastryukova, T. A., Journal of general chemistry of the USSR, 1992, vol. 62, # 5.2, p. 968 - 969
  作者：Aladzheva, I. M.、Odinets, I. L.、Mastryukova, T. A.

  DOI：——

  日期：——
• Complexation of (N, N-diethylthiocarbamoylmethyl) diphenylphosphine sulfide with silver nitrate. The structure of the [Ag{Ph2P(S)CH2C(S)NEt2}2]NO3 complex
  作者：M. P. Pasechnik、Z. A. Starikova、A. I. Yanovsky、I. M. Aladzheva、O. V. Bykhovskaya、E. I. Matrosov、T. A. Mastryukova、M. I. Kabachnik

  DOI：10.1007/bf02495219

  日期：1997.4

  (N,Diethylthiocarbamoylmethyl)diphenylphosphine sulfide, Ph2P(S)CH2C(S)NEt2, forms a distorted tetragonal bisligand complex [AgL2]NO3 with Ag+. The stability constant of the complex in acetonitrile was estimated by spectrophotometry (logK=3.7).