2,2-diethyl-3-methoxy-3-phenyl-oxirane | 88539-03-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,2-diethyl-3-methoxy-3-phenyl-oxirane
• 英文别名: 1-Methoxy-1,2-epoxy-2-ethyl-1-phenyl-butan；1,2-Epoxy-2-ethyl-1-methoxy-1-phenyl-butan；2,2-Diaethyl-3-methoxy-3-phenyl-oxiran；2,2-Diethyl-3-methoxy-3-phenyloxirane
• CAS: 88539-03-1
• 化学式: C₁₃H₁₈O₂
• 分子量: 206.285
• InChiKey: RSUUMMQKSPQBNK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  15
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.54
• 拓扑面积：
  21.8
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2-乙基苯丁酮 在 溴 、 potassium carbonate 作用下， 以 二氯甲烷 为溶剂， 反应 1.25h， 生成 2,2-diethyl-3-methoxy-3-phenyl-oxirane
  参考文献：
  名称：

  Kimpe, Norbert De; Buyck, Laurent De; Verhe, Roland, Chemische Berichte, 1983, vol. 116, # 11, p. 3631 - 3636

  摘要：

  DOI：

文献信息

• [EN] SIMPLE OXIDATIVE FUNCTIONALIZATION OF ALKYL ARYL KETONES<br/>[FR] FONCTIONNALISATION OXYDATIVE SIMPLE DE CÉTONES D'ALKYLARYLE
  申请人：IGM GROUP B V

  公开号：WO2018197324A1

  公开（公告）日：2018-11-01

  The present invention refers to a process for reacting an alkyl aryl ketone obtaining thereby the corresponding aryl oxirane or α-functionalized alkyl aryl ketal, the aryl oxirane or α-functionalized alkyl aryl ketal obtained by the process as well as the α-functionalized ketone obtained by the process.

  本发明涉及一种用于反应烷基芳基酮以获得相应的芳基环氧化物或α-官能化烷基芳基醚醇的过程，以及该过程获得的芳基环氧化物或α-官能化烷基芳基醚醇，以及该过程获得的α-官能化酮。
• SIMPLE OXIDATIVE FUNCTIONALIZATION OF ALKYL ARYL KETONES
  申请人：IGM Group B.V.

  公开号：EP3395806A1

  公开（公告）日：2018-10-31

  The present invention refers to a process for reacting an alkyl aryl ketone obtaining thereby the corresponding aryl oxirane or α-functionalized alkyl aryl ketal, the aryl oxirane or α-functionalized alkyl aryl ketal obtained by the process as well as the α-functionalized ketone obtained by the process.

  本发明涉及一种使烷基芳基酮发生反应，从而获得相应的芳基环氧乙烷或α官能化烷基芳基酮的工艺、通过该工艺获得的芳基环氧乙烷或α官能化烷基芳基酮以及通过该工艺获得的α官能化酮。
• Simple oxidative functionalized of alkyl aryl ketones
  申请人：IGM GROUP B.V.

  公开号：US11203580B2

  公开（公告）日：2021-12-21

  The present invention refers to a process for reacting an alkyl aryl ketone obtaining thereby the corresponding aryl oxirane or α-functionalized alkyl aryl ketal, the aryl oxirane or α-functionalized alkyl aryl ketal obtained by the process as well as the α-functionalized ketone obtained by the process.

  本发明涉及一种使烷基芳基酮发生反应，从而获得相应的芳基环氧乙烷或α官能化烷基芳基酮的工艺、通过该工艺获得的芳基环氧乙烷或α官能化烷基芳基酮以及通过该工艺获得的α官能化酮。
• Epoxyethers. XII.¹ Reduction with Lithium Aluminum Hybride
  作者：Calvin L. Stevens、Thomas H. Coffield

  DOI：10.1021/ja01541a034

  日期：1958.4
• DE, KIMPE, N.;DE, BUYCK, L.;VERHE, R.;SCHAMP, NICEAS, CHEM. BER., 1983, 116, N 11, 3631-3636
  作者：DE, KIMPE, N.、DE, BUYCK, L.、VERHE, R.、SCHAMP, NICEAS

  DOI：——

  日期：——