2-(1-Isopropenyl-3-methyl-but-3-enyloxymethyl)-biphenyl | 128316-30-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-(1-Isopropenyl-3-methyl-but-3-enyloxymethyl)-biphenyl
• 英文别名: 1-(2,5-dimethylhexa-1,5-dien-3-yloxymethyl)-2-phenylbenzene
• CAS: 128316-30-3
• 化学式: C₂₁H₂₄O
• 分子量: 292.421
• InChiKey: YKOXASPAYSCCPE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.2
• 重原子数：
  22
• 可旋转键数：
  7
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.24
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  O-(2'-Iodobenzoyl)-2,5-dimethylhexa-1,5-diene-3-ol 、 四苯硼钠 在 palladium diacetate 三苯基膦 作用下， 以 苯甲醚 为溶剂， 反应 16.0h， 生成 2-(1-Isopropenyl-3-methyl-but-3-enyloxymethyl)-biphenyl 、 (2S,3aR,9bR)-2-Benzyl-2,9b-dimethyl-2,3,5,9b-tetrahydro-1H,3aH-cyclopenta[c]isochromene
  参考文献：
  名称：

  Palladium catalysed tandem cyclisation-anion capture processes. Part 3. Organoboron anion transfer agents

  摘要：

  The cyclisation-anion capture protocol has been applied to a wide range of starter and terminating species to effect regio-and stereo-specific mono-and bis-cyclisation processes in which a variety of organoboronderivatives function as anion transfer reagents. Direct capture (no cyclisation) is rarely a problem and it can usually be suppressed by modification of the reaction conditions. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0040-4020(97)00754-0

文献信息

• Palladium-catalysed polycyclisation-anion capture processes
  作者：Ronald Grigg、Michael J Dorrity、John F Malone、Visuvanathar Sridharan、Sukanthini Sukirthalingam

  DOI：10.1016/s0040-4039(00)88802-4

  日期：1990.1
• GRIGG, RONALD;DORRITY, MICHAEL J.;MALONE, JOHN F., TETRAHEDRON LETT., 31,(1990) N, C. 1343-1346
  作者：GRIGG, RONALD、DORRITY, MICHAEL J.、MALONE, JOHN F.

  DOI：——

  日期：——
• Palladium catalysed tandem cyclisation-anion capture processes. Part 3. Organoboron anion transfer agents
  作者：Ronald Grigg、JoséM. Sansano、Vijayaratnam Santhakumar、Visuvanathar Sridharan、Ravishanker Thangavelanthum、Mark Thornton-Pett、David Wilson

  DOI：10.1016/s0040-4020(97)00754-0

  日期：1997.8

  The cyclisation-anion capture protocol has been applied to a wide range of starter and terminating species to effect regio-and stereo-specific mono-and bis-cyclisation processes in which a variety of organoboronderivatives function as anion transfer reagents. Direct capture (no cyclisation) is rarely a problem and it can usually be suppressed by modification of the reaction conditions. (C) 1997 Elsevier Science Ltd.