5,5'-di(anthracenecarboxylic) anhydride | 37939-68-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 5,5'-di(anthracenecarboxylic) anhydride
• 英文别名: anthracene-9-carboxylic anhydride；Anthracen-9-carbonsaeure-anhydrid；anthracene-9-carboxylic acid-anhydride；Anthracenecarboxylic anhydride；anthracene-9-carbonyl anthracene-9-carboxylate
• CAS: 37939-68-7
• 化学式: C₃₀H₁₈O₃
• 分子量: 426.471
• InChiKey: KTUSJCZQNQIHSD-UHFFFAOYSA-N

物化性质

• 熔点：
  249-250 °C(Solv: chloroform (67-66-3))
• 沸点：
  686.5±24.0 °C(Predicted)
• 密度：
  1.319±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  8.2
• 重原子数：
  33
• 可旋转键数：
  4
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  43.4
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  5,5'-di(anthracenecarboxylic) anhydride 在 氯仿 作用下， 生成 11,12-dihydro-5,12;6,11-di-o-benzeno-dibenzo[a,e]cyclooctene-5,6-dicarboxylic acid-anhydride
  参考文献：
  名称：

  The Structure of Anthracene Photodimers

  摘要：

  DOI：

  10.1021/ja01619a051
• 作为产物：
  描述：

  9-蒽甲酸 在 草酰氯 作用下， 生成 5,5'-di(anthracenecarboxylic) anhydride
  参考文献：
  名称：

  5,5'-Di(anthracenecarboxylic) Anhydride

  摘要：

  The title compound, C30H18O3, has a dihedral angle of 76.24 (5)degrees between the two anthracene units and a mean dihedral angle of 64.0 (2)degrees between an anthracene unit and the plane defined by C5 and the C and O atoms of the carbonyl group.

  DOI：

  10.1107/s0108270195004306

文献信息

• TBHP/n-Bu4PBr-Promoted Oxidative Cross-Dehydrogenative Coupling of Aryl Methanols: A Facile Synthesis of Symmetrical Carboxylic Anhydride Derivatives
  作者：Mehdi Adib、Rahim Pashazadeh

  DOI：10.1055/s-0036-1590905

  日期：2018.1

  A transition-metal-free oxidative cross-dehydrogenative coupling reaction has been developed for the preparation of symmetrical carboxylic anhydrides through self-coupling dual C–O bond formations of aryl methanols. In the presence of a catalytic amount of tetrabutylphosphonium bromide (TBPB) as transfer agent and aqueous tert-butyl hydroperoxide (TBHP) as oxidant and reactant, methylene groups of

  已经开发了一种不含过渡金属的氧化交叉脱氢偶联反应，用于通过芳基甲醇的自偶联双 C-O 键形成制备对称羧酸酐。在催化量的四丁基溴化鏻（TBPB）作为转移剂和叔丁基过氧化氢（TBHP）作为氧化剂和反应物存在下，芳基甲醇的亚甲基被有效地氧化为 C=O 并与来自 TBHP 的过氧化氧偶联形成各种对称的羧酸酐衍生物。
• A phosphine sulfide, a manufacturing process therefor and a use thereof
  申请人：MITSUI CHEMICALS, INC.

  公开号：EP0972776A1

  公开（公告）日：2000-01-19

  A basic organic compound which is soluble in an organic solvent, does not have problems in its preparation or handling and exhibits catalytic activity as a basic compound, is a phosphine sulfide represented by the (1): The phosphine sulfide represented by formula (1), is made by reacting one molecule of thiophosphoryl chloride with three molecules of a phosphorane represented by formula (2): A process for effectively manufacturing a poly(alkylene oxide) involves polymerizing an alkylene oxide in the presence of the above organic compound (phosphine sulfide), or in the presence of the phosphine sulfide and an active hydrogen compound selected from water and organic compounds having a partial structure of -OH or -NH-. A process for manufacturing a 1,2-dioxyethane derivative from an epoxy compound, i.e. manufacturing a 1,2-dioxyethane derivative involves reacting an epoxy compound with a carboxylate, carboxylic anhydride, carbonate or phenol compound, respectively, in the presence of the phosphine sulfide.

  一种可溶于有机溶剂、在制备或处理过程中不会出现问题并具有催化活性的碱性有机化合物是硫化膦，其代表式为（1）： 式（1）代表的硫化膦是由一分子硫代磷酰氯与三分子式（2）代表的磷烷反应制得的： 一种有效制造聚环氧亚烷烃的工艺是在上述有机化合物（硫化膦）存在下，或在硫化膦和选 自水和部分结构为-OH 或-NH-的有机化合物的活性氢化合物存在下，聚合环氧亚烷烃。 由环氧化合物制造 1，2-二氧乙烷衍生物的工艺，即制造 1，2-二氧乙烷衍生物的工艺包括在硫化膦存在下，环氧化合物分别与羧酸盐、羧酸酐、碳酸盐或苯酚化合物反应。
• US6153794A
  申请人：——

  公开号：US6153794A

  公开（公告）日：2000-11-28
• The Structure of Anthracene Photodimers
  作者：Frederick D. Greene、S. Leslie Misrock、James R. Wolfe

  DOI：10.1021/ja01619a051

  日期：1955.7
• 5,5'-Di(anthracenecarboxylic) Anhydride
  作者：A. J. Blake、R. S. Grimditch、M. Schröder

  DOI：10.1107/s0108270195004306

  日期：1995.7.15

  The title compound, C30H18O3, has a dihedral angle of 76.24 (5)degrees between the two anthracene units and a mean dihedral angle of 64.0 (2)degrees between an anthracene unit and the plane defined by C5 and the C and O atoms of the carbonyl group.