triphenylsulfonium 1,1,2,2,-tetrafluoro-4-(2-methyl-acryloyloxy)-butane-1-sulfonate | 960080-32-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: triphenylsulfonium 1,1,2,2,-tetrafluoro-4-(2-methyl-acryloyloxy)-butane-1-sulfonate
• 英文别名: triphenylsulfonium salt of 4-sulfo-3,3,4,4-tetrafluorobutyl 2-methyl-2-propenoate；triphenylsulfonium 1,1,2,2-tetrafluoro-4-(methacryloyloxy)butane-1-sulfonate；Triphenylsulfonium 1,1,2,2-tetrafluoro-4-(methacryloyloxy)butane-1-sulfonate；1,1,2,2-tetrafluoro-4-(2-methylprop-2-enoyloxy)butane-1-sulfonate;triphenylsulfanium
• CAS: 960080-32-4
• 化学式: C₈H₉F₄O₅S*C₁₈H₁₅S
• 分子量: 556.599
• InChiKey: XFCXPQZFZAEPCU-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  6.05
• 重原子数：
  37
• 可旋转键数：
  9
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.19
• 拓扑面积：
  92.9
• 氢给体数：
  0
• 氢受体数：
  9

反应信息

• 作为产物：
  描述：

  triethylammonium 1,1,2,2-tetrafluoro-4-hydroxy-butane-1-sulfonate 、 三苯基溴化锍 以 氯仿 为溶剂， 反应 3.0h， 以97%的产率得到triphenylsulfonium 1,1,2,2,-tetrafluoro-4-(2-methyl-acryloyloxy)-butane-1-sulfonate
  参考文献：
  名称：

  Ammonium Fluoroalkanesulfonates and a Synthesis Method Therefor

  摘要：

  一种氢氧基氟烷磺酸铵是通过在磺化剂的作用下使用有机碱对溴氟醇进行磺化而获得的。将氢氧基氟烷磺酸铵氧化后得到一种氢氧基氟烷磺酸铵盐。通过酯化将氢氧基氟烷磺酸铵转化为一种离子氟烷磺酸盐。这种离子氟烷磺酸盐在化学增感抗蚀剂等中作为光酸发生剂是有用的。

  公开号：

  US20120004447A1

文献信息

• METHOD OF PREPARING PHOTOACID GENERATING MONOMER
  申请人：Coley Suzanne M.

  公开号：US20120172619A1

  公开（公告）日：2012-07-05

  A method of preparing a monomer comprises reacting a sultone of the formula (I): wherein each R is independently F, C 1-10 alkyl, fluoro-substituted C 1-10 alkyl, C 1-10 cycloalkyl, or fluoro-substituted C 1-10 cycloalkyl, provided that at least one R is F; n is an integer of from 0 to 10, and m is an integer of 1 to 4+2n, with a nucleophile having a polymerizable group. Monomers, including a photoacid-generating monomer, may be prepared by this method.

  一种制备单体的方法包括将公式（I）的磺酮与具有聚合基团的亲核试剂反应，其中每个R独立地为F、C1-10烷基、氟取代的C1-10烷基、C1-10环烷基或氟取代的C1-10环烷基，但至少一个R为F；n为0至10的整数，m为1至4+2n的整数。通过这种方法可以制备单体，包括光酸生成单体。
• PHOTOACID GENERATING MONOMER AND PRECURSOR THEREOF
  申请人：Coley Suzanne M.

  公开号：US20120172555A1

  公开（公告）日：2012-07-05

  A monomer compound has the formula (I): where each R 1 , R 2 , and R 3 is independently H, F, C 1-10 alkyl, fluoro-substituted C 1-10 alkyl, C 1-10 cycloalkyl, or fluoro-substituted C 1-10 cycloalkyl, provided that at least one of R 1 , R 2 , or R 3 is F; n is an integer of from 1 to 10, A is a halogenated or non-halogenated C 2-30 olefin-containing polymerizable group, and G + is an organic or inorganic cation. The monomer is the reaction product of a sultone precursor and the oxyanion of a hydroxy-containing halogenated or non-halogenated C 2-30 olefin-containing compound. A polymer includes the monomer of formula (I).

  一种单体化合物具有以下化学式（I）：其中每个R1、R2和R3独立地是H、F、C1-10烷基、氟代C1-10烷基、C1-10环烷基或氟代C1-10环烷基，前提是R1、R2或R3中至少有一个是F；n是1到10之间的整数，A是卤代或非卤代的C2-30烯烃含有聚合基团，G+是有机或无机阳离子。该单体是砜前体和含有羟基的卤代或非卤代C2-30烯烃含有化合物的氧负离子的反应产物。聚合物包括化学式（I）的单体。
• POLYMERIZABLE PHOTOACID GENERATORS
  申请人：Thackeray James W.

  公开号：US20120171616A1

  公开（公告）日：2012-07-05

  A compound has formula (I): Q-O-(A)-Z − G + (I) wherein Q is a halogenated or non-halogenated, C 2-30 olefin-containing group, A is a fluorine-substituted C 1-30 alkylene group, a fluorine-substituted C 3-30 cycloalkylene group, a fluorine-substituted C 6-30 arylene group, or a fluorine-substituted C 7-30 alkylene-arylene group, Z is an anionic group comprising sulfonate, sulfonamide, or sulfonamide, and G + has formula (II): wherein X is S or I, each R 0 is halogenated or non-halogenated and is independently C 1-30 alkyl group; a polycyclic or monocyclic C 3-30 cycloalkyl group; a polycyclic or monocyclic C 4-30 aryl group; or a combination of these, wherein when X is S, one of the R 0 groups is optionally attached to one adjacent R 0 group by a single bond, and a is 2 or 3, wherein when X is I, a is 2, or when X is S, a is 3. A copolymer, a photoresist, a coated substrate and method of patterning are disclosed.

  一种化合物的化学式为(I): Q-O-(A)-Z−G+(I)，其中Q是卤代或非卤代的含有C2-30烯烃基团的基团，A是氟代的C1-30烷基烯基基团、氟代的C3-30环烷基烷基基团、氟代的C6-30芳基烷基基团或氟代的C7-30烷基芳基基团，Z是包括磺酸盐、磺酰胺或磺酰胺的阴离子基团，G+的化学式为(II)：其中X为S或I，每个R0为卤代或非卤代且独立的C1-30烷基基团；多环或单环的C3-30环烷基基团；多环或单环的C4-30芳基基团；或这些的组合，其中当X为S时，其中一个R0基团可以通过单键连接到相邻的一个R0基团上，且a为2或3，当X为I时，a为2，当X为S时，a为3。还公开了共聚物、光阻、涂层基板和图案化方法。
• POLYMERIZABLE SULFONIC ACID ONIUM SALT AND RESIN
  申请人：Nagai Tomoki

  公开号：US20100063232A1

  公开（公告）日：2010-03-11

  A resin that includes a repeating unit shown by the following formula (10) has an excellent performance as a radiation sensitive acid generator, and exhibits only a small adverse effect on the environment and a human body. wherein R 1 represents a hydrogen atom or the like, M + represents a specific cation, and n is an integer from 1 to 5.

  以下是翻译结果： 一种包括以下公式（10）所示的重复单元的树脂具有出色的辐射敏感酸发生剂性能，对环境和人体只有很小的负面影响。其中，R1代表氢原子或类似物，M+代表特定的阳离子，n为1至5的整数。
• Photoacid generating monomer and precursor thereof
  申请人：Coley Suzanne M.

  公开号：US08716518B2

  公开（公告）日：2014-05-06

  A monomer compound has the formula (I): where each R1, R2, and R3 is independently H, F, C1-10 alkyl, fluoro-substituted C1-10 alkyl, C1-10 cycloalkyl, or fluoro-substituted C1-10 cycloalkyl, provided that at least one of R1, R2, or R3 is F; n is an integer of from 1 to 10, A is a halogenated or non-halogenated C2-30 olefin-containing polymerizable group, and G+ is an organic or inorganic cation. The monomer is the reaction product of a sultone precursor and the oxyanion of a hydroxy-containing halogenated or non-halogenated C2-30 olefin-containing compound. A polymer includes the monomer of formula (I).

  单体化合物的化学式为（I）：其中每个R1，R2和R3独立地为H，F，C1-10烷基，氟代C1-10烷基，C1-10环烷基或氟代C1-10环烷基，前提是R1，R2或R3中至少有一个是F; n是1至10的整数，A是含卤或不含卤的C2-30含烯基可聚合基团，G +是有机或无机阳离子。该单体是磺酸酯前体和含羟基的卤代或不卤代C2-30含烯基化合物的氧阴离子的反应产物。聚合物包括化学式（I）的单体。