申请人:Public Joint Stock Company "Sibur Holding"
(PJSC "Sibur Holding")
公开号:EP4098666A1
公开(公告)日:2022-12-07
The invention relates to the production of synthetic polymers used in the manufacture of tires and tire parts, golf balls and other industrial rubber goods. In particular, the present invention relates to methods for producing a modified polydiene by catalytic polymerization of a conjugated diene in an organic solvent, wherein the catalytic system used includes a lanthanide compound, an organoaluminum compound, a conjugated diene, and a halogen-containing component, followed by post-polymerization modification with at least one phosphorus-nitrogen compound the chemical structure of which is based on repeating (-P=N-)n units, where n is an integer from 3 to 24. The technical result of the invention is the obtaining a modified stereoregular polydiene characterized by a narrow molecular weight distribution, good processability in the composition of rubber compounds, a low rolling resistance, and a low wearability.
本发明涉及用于制造轮胎和轮胎部件、高尔夫球和其他工业橡胶制品的合成聚合物的生产。特别是,本发明涉及通过共轭二烯在有机溶剂中的催化聚合生产改性聚二 烯的方法,其中使用的催化体系包括镧系化合物、有机铝化合物、共轭二烯和含卤 成分,然后用至少一种磷氮化合物进行聚合后改性,该磷氮化合物的化学结构基于 重复的 (-P=N-)n 单元,其中 n 为 3 至 24 的整数。本发明的技术成果是获得了一种改性立体扁平聚二烯烃,其特点是分子量分布窄、在橡胶复合物成分中具有良好的加工性、低滚动阻力和低磨损性。